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公开(公告)号:JP2000225437A
公开(公告)日:2000-08-15
申请号:JP2778099
申请日:1999-02-04
Applicant: KAO CORP
Inventor: KATO MASAYUKI , INA YOSHIMITSU
Abstract: PROBLEM TO BE SOLVED: To accelerate the hardening speed and to reduce the odor at the casting time by using binder composition containing acid hardenable resin and a specified hardening promoter, hardening agent composed of one or more kinds selected from groups of sulfonate compound and sufric acid and a specific ratio or higher of sulfur content brought about a phenol sulfonic acid and refractoriness granular material. SOLUTION: The binder composition containing the hardening promoter shown in the formula (in the formula, X1 and X2 show anyone of H, CH3 or C2H5), is used. The hardening agent containing >=50% sulfur content brought about the phenol sulfonic acid, is used. Desirably, the hardening agent is composed of the phenol sulfonic acid or the phenol sulfonic acid and the sulfric acid and the acid hardenable resin is one or more kinds selected from furfuryl alcohol, urea/formaldehyde polycondensation material, phenol/formaldehyde polycondensation material or fulfuryl alcohol/formaldehyde polycondensation material, and the hardening promoter is 7,5-bishydroxy methylfuran.
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公开(公告)号:JP2011224593A
公开(公告)日:2011-11-10
申请号:JP2010095168
申请日:2010-04-16
Inventor: KATO MASAYUKI , YOSHIDA AKIRA , MATSUO TOSHIKI
Abstract: PROBLEM TO BE SOLVED: To provide a binder composition for manufacturing a mold, which prevents an irritating gas from generating at manufacturing a mold and at molding, and to provide a composition for a mold using the binder composition.SOLUTION: The binder composition for manufacturing a mold contains: a fran resin; and a metallic halide containing one or more metallic elements selected from the group of alkali earth metals and zinc, wherein the content of the metallic element in the binder composition is 0.02-0.30 wt.%.
Abstract translation: 要解决的问题:提供一种用于制造模具的粘合剂组合物,其防止在制造模具和模制时产生刺激性气体,并提供使用粘合剂组合物的模具组合物。 解决方案:用于制造模具的粘合剂组合物包含:法兰树脂; 和含有一种或多种选自碱土金属和锌的金属元素的金属卤化物,其中粘合剂组合物中金属元素的含量为0.02-0.30重量%。 版权所有(C)2012,JPO&INPIT
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公开(公告)号:JP2011062729A
公开(公告)日:2011-03-31
申请号:JP2009215753
申请日:2009-09-17
Inventor: KATO MASAYUKI , SAWA MASUO
Abstract: PROBLEM TO BE SOLVED: To provide a binder composition for molding a mold which has excellent mold strength, has no precipitation of a resin, and has excellent preservation stability, and to provide a method for producing the mold using the same.
SOLUTION: The binder composition for molding the mold includes: an acid-curable resin (A); hydrolyzable tannin (B); and one or more silane coupling agents (C) selected from epoxy silane, mercapto silane and ureido silane.
COPYRIGHT: (C)2011,JPO&INPITAbstract translation: 待解决的问题:提供一种成型模具的粘合剂组合物,该模具具有优异的模具强度,没有树脂沉淀,并且具有优异的保存稳定性,并且提供了使用该模具的模具的制造方法。 解决方案:用于模塑模具的粘合剂组合物包括:酸固化树脂(A); 可水解单宁(B); 和一种或多种选自环氧硅烷,巯基硅烷和脲基硅烷的硅烷偶联剂(C)。 版权所有(C)2011,JPO&INPIT
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公开(公告)号:JP2000317578A
公开(公告)日:2000-11-21
申请号:JP13011199
申请日:1999-05-11
Applicant: KAO CORP
Inventor: KATO MASAYUKI , NAKAI SHIGEO
Abstract: PROBLEM TO BE SOLVED: To obtain heat generating element, with which the heat generating material for casting having high strength can be produced without developing any trouble caused by mutual reaction between binder and the heat generating component. SOLUTION: The heat generating element is combined of heat generating composition composed of an easily oxidizing material and an oxidant and if necessary, further, an oxidizing promotor with an organic coating. The organic coating is a capsule of polymer compound. This heat generating element is used for manufacturing the heat generating material for casting together with refractory granular material and binder and desirably, integrating with a mold. In this way, the heat generating efficiency can be improved, and since this element can simultaneously be molded with mold, the absorption of the moisture at the storing time can be restrained, too.
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公开(公告)号:JP2000246391A
公开(公告)日:2000-09-12
申请号:JP5524299
申请日:1999-03-03
Applicant: KAO CORP
Inventor: NAKAI SHIGEO , KATO MASAYUKI
IPC: B22C1/22
Abstract: PROBLEM TO BE SOLVED: To provide a manufacturing method for obtaining a caking additive with fast hardening velocity by reacting furfuryl alcohol and folmaldehyde. SOLUTION: In this manufacturing method, folmaldehyde and furfuryl alcohol are reacted while having an acidic catalyst whose acid dissociative constant (pKa) in one step is 2.5-4.6 at 25 deg.C, where folmaldehyde: furfuryl alcohol = 0.2-2.0:1 (mole ratio) will be satisfied. Also, acidic catalyst and furfuryl alcohol are reacted at acidic catalyst: furfuryl alcohol = 0.01-0.1:1 (mole ratio).
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公开(公告)号:JPH08174139A
公开(公告)日:1996-07-09
申请号:JP32479794
申请日:1994-12-27
Applicant: KAO CORP
Inventor: NAKAI SHIGEO , KATO MASAYUKI , SAWA MASUO , KIUCHI KAZUHIKO
IPC: B22C3/00
Abstract: PURPOSE: To prevent the degradation in the strength of a casting mold at the time of igniting and drying by incorporating a solvent having specific low polarity into an alcoholic mold coat compsn. to be applied on the surface of the casting mold formed of an acid curing binder, acidic hardener and refractories. CONSTITUTION: The org. solvent having a dissolution parameter of 6.5 to 11.0 and 3 to 10C is incorporated at 2 to 80wt. into this coating agent compsn. The acid hardener is one or >=2 kinds selected from an orthophosphoric acid, sulfuric acid and xylene sulfonic acid. Further, the dissolution parameter of the org. solvent is preferably 7.0 to 10.0 and more preferably 7.0 to 9.0. The carbon atoms of the org. solvent are preferably 5 to 7. In either case the content of the org. solvent is specified to 5 to 50wt.%.
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公开(公告)号:JPH0857577A
公开(公告)日:1996-03-05
申请号:JP21810294
申请日:1994-08-19
Applicant: KAO CORP
Inventor: KIUCHI KAZUHIKO , KATO MASAYUKI , SAWA MASUO , NAKAI SHIGEO
IPC: B22C1/10 , B22C1/22 , C08K5/15 , C08K5/1535 , C08L45/00
Abstract: PURPOSE: To provide a binder compsn. for production of a casting mold having a high curing rate. CONSTITUTION: This binder compsn. is formed by polycondensation of furfuryl alcohol, urea and aldehydes as essential components. The difference [A-B] between the furfuryl alcohol weight % (A) charged in the binder compsn. and unreacted furfuryl alcohol weight % (B) 5.0 to 60.0. Effect accelerators, such as 2,5-bishydroxy methyl furan and 2,5-bismethoxy methyl furan, are incorporated at 0.5 to 63.0wt.% into the binder compsn. Further, the water content in the binder compsn. is preferably
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公开(公告)号:JPH0857576A
公开(公告)日:1996-03-05
申请号:JP21810194
申请日:1994-08-19
Applicant: KAO CORP
Inventor: KIUCHI KAZUHIKO , KATO MASAYUKI , SAWA MASUO , NAKAI SHIGEO
IPC: B22C1/10 , B22C1/22 , C08K5/15 , C08K5/1535 , C08L45/00
Abstract: PURPOSE: To provide binder-hardener compsn. for producing a casting mold which makes it possible to obtain a casting mold which is high in curing rate, less generates harmful gases and has high strength. CONSTITUTION: This binder compsn. is formed by polycondensation of furfuryl alcohol, urea and aldehydes as essential components. The difference [A-B] between the furfuryl alcohol weight % (A) charged in the binder compsn. and unreacted furfuryl alcohol weight % (B) is 5.0 to 60.0. The water content in the binder compsn. is
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公开(公告)号:JPH07204775A
公开(公告)日:1995-08-08
申请号:JP1486994
申请日:1994-01-12
Applicant: KAO CORP
Inventor: KIUCHI KAZUHIKO , SAWA MASUO , NAKAI SHIGEO , KATO MASAYUKI
Abstract: PURPOSE:To provide a hardener compsn. for producing casting molds with which production of casting molds having high strength is possible. CONSTITUTION:A reformed wet phosphoric acid liquid is incorporated in this hardener compsn. for producing the casting molds. This reformed wet phosphoric acid liquid is formed by reforming a wet phosphoric acid liquid for industrial purposes produced by a wet phosphoric acid production process. The reformed wet phosphoric acid liquid is reformed in terms of concn. of P2O5 and oxidation reduction potential and is so reformed that the concn. of the P2O5 attains 40 to 65wt.% and the oxidation reduction potential attains 600 to 1250mV. The reformed wet phosphoric acid liquid is so reformed that the content of arsenic attains
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公开(公告)号:JPH05237587A
公开(公告)日:1993-09-17
申请号:JP33313292
申请日:1992-12-14
Applicant: KAO CORP
Inventor: TAKEYAMA ISAO , KIUCHI KAZUHIKO , NAKAI SHIGEO , TANAKA TSUTOMU , KATO MASAYUKI , MIZUNO WATARU
Abstract: PURPOSE:To improve a working environment, to drastically lessen the generation of blowhole defects in a resulted casting and to obtain sound casting. CONSTITUTION:The sand compsn. for forming a casting mold, the process for production of the casting mold and the hardener compsn. for forming the casting mold in which the nitrogen content, more preferably nitrogen content and phosphorus content in the formed casting mold and further preferably, the nitrogen content, phosphorus content and sulfur content therein are in a specified range and the weight ratio expressed by the sulfur content/(phosphorus content + sulfur content) in regenerated sand and hardener are in a specified range at the time of producing the casting mold by using the regenerated sand as an essential component and curing an acid curing furan resin.
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