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    PRODUCTION OF ISOBUTYLENE HOMOPOLYMER OR COPOLYMER DERIVATIVES
    2.
    发明申请
    PRODUCTION OF ISOBUTYLENE HOMOPOLYMER OR COPOLYMER DERIVATIVES 审中-公开
    MANUFACTURING异丁烯或共聚物衍生物

    公开(公告)号：WO2012072643A2

    公开(公告)日：2012-06-07

    申请号：PCT/EP2011071306

    申请日：2011-11-29

    Applicant: BASF SE ,  KOENIG HANNAH MARIA ,  MUEHLBACH KLAUS ,  MACH HELMUT ,  EICHENAUER ULRICH

    Inventor： KOENIG HANNAH MARIA ,  MUEHLBACH KLAUS ,  MACH HELMUT ,  EICHENAUER ULRICH

    IPC: C08F8/00 ,  C08F4/06 ,  C08F4/14 ,  C08F4/26 ,  C08F10/10 ,  C08F110/10

    CPC classification number: C08F8/00 ,  C08F2810/40 ,  C08F10/10 ,  C08F4/26 ,  C08F4/70

    Abstract: Disclosed is the production of isobutylene homopolymer or copolymer derivatives comprising a hydrophobic polyisobutylene polymer residue that has a number average molecular weight of 110 to 250,000 and low-molecular polar groups containing amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups. According to the invention, isobutylene or a monomer mixture containing isobutylene is polymerized in the presence of an iron halide donor complex acting as a polymerization catalyst, an aluminum trihalide donor complex or an aluminum alkyl halide donor complex containing an organic compound having an ether function or a carboxylic acid ester function as a donor, or a Lewis acid complex containing organic sulfonic acids and optional donors, the resulting highly reactive isobutylene polymer is reacted with a compound introducing the low-molecular polar group or a substructure thereof, and in case the reaction is performed using a substructure, the formation of the low-molecular polar group is completed by performing successive reactions.

    Abstract translation: 具有残余HY-降的解除，其数均分子量为110的聚异丁烯聚合物250,000，低分子量xylgruppen每个氨基官能团的极性基团，硝基，水力，硫醇基团，羧酸或-Car-onäurederivatfunktionen异丁烯或共聚物衍生物的生产， 包括磺酸或Sulfonsäurederivatfunktionen，醛和/或甲硅烷基，所述异丁烯或以有效的存在作为聚合卤化铁供体络合物，Aluminiumtrihalo-卤化物供体络合物或Aluminumalkylhalogenid供体复合物，其作为含异丁烯的单体混合物 供体包含具有醚官能团或羧酸功能，或含路易斯酸 - 柑-PLEX具有或不具有聚合供体的有机磺酸的有机化合物，所得到的与NIED高反应性异丁烯 ermolekulare极性基团或它们的部分结构，导入化合物和低分子量的极性基团的形成反应在与由随后的反应的部分结构反应的情况下完成。

    PRODUCTION OF ISOBUTYLENE COPOLYMER DERIVATIVES
    3.
    发明申请
    PRODUCTION OF ISOBUTYLENE COPOLYMER DERIVATIVES 审中-公开
    生产ISOBUTENCOPOLYMERISATEN导数的

    公开(公告)号：WO2012072536A2

    公开(公告)日：2012-06-07

    申请号：PCT/EP2011071112

    申请日：2011-11-28

    Applicant: BASF SE ,  KOENIG HANNAH MARIA ,  MUEHLBACH KLAUS ,  MACH HELMUT ,  EICHENAUER ULRICH

    Inventor： KOENIG HANNAH MARIA ,  MUEHLBACH KLAUS ,  MACH HELMUT ,  EICHENAUER ULRICH

    IPC: C08F8/32

    CPC classification number: C08F8/32 ,  C08F8/14 ,  C08F8/44 ,  C08F10/10 ,  C08F255/10 ,  C08F290/042 ,  C08F2810/40 ,  C08F4/70 ,  C08F4/26

    Abstract: Disclosed is the production of isobutylene copolymer derivatives by radically copolymerizing (a) 10 to 90 mol-% of a monoethylenically unsaturated C4 to C12 dicarboxylic acid or the anhydride, half-ester or full ester thereof, (b) 10 to 90 mol-% of a highly reactive isobutylene polymer having a number average molecular weight of 110 to 250,000, and (c) 0 to 50 mol-% of monoethylenically unsaturated compounds that can be copolymerized with monomer components (a) and (b), and then reacting the carboxylic acid or carboxylic acid derivative functions in the obtained isobutylene copolymer with ammonia, an amine and/or an alcohol so as to form groupings having hydroxy, carboxylic acid ester, amino, quaternized amino, amido and/or imido groups. In order to produce monomer component (b), isobutylene or a monomer mixture containing isobutylene is polymerized in the presence of an iron halide donor complex acting as a polymerization catalyst, an aluminum trihalide donor complex or an aluminum alkyl halide donor complex containing an organic compound having an ether function or a carboxylic acid ester function as a donor, or a Lewis acid complex containing at least one organic sulfonic acid and optional donors.

    Abstract translation: Isobutencopolymerisaten的衍生物的制备由（a）的10〜90％（摩尔）单烯类不饱和C 4至C 12二羧酸，bonsäure或其酸酐，半桥或全酯，自由基共聚（B）10〜90摩尔％反应性高的异丁烯 具有110的数均分子量为250,000，和（c）0〜50摩尔％的单烯属不饱和化合物的与所述单体组分（a）和（b）共聚，然后将羧酸或羧酸衍生物功能性在所得Isobutencopolymerisat与反应 含有氨，胺和/或醇，以形成具有羟基，羧酸酯，氨基，季铵化的氨基，酰氨基和/或酰亚胺基团，部分，其中一个（b）异丁烯以产生单体成分或异丁烯 在有效的情况下，作为聚合卤化铁供体络合物，Aluminiumtr单体混合物 含有ihalogenid供体配合物或Aluminumalkylhalogenid供体络合物作为供体，具有醚功能或羧酸酯官能团，或至少一种有机含磺酸 - 路易斯酸络合物，具有或不具有聚合供体的有机化合物。

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