REMOVAL OF UNREACTED MATERIALS FROM UREA DYNTHESIS RFFLUENT

    公开(公告)号:CA939293A

    公开(公告)日:1974-01-01

    申请号:CA91858

    申请日:1970-08-28

    Abstract: 1295742 Treatment of urea-synthesis effluent MITSUI TOATSU CHEMICALS Inc 19 Aug 1970 [30 Aug 1969] 39911/70 Heading C2C Unreacted materials are separated from a urea-synthesis process obtained by reacting ammonia and carbon dioxide and containing urea, water, ammonia and carbon dioxide, by a high pressure distillation at 10-100 kg./cm. 2 gauge to remove the greater part of the unreacted ammonia and carbon dioxide as a gaseous mixture and separating the remaining unreacted materials at a low pressure by introducing the depleted urea-synthesis effluent into a low pressure rectification zone maintained at a pressure up to 5 kg./cm. 2 gauge and a head temperature of 60-120‹ C., heating the urea solution from the rectification zone in a heating zone maintained at 100-140‹ C. to drive out the remaining unreacted materials as a gaseous mixture of carbon dioxide and ammonia, and stripping urea solution from the heating zone in a stripping zone by contact with 0À01 to 0À2 mol. of carbon dioxide per mol. of urea.

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