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公开(公告)号:NZ571015A
公开(公告)日:2011-04-29
申请号:NZ57101507
申请日:2007-02-21
Applicant: BASF SE
Inventor: LANGE ARNO , MACH HELMUT , RATH HANS PETER , POSSELT DIETMAR
IPC: C10L1/2383 , C07C215/50 , C07D265/16 , C08F8/32 , C08G14/073 , C08G61/12 , C08G73/02 , C09K15/24 , C09K15/30 , C10L1/222 , C10L1/233 , C10L1/238 , C10L10/18 , C10M159/16
Abstract: Disclosed is the use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtained by reacting a tetrahydrobenzoxazine of the general formula I, wherein the substituents are as defined in the specification, with one or more of the same or different phenols of the general formula II, wherein the substituents are as defined in the specification, and/or with one or more of the same or different tetrahydrobenzoxazines of the general formula I, as antioxidants for stabilizing inanimate organic material against the action of light, oxygen and heat.
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公开(公告)号:AT484546T
公开(公告)日:2010-10-15
申请号:AT08761240
申请日:2008-06-19
Applicant: BASF SE
Inventor: HANEFELD PHILLIP , HILDEBRANDT NICOLE , MUEHLBACH KLAUS , MACH HELMUT , WALTER HANS-MICHAEL , TEYSSIE DOMINIQUE , FICHET ODILE , VANCAEYZEELE CEDRIC , DAVION BENJAMIN
IPC: C08L23/22
Abstract: A description is given of a semi-interpenetrating network having a first phase of a linear noncrosslinked isobutene polymer and a second phase of a crosslinked polymer, wherein the crosslinked polymer is obtained by crosslinking molecular enlargement reaction in the presence of the isobutene polymer. The crosslinked polymer is preferably obtained by free-radical polymerization of ethylenically unsaturated monomers comprising at least one polyethylenically unsaturated monomer. The networks are suitable as molding compounds having gas and moisture barrier effect or as adhesives.
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公开(公告)号:DE502005010046D1
公开(公告)日:2010-09-16
申请号:DE502005010046
申请日:2005-05-11
Applicant: BASF SE
Inventor: HERRLICH-LOOS MIRJAM , DROHMANN CHRISTIAN , MIJOLOVIC DARIJO , WETTLING THOMAS , MACH HELMUT
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公开(公告)号:AT468360T
公开(公告)日:2010-06-15
申请号:AT04732983
申请日:2004-05-14
Applicant: BASF SE
Inventor: LANGE ARNO , MACH HELMUT , RATH HANS , KARL ULRICH , IVAN BELA , GROH PETER , NAGY ZSUZSANNA , PALFI VIKTORIA
IPC: C08F8/06 , C08F2/38 , C08F10/10 , C10L1/16 , C10L1/18 , C10L1/195 , C10L1/198 , C10M143/04 , C10M143/18
Abstract: The present invention relates to a process for preparing carboxyl-terminated polyisobutenes by ozonolysis of polyisobutenes terminated by an ethylenically unsaturated double bond.
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公开(公告)号:AT455132T
公开(公告)日:2010-01-15
申请号:AT06777092
申请日:2006-08-28
Applicant: BASF SE
Inventor: RATH HANS , LANGE ARNO , MACH HELMUT , BLACKBOROW RICHARD
Abstract: A process is described for epoxidizing an ethylenically unsaturated isobutene polymer, in which an organic phase comprising the isobutene polymer is contacted with an aqueous phase which comprises formic acid and hydrogen peroxide. The process affords essentially quantitative conversions after a short reaction time.
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公开(公告)号:HUE048286T2
公开(公告)日:2020-07-28
申请号:HUE10180624
申请日:2007-02-21
Applicant: BASF SE
Inventor: LANGE ARNO , MACH HELMUT , RATH HANS PETER , POSSELT DIETMAR
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公开(公告)号:CA2641399C
公开(公告)日:2015-11-24
申请号:CA2641399
申请日:2007-02-21
Applicant: BASF SE
Inventor: LANGE ARNO , MACH HELMUT , RATH HANS PETER , POSSELT DIETMAR
IPC: C10L1/2383 , C07C215/50 , C07D265/16 , C08F8/32 , C08G14/073 , C08G61/12 , C08G73/02 , C09K15/24 , C09K15/30 , C10L1/222 , C10L1/233 , C10L1/238 , C10L10/18 , C10M159/16
Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine 1 (see formula I) where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II (see formula II) where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.
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公开(公告)号:ES2380448T3
公开(公告)日:2012-05-11
申请号:ES10167054
申请日:2006-07-18
Applicant: BASF SE
Inventor: LANGE ARNO , MACH HELMUT , RATH HANS PETER , POSSELT DIETMAR
IPC: C07D265/16 , C07D498/04 , C09K15/20 , C10L1/22 , C10M133/48
Abstract: Tetrahidrobenzoxazinas de la fórmula general **Fórmula**Ia en la que el substituyente R1 designa un resto hidrocarburo con 1 a 3000 átomos de carbono, que puede estar interrumpido por uno o varios heteroátomos del grupo O y S, y/o por una o varias agrupaciones NR6, designando R6 un átomo de hidrógeno o un resto alquilo con 1 a 4 átomos de carbono, y representando los substituyentes R2, R3, R4 y R5, independientemente entre sí, átomos de hidrógeno, grupos hidroxilo o restos hidrocarburo, respectivamente con 1 a 3000 átomos de carbono, que pueden estar interrumpidos por uno o varios heteroátomos del grupo O y S y/o por una o varias agrupaciones NR6, pudiendo representar el substituyente R4 también un resto de la fórmula Y **Fórmula** en la que los substituyentes R1, R2, R3 y R5 tienen los significados citados anteriormente, y el substituyente X designa un eslabón puente de carbono-hidrógeno, que está constituido por una o varias unidades isobuteno, o contiene una o varias unidades isobuteno, o pudiendo representar el substituyente R4 también un resto de la fórmula Z o Z' **Fórmula** en las que los substituyentes R1, R2, R3 y R5 tienen los significados citados anteriormente, y los substituyentes R10 y R11 pueden ser iguales o diferentes y designan hidrógeno o un resto alquilo con 1 a 10 átomos de carbono, y en las que los substituyentes R2 y R3 o R3 y R4 o R4 y R5 pueden formar también un segundo anillo de tetrahidrooxazina con la estructura parcial -O-CH2-NR7-CH2- enlazada al anillo de benceno, o los substituyentes R2 y5 R3 y R4 y R5 pueden formar también un segundo y un tercer anillo de tetrahidrooxazina con las estructuras parciales unidas al núcleo de benceno -O-CH2-NR7-CH2- y -O-CH2-NR8-CH2-, significando R7 y R8, independientemente entre sí, restos hidrocarburo con 1 a 3000 átomos de carbono en cada caso, que pueden estar interrumpidos por uno o varios heteroátomos del grupo O y S y/o por una o varias agrupaciones NR6, con la condición de que al menos uno de los substituyentes R1, R7 o R8 presente 25 a 3000 átomos de carbono, y los demás substituyentes del grupo R1, R2, R3, R4, R5, R7 y R8, si representan restos hidrocarburo, presenten respectivamente 1 a 20 átomos de carbono.
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公开(公告)号:AT512141T
公开(公告)日:2011-06-15
申请号:AT06777819
申请日:2006-07-18
Applicant: BASF SE
Inventor: LANGE ARNO , MACH HELMUT , RATH HANS , POSSELT DIETMAR
IPC: C07D265/16 , C07D498/04 , C10L1/22
Abstract: Use of tetrahydrobenzoxazine compound (I) as stabilizers for the stabilization of dead organic materials against light, oxygen and heat. Use of tetrahydrobenzoxazine compound of formula (I) as stabilizers for the stabilization of dead organic materials against light, oxygen and heat. R 1> : 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); R 6> : H or 1-4C alkyl; either R 2>, R 3>, R 5> : H, OH or 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); and R 4> : H, OH or 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); or R 4> : benzoxazine compound of formula (II), benzoxazine compound of formula (III) or (III-a); or R 2>+R 3> with benzol, R 3>+R 4> with benzol, R 4>+R 5> with benzol : O-CH 2-NR 7>-CH 2, O-CH 2-NR 8>-CH 2 or tetrahydro oxazine ring; X : hydrocarbon bridge containing one or more isobutene units; R 10>, R 11> : H or 1-10C-akyl; and R 7>, R 8> : 1-3000C hydrocarbyl (interrupted with one or more heteroatom of O or S, and one or more NR 6>). Where at least R 1>-R 8> has 4-3000C atoms and the remaining groups has 1-20C atoms. Independent claims are included for: (1) turbine fuel composition comprising a turbine fuel (jet fuel) and at least (I); (2) an additive concentrate for turbine fuels comprising (I), optionally at least a diluent and an additive; (3) a preparation of (I) comprising reacting substituted phenol, benzcatechin, resorcin, hydroquinone, phloroglucin or hydroxyhyroquinone with one mole of primary amine of formula (R 1>NH 2), (R 7>-NH 2) or (R 8>-NH 2), and two mole of formaldehyde or formaldehyde-free substance and two mole of alcohol of formula (R 9>-OH) in the presence of nitrogen reagent of formula (R 9>-O-CH 2-N(A)-CH 2-O-R 9>); and (4) tetrahydrobenzoxazine compound (I). A : R 1> or R 7>; and R 9> : 1-8C alcohol. [Image] [Image].
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公开(公告)号:AU2006274052B2
公开(公告)日:2011-05-12
申请号:AU2006274052
申请日:2006-07-18
Applicant: BASF SE
Inventor: LANGE ARNO , RATH HANS PETER , MACH HELMUT , POSSELT DIETMAR
IPC: C07D265/16 , C07D498/04 , C10L1/22
Abstract: Use of tetrahydrobenzoxazine compound (I) as stabilizers for the stabilization of dead organic materials against light, oxygen and heat. Use of tetrahydrobenzoxazine compound of formula (I) as stabilizers for the stabilization of dead organic materials against light, oxygen and heat. R 1> : 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); R 6> : H or 1-4C alkyl; either R 2>, R 3>, R 5> : H, OH or 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); and R 4> : H, OH or 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); or R 4> : benzoxazine compound of formula (II), benzoxazine compound of formula (III) or (III-a); or R 2>+R 3> with benzol, R 3>+R 4> with benzol, R 4>+R 5> with benzol : O-CH 2-NR 7>-CH 2, O-CH 2-NR 8>-CH 2 or tetrahydro oxazine ring; X : hydrocarbon bridge containing one or more isobutene units; R 10>, R 11> : H or 1-10C-akyl; and R 7>, R 8> : 1-3000C hydrocarbyl (interrupted with one or more heteroatom of O or S, and one or more NR 6>). Where at least R 1>-R 8> has 4-3000C atoms and the remaining groups has 1-20C atoms. Independent claims are included for: (1) turbine fuel composition comprising a turbine fuel (jet fuel) and at least (I); (2) an additive concentrate for turbine fuels comprising (I), optionally at least a diluent and an additive; (3) a preparation of (I) comprising reacting substituted phenol, benzcatechin, resorcin, hydroquinone, phloroglucin or hydroxyhyroquinone with one mole of primary amine of formula (R 1>NH 2), (R 7>-NH 2) or (R 8>-NH 2), and two mole of formaldehyde or formaldehyde-free substance and two mole of alcohol of formula (R 9>-OH) in the presence of nitrogen reagent of formula (R 9>-O-CH 2-N(A)-CH 2-O-R 9>); and (4) tetrahydrobenzoxazine compound (I). A : R 1> or R 7>; and R 9> : 1-8C alcohol. [Image] [Image].
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