ZYLINDRISCHER REAKTOR UND DESSEN VERWENDUNG ZUR KONTINUIERLICHEN HYDROFORMYLIERUNG

    公开(公告)号:EP3394022A1

    公开(公告)日:2018-10-31

    申请号:EP16822988.8

    申请日:2016-12-21

    Applicant: BASF SE

    Abstract: The invention relates to a cylindrical reactor (1) having a vertical longitudinal axis for continuous hydroformylation of a C6-C20 olefin or a mixture of C6-C20 olefins with synthesis gas in the presence of a homogeneously dissolved metal-carbonyl complex catalyst, - comprising a plurality of field tubes (2) oriented parallel to the longitudinal axis of the reactor (1) and welded in a tube base at the upper end of the reactor (1), - comprising a circulation tube (3) that is open at both ends, which surrounds the field tubes (2) and protrudes over same at the lower end thereof, - comprising a jet nozzle (4) at the base of the reactor (1) for injecting the educt mixture containing the C6-C20 olefin, the synthesis gas and the metal-carbonyl complex catalyst, wherein - the field tubes (2) are designed in terms of the number and dimensions thereof such that - the total heat exchange surface thereof with respect to the internal volume of the reactor is in the range of 1 m2/m3 to 11 m2/m3 and - the cross-sectional surface area occupied by the field tubes (2) in relation to the cross-sectional area of the circulation tube (3) is in the range of 0.03 m2/m2 to 0.30 m2/m2,- a gas distributor ring (5) is provided at the lower end of the circulation tube (3), on the inner wall thereof, by means of which a sub-stream of the synthesis gas can be supplied, and wherein - one or more distributor bases (6) are provided in the circulation tube (3).

    VERFAHREN ZU HERSTELLUNG VON OLIGOMEREN DES BUTEN
    37.
    发明公开
    VERFAHREN ZU HERSTELLUNG VON OLIGOMEREN DES BUTEN 有权
    用于生产低聚物丁烯

    公开(公告)号:EP2782888A1

    公开(公告)日:2014-10-01

    申请号:EP12778343.9

    申请日:2012-10-25

    Applicant: BASF SE

    Abstract: Procedure for manufacturing oligomers by continuous oligomerization of butenes, characterized in that a) an initial stream is used which contains 1-butene and 2-butene at a total concentration of 10 to 70 wt% and 10 to 60 wt% of iso-butane (called initial stream 1 hereafter), b) said initial stream 1 is converted until more than 60 wt% of the 1-butene contained in initial stream 1, but less than 50 wt% of the 2-butene contained in initial stream 1, are converted into oligomers, c) the oligomers obtained in b) are separated and optionally fed to further processing, and the remaining stream is fed to a distillation processing step, d) iso-butane is separated by distillation from the remaining steam, e) the iso-butane-depleted stream (called initial stream 2 hereafter) obtained after the distillation processing step d) is converted into oligomers.

    VERFAHREN ZUR HYDROFORMYLIERUNG VON OLEFINEN

    公开(公告)号:EP3071542A1

    公开(公告)日:2016-09-28

    申请号:EP14792800.6

    申请日:2014-10-31

    Applicant: BASF SE

    CPC classification number: C07C45/50 C07C47/02

    Abstract: The invention relates to the hydroformylation of olefins having 6 to 20 carbon atoms in the presence of a cobalt catalyst in the presence of an aqueous phase being mixed in a reactor, wherein a first current containing hydroformylation products is drawn on the head of the reactor and a second current containing an aqueous phase is drawn from the sump of the reactor. The flow rate of the second current is controlled according to a temperature which is measured at a location in the sump of the reactor or in a line leading out of the sump. The yield of raw hydroformylation product is increased as a consequence of stable continuous operation.

    Abstract translation: 本发明涉及在反应器中混合水相存在下,在钴催化剂存在下,在钴催化剂存在下,碳原子数为6〜20的烯烃的加氢甲酰化反应,其中含有加氢甲酰化产物的第一流含有反应器的头部, 含有水相的第二电流从反应器的集水槽抽出。 第二电流的流量根据在反应堆的集水池中的位置处或在从集水槽出来的管线中测量的温度来控制。 原始加氢甲酰化产物的产率由于稳定的连续操作而增加。

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