公开(公告)号：CA2863836C

公开(公告)日：2020-06-30

申请号：CA2863836

申请日：2013-02-15

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS ,  MUHLBACH KLAUS ,  CORBERAN ROC ROSA ,  HASCHICK ROBERT ,  DAISS ANDREAS ,  VOLLAND MARCO-CHRISTIAN

IPC: C08F10/10

Abstract: Preparation of isobutene homopolymers having a weight-average molecular weight of 75 000 to 10 000 000 by polymerization of isobutene, by (a) performing the polymerization at -80°C to -190°C, (b) using, as an inert solvent, optionally halogenated C1 to C5 hydrocarbons, (c) using, as a polymerization catalyst, a Lewis acid complex, (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound comprising one oxygen atom and no abstractable proton, and (e) performing the polymerization in the presence of at least one chain length regulator comprising one tertiary olefinic carbon atom.

公开(公告)号：CA3014685A1

公开(公告)日：2017-08-24

申请号：CA3014685

申请日：2017-02-13

Applicant: BASF SE

Inventor： CORBERAN ROC ROSA ,  MUEHLBACH KLAUS ,  WETTLING THOMAS ,  KOSTJUK SERGEI V ,  VASILENKO IRINA ,  SHIMAN DMITRYI

IPC: C08F10/10 ,  C08F4/14 ,  C08F4/52 ,  C08F4/54 ,  C08F110/10

Abstract: The present invention relates to a process for preparing high- reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per homo- or copolymer chain end of at least 70 mol% which comprises polymerizing isobutene or an isobutene- comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or of an alkylaluminum halide-donor complex, said complex comprising, as the donor, a mixture of at least two organic compounds with at least one ether function each.

公开(公告)号：SG11201403143VA

公开(公告)日：2014-10-30

申请号：SG11201403143V

申请日：2013-01-04

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS

IPC: C08F110/10 ,  C08F2/00

Abstract: Continuous production of polyisobutylene having a content of terminal double bonds of greater than 50% by polymerization of isobutene in the presence of a polymerization catalyst usual therefor, by combining a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream together with a stream of pure isobutene, and feeding the combined stream into the reaction zone in such a manner that the steady state concentration of isobutene in the combined stream at the point where the combined stream is fed into the reaction zone has a value of on average at least 40% by weight, and the invention also relates to a polymerization system therefor.

公开(公告)号：AT508147T

公开(公告)日：2011-05-15

申请号：AT07704597

申请日：2007-02-15

Applicant: BASF SE

Inventor： HANEFELD PHILLIP ,  WALTER HANS-MICHAEL ,  KIEFER MATTHIAS ,  MACH HELMUT ,  WETTLING THOMAS ,  SIGL MARCUS ,  SCHUBERT MARKUS ,  STEPHAN JUERGEN ,  PAPP RAINER ,  POPLOW FRANK

IPC: C08F110/10 ,  C08F2/00 ,  C10G57/02

Abstract: Preparation of polyisobutylene having a content of terminal double bonds of more than 50% by polymerizing isobutene using a polymerization catalyst customary therefor from a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream which may comprise up to 3000 ppm by weight, of 1,3-butadiene, by reducing the content of oxygenates in the C4 hydrocarbon stream before the polymerization of the isobutene by contacting it with an inorganic adsorbent at a pressure of from 1 to 20 bar and a temperature of from 20 to 220° C.

公开(公告)号：AT495203T

公开(公告)日：2011-01-15

申请号：AT06807243

申请日：2006-10-13

Applicant: BASF SE

Inventor： RATH HANS PETER ,  MACH HELMUT ,  WETTLING THOMAS

IPC: C08F10/10 ,  C08F4/14

Abstract: The invention relates to a process for preparing polyisobutene having a mean molecular weight Mn of from 400 to 50 000, in particular from 500 to 10 000, by polymerizing isobutene in the presence of a BF3-containing complex catalyst, wherein the polymerization is carried out at least temporarily in the presence of one or more cyclic ethers.

公开(公告)号：CA3070031A1

公开(公告)日：2019-02-21

申请号：CA3070031

申请日：2018-08-07

Applicant: BASF SE

Inventor： CORBERAN ROC ROSA ,  MUEHLBACH KLAUS ,  WETTLING THOMAS ,  KOSTJUK SERGEI V ,  VASILENKO IRINA ,  SHIMAN DMITRYI

IPC: C08F110/10 ,  C08F4/14

Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol%. The present invention further relates to novel isobutene polymers.

公开(公告)号：SG11201810402PA

公开(公告)日：2018-12-28

申请号：SG11201810402P

申请日：2017-07-14

Applicant: BASF SE

Inventor： CORBERAN ROC ROSA ,  MUEHLBACH KLAUS ,  WETTLING THOMAS ,  KOSTJUK SERGEI V ,  VASILENKO IRINA ,  SHIMAN DMITRYI ,  BERAZIANKA IVAN

IPC: C08F10/10 ,  C08F4/12 ,  C08F4/14 ,  C08F4/18 ,  C08F4/26

Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.

公开(公告)号：CA3031140A1

公开(公告)日：2018-01-25

申请号：CA3031140

申请日：2017-07-14

Applicant: BASF SE

Inventor： CORBERAN ROC ROSA ,  MUEHLBACH KLAUS ,  WETTLING THOMAS ,  KOSTJUK SERGEI V ,  VASILENKO IRINA ,  SHIMAN DMITRYI ,  BERAZIANKA IVAN

IPC: C08F10/10 ,  C08F4/12 ,  C08F4/14 ,  C08F4/18 ,  C08F4/26

Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol%. The present invention further relates to novel isobutene polymers.

公开(公告)号：SG11201510755VA

公开(公告)日：2016-02-26

申请号：SG11201510755V

申请日：2014-07-07

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS

IPC: C08F10/10 ,  C08F2/00 ,  C08F110/10

Abstract: A polyisobutylene having a total content of vinylidene double bonds of more than 50 mol % and a number-average molecular weight of 500 to 10 000 daltons, where at least 10% of all the vinylidene double bonds in the polyisobutylene are part of one or more side chains composed of at least 2 carbon atoms from the main polyisobutylene chain. Such a polyisobutylene is suitable for production of fuel and lubricant additives.

公开(公告)号：SG11201401042RA

公开(公告)日：2014-09-26

申请号：SG11201401042R

申请日：2012-10-10

Applicant: BASF SE

Inventor： KÖNIG HANNAH MARIA ,  URBAN RAINER ,  MÜHLBACH KLAUS ,  WETTLING THOMAS ,  RACHWALSKY UWE ,  HIRSCH STEFAN ,  BERG ANNE ,  MACH HELMUT

IPC: C08F10/10 ,  C08F4/14

Abstract: Production of isobutene homo- or copolymers having a number average molecular weight of 500 to 5,000,000 by polymerisation of isobutene or an isobutene-containing monomer mixture in the presence of a Lewis acid or a complex containing a Lewis acid as a polymerisation catalyst, the polymerisation being performed in the presence of at least one hemiacetal or acetal, which can be obtained by protonic acid-catalysed reaction of at least one C1 to C12 hydrocarbyl alcohol with at least one aldehyde or ketone having 1 to 12 carbon atoms.