Quick-hardening polymer mixt. coating powders or solns. - contain epoxy cpd. and poly:carboxylic acid units as acid, anhydride and/or ester gps.

    公开(公告)号:DE2754399A1

    公开(公告)日:1979-06-13

    申请号:DE2754399

    申请日:1977-12-07

    Applicant: HOECHST AG

    Abstract: Reactive, hardenable polymer mixt. contains (A) epoxy cpds. and (B) polycarboxylic acid units. (B) contains (a) a cpd. of formula (I) or (Ia): (where R1 is the residue of an OH gp.-contg. polymeric polymsn. and/or condensn. prod. polyester having OH-no. 20-300 or phenoplast having OH-no. 100-800; R2 is the residue of an at least tetrabasic carboxylic acid contg. an esterifiable COOH gp. in o- or peri-position; R5 is as R2 or is the residue of an at least dibasic carboxylic acid contg. an esterifiable COOH gp. in the o- or periposition) and/or (b) an at least tetrabasic cyclic carboxylic acid cpd. contg. two o- or peri-COOH gps. or one anhydride gp. together with at least one R1 gp. and/or (c) a cpd. (I) or (Ia) in which the anhydride gps. are replaced, at least partly, by free acid and/or ester gps., and/or (d) a cpd. (b) in which the anhydride gps. of the polycarboxylic acid cpds. are replaced, at least partly, by free acid- and/or ester gps. The mixts., as solns. or powders, may be used as coating compsns., e.g. as stovable lacquers, primers, top lacquers, 1-layer lacquers, shock-drying systems for coil-coating in lacquering food tins. The mixts. can also be used as laminates, as protective coatings, e.g. for articles exposed to aggressive media, weathering, solvents, heat, 2-component hot melt- and thermosetting adhesives; as binders, e.g. for textiles, and as moulded resins, casting resins, putties, foams and insulating lacquers. The mixts. are stable, have high reactivity, can be crosslinked at 20 degrees C, and can be used as powders which cause no environmental pollution in use. Powder lacquers may be hardened by stoving at 100-180 degrees C in 30 min.

    35.
    发明专利
    未知

    公开(公告)号:ES2042490T3

    公开(公告)日:1993-12-16

    申请号:ES86117167

    申请日:1986-12-09

    Applicant: HOECHST AG

    Abstract: Aqueous polymer dispersions based on (A) 1 to 99% by weight of a carboxy-functional polymer which additionally contains epoxy groups, (B) 1 to 99% by weight of a polymer obtained from at least one alpha , beta -olefinically unsaturated monomer, the polymer (B) having been prepared in the presence of polymer (A), (C) 0 to 20% by weight of anionic or non-ionic emulsifiers or a mixture of the two or protective colloids, the quantity data relating to the solids content of components (A) to (C), and if appropriate further conventional additives, the sum of all the components always being 100%. The invention also relates to a process for the preparation of such polymer dispersions, which are particularly suitable as a binder component in metallic basecoats or metal-free, (uni) basecoats and electrocoatings.

    36.
    发明专利
    未知

    公开(公告)号:MX164417B

    公开(公告)日:1992-08-12

    申请号:MX464686

    申请日:1986-12-12

    Applicant: HOECHST AG

    Abstract: Aqueous polymer dispersions based on (A) 1 to 99% by weight of a carboxy-functional polymer which additionally contains epoxy groups, (B) 1 to 99% by weight of a polymer obtained from at least one alpha , beta -olefinically unsaturated monomer, the polymer (B) having been prepared in the presence of polymer (A), (C) 0 to 20% by weight of anionic or non-ionic emulsifiers or a mixture of the two or protective colloids, the quantity data relating to the solids content of components (A) to (C), and if appropriate further conventional additives, the sum of all the components always being 100%. The invention also relates to a process for the preparation of such polymer dispersions, which are particularly suitable as a binder component in metallic basecoats or metal-free, (uni) basecoats and electrocoatings.

    40.
    发明专利
    未知

    公开(公告)号:FI865060A

    公开(公告)日:1987-06-15

    申请号:FI865060

    申请日:1986-12-11

    Applicant: HOECHST AG

    Abstract: Aqueous polymer dispersions based on (A) 1 to 99% by weight of a carboxy-functional polymer which additionally contains epoxy groups, (B) 1 to 99% by weight of a polymer obtained from at least one alpha , beta -olefinically unsaturated monomer, the polymer (B) having been prepared in the presence of polymer (A), (C) 0 to 20% by weight of anionic or non-ionic emulsifiers or a mixture of the two or protective colloids, the quantity data relating to the solids content of components (A) to (C), and if appropriate further conventional additives, the sum of all the components always being 100%. The invention also relates to a process for the preparation of such polymer dispersions, which are particularly suitable as a binder component in metallic basecoats or metal-free, (uni) basecoats and electrocoatings.

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