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公开(公告)号:ZA87487B
公开(公告)日:1987-08-26
申请号:ZA87487
申请日:1987-01-22
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , SHIZUKA KOHEI , KAMBARA YOSHIHIKO
IPC: C07B61/00 , B01J23/00 , B01J23/72 , C07C67/00 , C07C231/00 , C07C231/06 , C07C233/09 , C07C
Abstract: Disclosed is a method for stopping and starting a reactor equipped with a heat exchanger, a catalyst settler, a catalyst filter and the like, which method is suitable for use in a process for the preparation of acrylamide by reacting acrylonitrile with water in the presence of a metallic copper-based catalyst used as a suspended bed. According to this method, various undesired phenomena which may occur at the beginning of operation can be prevented by discharging the metallic copper-based catalyst until the total amount of metallic copper and copper oxides present in the catalyst remaining in the reactor is not greater than a certain level based on the amount of metallic copper catalyst used at the beginning of the operation, or by discharging the catalyst until the amount of copper oxides is not greater than a certain level and then establishing an inert environment within the reactor.
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公开(公告)号:AU6820487A
公开(公告)日:1987-08-06
申请号:AU6820487
申请日:1987-02-02
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , SHIZUKA KOHEI , KAMBARA YOSHIHIKO
IPC: C07B61/00 , B01J23/00 , B01J23/72 , C07C67/00 , C07C231/00 , C07C231/06 , C07C233/09 , C07C102/08 , C07C103/133
Abstract: Disclosed is a method for stopping and starting a reactor equipped with a heat exchanger, a catalyst settler, a catalyst filter and the like, which method is suitable for use in a process for the preparation of acrylamide by reacting acrylonitrile with water in the presence of a metallic copper-based catalyst used as a suspended bed. According to this method, various undesired phenomena which may occur at the beginning of operation can be prevented by discharging the metallic copper-based catalyst until the total amount of metallic copper and copper oxides present in the catalyst remaining in the reactor is not greater than a certain level based on the amount of metallic copper catalyst used at the beginning of the operation, or by discharging the catalyst until the amount of copper oxides is not greater than a certain level and then establishing an inert environment within the reactor.
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公开(公告)号:ZA8506934B
公开(公告)日:1986-04-30
申请号:ZA8506934
申请日:1985-09-10
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , KITAGAWA JUN
IPC: C07D213/82 , B01J25/00 , C07B31/00 , C07B43/06 , C07B61/00 , C07C67/00 , C07C231/00 , C07C231/06 , C07C233/09 , C07D213/81 , C07D233/00 , C07C
CPC classification number: C07D213/81
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公开(公告)号:FI67843C
公开(公告)日:1985-06-10
申请号:FI770322
申请日:1977-01-31
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , SHIZUKA KOHEI , MIKAMI JUNJI , HIRAKAWA KENICHI , MATSUMURA MUTSUO
IPC: C07C231/06 , B01D15/04 , C07C20060101 , C07C67/00 , C07C231/00 , C07C231/24 , C07C233/09 , C08F120/56 , C07C103/133
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公开(公告)号:CS192477B2
公开(公告)日:1979-08-31
申请号:CS100477
申请日:1977-02-15
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , SHIZUKA KOHEI , MIKAMI JUNJI , HIRAKAWA KENICHI , MATSUMURA MUTSUO
IPC: C07C231/06 , B01D15/04 , C07C20060101 , C07C67/00 , C07C231/00 , C07C231/24 , C07C233/09 , C08F120/56 , C07C103/133
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公开(公告)号:CA985300A
公开(公告)日:1976-03-09
申请号:CA149198
申请日:1972-08-11
Applicant: MITSUI TOATSU CHEMICALS
Inventor: HASHIMOTO NOBUYOSHI , ASANO SHIRO , HONDA TADATOSHI , YOSHIMURA KIYOTAKA , TSUCHIYA RYOZI
IPC: C07B61/00 , B01J21/00 , C07C67/00 , C07C231/00 , C07C231/06 , C07C233/09
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公开(公告)号:DE2426805A1
公开(公告)日:1975-01-09
申请号:DE2426805
申请日:1974-06-04
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , YOSHIMURA KIYOTAKA , HASHIMOTO MASAO
IPC: C07C231/06 , C07C20060101 , C07C67/00 , C07C231/00 , C07C231/22 , C07C231/24 , C07C233/09 , C07C103/12
Abstract: A method of purifying an aqueous solution of acrylamide, which has been formed by reacting acrylonitrile with water in the presences of the metallic copper catalyst, and which contains cuprous ions, comprising treating said aqueous solution in a reaction zone which is substantially free of an oxygen containing gas or liquid.
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公开(公告)号:DE2427204A1
公开(公告)日:1974-12-19
申请号:DE2427204
申请日:1974-06-05
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , YOSHIMURA KIYOTAKA , HASHIMOTO MASAO
IPC: C07D213/82 , B01J23/00 , B01J23/72 , B01J25/00 , B01J27/00 , B01J27/24 , C07B61/00 , C07C67/00 , C07C231/00 , C07C231/06 , C07C233/09 , C07D213/81 , C07C103/08 , C07C103/12 , C07D31/44
Abstract: An improved process for converting acrylonitrile to the corresponding amide by hydrating said nitrile in the presence of a metallic copper catalyst and aluminum nitrate as promoter for said catalyst.
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公开(公告)号:CA930377A
公开(公告)日:1973-07-17
申请号:CA129949
申请日:1971-12-13
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , HONDA TADATOSHI , YOSHIMURA KIYOTAKA
IPC: C07B61/00 , B01J21/00 , B01J23/00 , B01J31/00 , C07C67/00 , C07C231/00 , C07C231/06 , C07C233/09
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公开(公告)号:DE2259096A1
公开(公告)日:1973-06-14
申请号:DE2259096
申请日:1972-12-02
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ASANO SHIRO , YOSHIMURA KIYOTAKA , TSUCHIYA RYOJI , HONDA TADATOSHI
IPC: C07C233/09 , C07C103/12
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