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    Composition and method for dyeing keratinous fibers
    31.
    发明授权
    Composition and method for dyeing keratinous fibers 失效
    染色角质纤维的组合物和方法

    公开(公告)号：US3905761A

    公开(公告)日：1975-09-16

    申请号：US30199872

    申请日：1972-10-30

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ESTRADIER FRANCOISE

    IPC: A61K8/41 ,  A61Q5/10 ,  A61K7/13

    CPC classification number: A61Q5/10 ,  A61K8/413 ,  Y10S424/02

    Abstract: Diphenylamines having the formula

    WHEREIN: Y represents a member selected from the group consisting of a hydroxy and amino, R1 and R3, each independently, represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, a ureido residue, and -NHCOR wherein R is lower alkyl, R2 represents a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, a ureido residue, -NHCOR wherein R is lower alkyl, and -NHR8 wherein R8 represents a member selected from the group consisting of hydrogen, lower alkyl, lower hydroxyalkyl and carbamylmethyl, with the proviso that when R2 is -NHR8, R3 is not hydrogen R4, R5, R6, and R7 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl and lower alkoxy, with the proviso that when Y is hydroxy, R2 is not hydrogen, halogen, lower alkyl or lower alkoxy, and that when Y is amino, at least two of R1, R2 and R3 are other than a hydrogen and R2 is not hydrogen when R4, R5, R6 and R7 are all hydrogen and the acid addition salts of said diphenylamines.

    Abstract translation: 具有式WHEREIN：Y的二苯胺表示选自羟基和氨基的成员，R 1和R 3各自独立地表示选自氢，卤素，低级烷基，低级烷氧基，脲基残基的成员 和-NHCOR，其中R是低级烷基，R 2表示选自氢，卤素，低级烷基，低级烷氧基，脲基残基，-NHCOR，其中R是低级烷基，-NHR 8，其中R8代表成员 选自氢，低级烷基，低级羟基烷基和氨基甲酰甲基，条件是当R 2为-NHR 8时，R 3不为氢，R 4，R 6和R 7各自独立地表示选自氢， ，卤素，低级烷基和低级烷氧基，条件是当Y为羟基时，R 2不为氢，卤素，低级烷基或低级烷氧基，当Y为氨基时，R 1，R 2和R 3中的至少两个为 氢和 当R4，R5，R6和R7都是氢时，R2不是氢，也就是所说的二苯胺的酸加成盐。

    Indamines for dyeing keratinic fibers
    33.
    发明授权
    Indamines for dyeing keratinic fibers 失效
    用于染色可卡因纤维的痕迹

    公开(公告)号：US3876368A

    公开(公告)日：1975-04-08

    申请号：US38761373

    申请日：1973-08-13

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ESTRADIER FRANCOISE

    IPC: A61K8/41 ,  A61Q5/10 ,  H01K1/12 ,  D06P3/04

    CPC classification number: A61K8/413 ,  A61Q5/10 ,  Y10S424/01 ,  Y10S424/02

    Abstract: Imdamine having the formula

    Wherein R and R'' each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms, lower alkoxy having 1-4 carbon atoms, amino, acylamino wherein the acyl moiety has 1 to 4 carbon atoms and hydroxy, with the proviso that one, but not both of R and R'' is said amino, acylamino or hydroxy; R.sub.1 and R.sub.2 each independently represent a member selected from the group consisting of lower alkyl having 1-4 carbon atoms and lower alkyl having 1-4 carbon atoms and substituted with a member selected from the group consisting of hydroxy, acylamino wherein the acyl moiety has 1 to 4 carbon atoms, carbamyl, piperidino, benzoylamino and alkylsulfonamido wherein the alkyl moiety has 1 to 4 carbon atoms; R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms and lower alkoxy having 1-4 carbon atoms, and the salts formed by these indamines with organic or inorganic acids, in particular, their acetates, hydrochlorides, hydrobromides, persulfates, perchlorates and the double zinc salts of these compounds, which can, of course, be in a tautomeric form of that represented by formula (I), are usefully employed for dyeing keratinous fibers, and, in particular, human hair.

    Process for dyeing locks of human hair with tetragolium salts
    35.
    发明授权
    Process for dyeing locks of human hair with tetragolium salts 失效
    用TALRAGOLIUM SALTS染色人造毛发的方法

    公开(公告)号：US3649158A

    公开(公告)日：1972-03-14

    申请号：US3649158D

    申请日：1968-08-05

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE

    IPC: A61K8/49 ,  A61Q5/06 ,  C09B50/00 ,  D06P1/42 ,  D06P3/02 ,  D06P3/04 ,  D06P3/08 ,  D06P3/14

    CPC classification number: A61K8/494 ,  A61Q5/065 ,  Y10S8/917

    Abstract: A process and composition for dyeing keratinic fibers, particularly, human hair, in which tetrazolium salts are applied to the fibers in a colorless oxidized state and reduced to colored insoluble formazanes by reducing agents. The reducing agents are used so that the keratinic bonds are not disrupted and can be used at the same time that a permanent wave process is applied. Also, various shades can be obtained using leuco derivative dyes which become oxidized when functioning as reducing agents.

    Abstract translation: 用于染色角蛋白纤维，特别是人毛的方法和组合物，其中将四唑鎓盐以无色氧化态施用于纤维，并通过还原剂还原成为不溶性的甲。。 使用还原剂，使得角蛋白键不被破坏，并且可以在施加永久性波过程的同时使用。 此外，可以使用当用作还原剂时被氧化的无色衍生物染料获得各种色调。

    Basic dyes for use in coloring hair
    36.
    发明授权
    Basic dyes for use in coloring hair 失效
    用于染色头发的基本染发剂

    公开(公告)号：US3617163A

    公开(公告)日：1971-11-02

    申请号：US3617163D

    申请日：1967-01-09

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE

    IPC: A61K8/35 ,  A61Q5/06 ,  C07D209/48 ,  C07D295/13 ,  C09B1/28 ,  C09B51/00 ,  D06P1/41 ,  D06P3/14 ,  A61K7/12

    CPC classification number: C09B51/00 ,  A61K8/355 ,  A61Q5/065 ,  C07D209/48 ,  C07D295/13 ,  C09B1/28 ,  C09B1/285 ,  Y10S8/917

    Abstract: A hair dyeing composition comprises an aqueous solution of a hair coloring amount of a dye compound having the formula A-NR(CH2)n-NHR'' wherein R and R'' each independently are selected from the group consisting of hydrogen, lower alkyl and lower alkoxy, n is an integer of 2-6 and A is selected from the group consisting of anthroquinone, azo and benzene. The composition contains 0.01 to 3 percent of said dye compound and has a pH of about 4-10.

    Abstract translation: 式A-NR-（CH2）n-NHR'的化合物，其中R和R'是氢，n是2和6之间的整数，其中A选自（1）蒽醌基，其中NR-（CH2 ）n-NHR'在位置2或（2）蒽醌基，其中R 1和R 2选自氢和低级烷基，NR-（CH 2）n -NHR'链处于5位。 化合物可用作着色头发的基本染料。

    Amino phenols
    38.
    发明授权
    Amino phenols 失效
    AMINO PHENOLS

    公开(公告)号：US3546293A

    公开(公告)日：1970-12-08

    申请号：US3546293D

    申请日：1967-06-12

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE

    IPC: D06P1/32 ,  C07C91/44

    CPC classification number: A61K8/415 ,  A61Q5/10 ,  D06P1/32

    Abstract: Compounds suitable for use in one step hair and keratin fiber dyeing compositions which do not require the use of separate dye modifiers and are exceptionally color stable, having the formula IN WHICH R is selected from the group consisting of hydrogen and alkyll R1 is selected from the group consisting of alkyl, alkoxy, and dialkylamino, R4 which can be in position 5 or 6 on the ring is selected from the group consisting of hydrogen, halogen, hydroxy, alkyl, alkoxy and NH2, and at least one of said R1 and R4 is said dialkylamino or said NH2 .

    Abstract translation: 适合用于一步毛发和角蛋白纤维染色组合物的化合物，其不需要使用分开的染料改性剂并且是特别颜色稳定的，具有式I，其中R选自氢和烷基R1，选自 由烷基，烷氧基和二烷基氨基组成的组，可在环上5或6位的R 4选自氢，卤素，羟基，烷基，烷氧基和NH 2，并且所述R 1和R 4中的至少一个 是二烷基氨基或所述NH 2。

    Indoanilines in keratinic fiber dye compositions
    40.
    发明授权
    Indoanilines in keratinic fiber dye compositions 失效
    角质纤维染料组合物中的印花尼牌

    公开(公告)号：US3929404A

    公开(公告)日：1975-12-30

    申请号：US48252374

    申请日：1974-06-24

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ESTRADIER FRANCOISE

    IPC: A61K8/41 ,  A61Q5/10 ,  C07C275/26 ,  C07D295/13 ,  C07D295/135 ,  C09B53/02 ,  D06P3/14 ,  A61K7/13

    CPC classification number: C07D295/13 ,  A61K8/413 ,  A61Q5/10 ,  C07C275/26 ,  C07D295/135 ,  Y10S424/01

    Abstract: WHEREIN R1 represents hydrogen, halogen, alkyl or alkoxy; R2 represents alkyl, hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl) and mesylaminoalkyl; R3 represents hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinoalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl), mesylaminoalkyl; or R2 and R3 together form with the nitrogen atom to which they are attached a heterocycle selected from piperidino or morpholino; R4, R5 and R6 each independently represents hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino, and R5 can also represent amino, alkylamino, hydroxyalkylamino or carbamylalkylamino. The alkyl and alkoxy groups above can contain from 1 to 6 carbon atoms and the acyl group can contain from 2 to 7 carbon atoms. The present invention also relates to a process for the preparation of the above indoanilines and to dye compositions for keratinic fibers, and in particular living human hair, containing said indoanilines.

    Indoaniline of the formula

    Abstract translation: 式AD的吲哚苯胺，其中R1表示氢，卤素，烷基或烷氧基; R 2表示烷基，羟基烷基，氨基甲酰基烷基，哌啶子基烷基，吗啉基烷基，磺基烷基，二烷基氨基烷基，酰基氨基烷基（优选乙酰氨基烷基或苯甲酰基氨基烷基）和甲磺酰氨基烷基; R 3表示羟烷基，氨基甲酰基烷基，哌啶子基烷基，吗啉代烷基，磺基烷基，二烷基氨基烷基，酰氨基烷基（优选乙酰氨基烷基或苯甲酰氨基烷基），甲磺酰氨基烷基; 或者R 2和R 3与它们所连接的氮原子一起形成选自哌啶子基或吗啉代的杂环; R 4，R 5和R 6各自独立地表示氢，卤素，烷基，烷氧基，酰氨基，脲基或烷氧基氨基，R 5也可以表示氨基，烷基氨基，羟基烷基氨基或氨基甲酰基烷基氨基。 上述烷基和烷氧基可含有1至6个碳原子，酰基可含有2至7个碳原子。 本发明还涉及制备上述吲哚苯胺的方法和用于角蛋白纤维的染色组合物，特别是包含所述吲哚苯胺的活人的头发。

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