公开(公告)号：JPS61226619A

公开(公告)日：1986-10-08

申请号：JP6802785

申请日：1985-03-31

Applicant: SHIMADZU CORP

Inventor： AKIYAMA OSAMU

IPC: G01J3/02 ,  G01J3/42 ,  G01M11/02 ,  G01N21/01 ,  G01N21/47 ,  G01N21/59

Abstract: PURPOSE:To make possible the measurement of transmitted light with high accuracy even with a sample of an optional shape with which the luminous flux after the transmission thereof diverges, shifts or deflects or a sample having a light scattering characteristic by making exchangeable a reference light signal and sample light signal in a photometric circuit. CONSTITUTION:The photometric output of the luminous flux R is inputted from a switch Sw via a contact 1 to a comparator C in the case of connecting a manual change-over switch SC to the arrow shown by a solid line. The output is then compared with a reference level in a comparator C and the difference between both is inputted to a high-voltage generating circuit H. The high-voltage outputted from the H is fed back to a photodetector P and the sensitivity of the photodetector P is so controlled that the photometric signal of the flux R is made constant. On the other hand, the photometric output of the flux S is inputted from the switch Sw via a contact 2 to a signal processing circuit N. The sensitivity of the photodetector P is so controlled that the photometric output of the flux S is this time made constant when the switch SC is changed over to the connection state shown by a dotted line. The photometric output of the flux R is then inputted to the circuit N.

公开(公告)号：JPS60225043A

公开(公告)日：1985-11-09

申请号：JP8256884

申请日：1984-04-23

Applicant: SHIMADZU CORP

Inventor： AKIYAMA OSAMU ,  GOTOU SEIJI ,  KOIKE MASAHITO

IPC: G01M11/02

Abstract: PURPOSE:To attain to shorten a measuring time, by providing a means for forming specimen beam and reference beam both of which are respectively fine parallel beam and a detector part constituted of an integration shere. CONSTITUTION:Two beams formed by a beam splitter B are formed into specimen beam (s) and reference beam (r) parallel to each other by mirrors 21, 22. Both beams (s), (r) are converted to fine parallel beams (s), (r) through lenses 31, 32, irises 41, 42, collimator lenses 51, 52 and beam limit irises 61, 62. A guide G parallel to the beams (s), (r) is provided to a measuring part 15 and a detector part 14 is attached to the guide G in a slidable manner and the beam (s) is directly incident to an integration sphere 12 through an iris 11 while the beam (r) is incident thereto through a mirror 7, a lens 8 and a photomultiplier 13. In measurement, a lens 9 to be inspected held to a lens holder 10 so that the optical axis thereof is coincided with the beam (s) and the before and behind position of the detection part 14 is adjusted so as to form the image of the iris 41 by the lens 9 to be inspected onto the iris 11 in front of the specimen beam incident window of the integration sphere 12.

公开(公告)号：JPS5960229A

公开(公告)日：1984-04-06

申请号：JP17243282

申请日：1982-09-29

Applicant: Shimadzu Corp

Inventor： AKIYAMA OSAMU

IPC: G01J1/02 ,  G01N21/47

CPC classification number: G01N21/474

Abstract: PURPOSE:To perform two reflection measurements without changing the positions of a light source and a light detector, by providing four windows in the same plane including an optical axis in an integrating sphere, with one window as a light inputting window, another window as a light emitting window, and the remaining two windows as sample windows. CONSTITUTION:In an integrating sphere, four windows Wi, Wo, Ws1, and Ws2 are provided. In the case of Ro/d measurement, a sample S is placed at the window Ws1 facing the light inputting window Wi. A white plate Sw is placed on the other sample window Ws2. Then, the light, which is inputted from the light inputting window Wi, is directly inputted to the sample S in the vertical direction. The component of the light reflected by the mirror surface of the sample S is emitted out of the integrating sphere through the light inputting window Wi. Only the diffused component of the reflected light repeats the reflection in the integrating sphere and is inputted to a light detector D through the light emitting window Wo. In the case of Rd/o measurement, the white plate Sw is placed at the sample window Ws1, and the sample S is paced at the sample window Ws2 facing the light emitting window Wo.

Abstract translation: 目的：在不改变光源和光检测器的位置的情况下进行两次反射测量，通过在包括积分球中的光轴的同一平面中提供四个窗口，一个窗口作为光输入窗口，另一个窗口为 发光窗口，其余两个窗口作为示例窗口。 构成：在积分球中，提供了四个窗口Wi，Wo，Ws1和Ws2。 在Ro / d测量的情况下，将样本S放置在面向光输入窗口Wi的窗口Ws1处。 白板Sw放置在另一个样品窗口Ws2上。 然后，从光输入窗口Wi输入的光在垂直方向直接输入到样本S. 由样品S的镜面反射的光的分量通过光输入窗口Wi从积分球发射出去。 只有反射光的扩散分量重复积分球中的反射，并通过发光窗口Wo输入到光检测器D. 在Rd / o测量的情况下，将白色板Sw放置在采样窗口Ws1处，并且样品S在面向发光窗口Wo的采样窗口Ws2处摆动。

公开(公告)号：JPS58113821A

公开(公告)日：1983-07-06

申请号：JP21189281

申请日：1981-12-28

Applicant: SHIMADZU CORP

Inventor： AKIYAMA OSAMU

IPC: G01J1/02 ,  G01N21/25

Abstract: PURPOSE:To improve measuring sensitivity, by providing variable masks constituted by a substrate on which apertures having various shapes are provided in front of a light receiving surface of an end ON type photomultiplier. CONSTITUTION:Luminous flux I0 which is emitted from a spectroscope, is inputted into a sample cell C. The luminous flux Ii, which has passed the cell, is inputted into the light receiving surface of the photomulitplier. PM through a window W. The mask substrate B is contacted with the far side of a wall D so that it can be slidden and moved in the direction of arrows. On said substrate B, a light shielding part MS1 having no aperture and three kinds of apertures MS2, MS3, and MS4 are provided. The substrate B is moved in the directions of the arrows, any of the masks MS1-MS4 is positioned at the window W, and the four masks are switched and selected.

公开(公告)号：JPS57179719A

公开(公告)日：1982-11-05

申请号：JP6635781

申请日：1981-04-30

Applicant: SHIMADZU CORP

Inventor： AKIYAMA OSAMU ,  ICHIKAWA TETSUO ,  TSUNASAWA YOSHIO

IPC: G01J1/36 ,  G01J3/42

Abstract: PURPOSE:To widen a sample chamber and to reduce the distance between the sample and a photodetector by so arranging a titled meter that divided two luminous fluxes are intersected again at around 90 deg. angle and disposing one photodetector commonly for the two luminous fluxes near the point of intersection thereof. CONSTITUTION:The luminous flux emitted from a spectroscope is divided and the divided luminous fluxes are intersected again at around 90 deg.. One photodetector is disposed commonly for the two luminous fluxes near the point where the two luminous fluxes intersect. For example, the light out from a spectroscope M is divided to two luminous fluxes with a sector mirror S1; the reflected luminous flux is reflected by mirrors m3, m4, and the transmitted luminous flux is reflected by mirrors m1, m2. These two luminous fluxes are intersected orthogonally on the photodetection surface of a photomultiplier P. Further, two sheets of light diffusion plates D, D' are disposed orthogonally in front of the photodetection surface of the photomultiplier P so as to assure the equivalency of the two luminous fluxes.

公开(公告)号：JPS5756724A

公开(公告)日：1982-04-05

申请号：JP13195680

申请日：1980-09-22

Applicant: Shimadzu Corp

Inventor： AKIYAMA OSAMU

IPC: G01J3/443 ,  G01J1/02 ,  G01J3/44 ,  G01J3/50

CPC classification number: G01J3/4406 ,  G01J3/0251 ,  G01J3/502 ,  G01J3/524

Abstract: PURPOSE:To detect fluorescence surely by subtracting fluorescence intensity from the apparent reflected light intensity in the wavelength of lighting light of reflected light spectra and calculating a spectral reflected radiance factor and a spectral fluorescence radiance factor. CONSTITUTION:The device consits of a lighting spectroscope M1 and a reflection spectroscope M2. In the spectroscope M2, a multichannel photometric element D is disposed along the spectral image plane, and the operation of interpolating the fluorescence intensity at the wavelength of lighting light from the reflected light spectra of a sample Sm is accomplished at every wavelength in the wavelength scanning of the spectroscope M1. The interpolated fluorescence intensity is subtracted from the apparent reflected light intensity at the lighting light wavelength of the reflected light spectra in an arithmetic circuit. The fluorescence intensity is divided by the ratio of the wavelength width of the spectroscope M2 to the wave- length width of the spectroscope M1. An arithmetic circuit calculating a spectral reflection radiance factor and a spectral fluorescence radiance factor from these two is provided.

Abstract translation: 目的：通过从反射光谱的照明光的波长中的表观反射光强度减去荧光强度并计算光谱反射辐射系数和光谱荧光辐射系数来确定荧光检测的荧光。 构成：照明分光器M1和反射光谱仪M2的装置。 在分光镜M2中，沿着光谱图像平面设置多通道光度测定元件D，并且在波长扫描中的每个波长处实现从样品Sm的反射光谱在照明光的波长处内插荧光强度的操作 的分光仪M1。 从运算电路中反射光谱的发光光波长的表观反射光强度中减去内插荧光强度。 荧光强度除以分光镜M2的波长宽度与分光镜M1的波长宽度的比值。 提供了从这两个算出光谱反射辐射系数和光谱荧光辐射系数的运算电路。

公开(公告)号：JPS56145335A

公开(公告)日：1981-11-12

申请号：JP3674280

申请日：1980-03-22

Applicant: SHIMADZU CORP

Inventor： AKIYAMA OSAMU

IPC: G01N21/27 ,  G01N21/63

Abstract: PURPOSE:To enable employment of biface ground cell by conducting irradiation and incidence of an excitation light and a measurement light to a sample cell from one direction through the same light path. CONSTITUTION:When the light path is closed by choppers CH1 and CH2, a monochromatic exitation light flux having a fixed wavelength, shown by dotted lines, is reflected by the chopper CH1, irradiates a sample S from the front of the sample cell C1, is transmitted therethrough, promoting the photochemical reaction, and is reflected by the chopper CH2 and caught and absorbed by a trap Tr1 via reflecting mirror M2. When the light path is opened by the choppers CH1 and CH2 simultaneously, the monochromatic excitation light having the fixed wavelength is caught and absorbed by a trap Tr2 via reflecting mirror M3. On the other hand, a monochromatic measurement light flux having a specified wavelength, shown by a solid line, passed through the same light path, is made incident in the sample S from the front of the sample cell C1, transmitted therethrough, caught by a detector D, transduced into an absorptivity signal by a signal processing circuit, and thus the photochemical reaction of the sample S at that point of time is measured.

公开(公告)号：JP2009080017A

公开(公告)日：2009-04-16

申请号：JP2007249703

申请日：2007-09-26

Applicant: Shimadzu Corp ,  株式会社島津製作所

Inventor： AKIYAMA OSAMU

IPC: G01N21/05 ,  G01N21/03 ,  G01N21/61

Abstract: PROBLEM TO BE SOLVED: To provide a flow cell for a multiple reflection cell type gas analysis system, capable of easily compensating an effect of variation in curvature radius of Miller with no increase in cost, a multiple reflection cell type gas analysis system, and an adjustment method of a mirror-to-mirror distance of the flow cell. SOLUTION: The flow cell includes: a cylindrical cell body 5 having a sample gas inlet 15 and a sample gas outlet 16; a first mirror 2a located at a first termination section of the cell body 5, having a tunnel 4 through which incident light and emission light pass; a second mirror 6 located at a second termination section of the cell body 5, having a second mirror surface opposed a first mirror surface of the first mirror 2a; and spacer insertion units (11b, 12, 17b, 18) for inserting a spacer 13 between the second termination section and the second mirror 6 to adjust the distance between the first mirror 2a and the second mirror 6. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 解决问题：为了提供一种多反射型气体分析系统的流通池，能够容易地补偿米勒的曲率半径的变化的影响而不增加成本，多反射型气体分析系统 以及流动池的镜面到镜面距离的调整方法。 解决方案：流动池包括：具有样品气体入口15和样品气体出口16的圆柱形电池体5; 位于电池体5的第一端接部的第一反射镜2a，具有入射光和发射光通过的隧道4; 位于电池体5的第二终端部的第二反射镜6，具有与第一反射镜2a的第一反射镜面相对的第二镜面; 以及用于在第二终端部分和第二反射镜6之间插入间隔件13以调节第一反射镜2a和第二反射镜6之间的距离的间隔件插入单元（11b，12,17b，18）。 ）2009，JPO＆INPIT

公开(公告)号：JP2003130793A

公开(公告)日：2003-05-08

申请号：JP2001322715

申请日：2001-10-19

Applicant: SHIMADZU CORP ,  KINOSUI KENKYUSHO KK

Inventor： AKIYAMA OSAMU ,  AKAISHI KENICHI

IPC: G01N21/05 ,  A61L2/02 ,  C02F1/00 ,  G01N21/33

Abstract: PROBLEM TO BE SOLVED: To improve maintainability by highly accurately monitoring effective chlorine concentration in generated strongly acidic water even by intermittent measurements and extending the life of the monitoring apparatus by this. SOLUTION: When a predetermined time has elapsed, the operation of shear pumps 24 and 25 are restarted to start the operation of sucking strongly acidic water and strongly alkaline water generated by a strongly electrolytic water generator 11 and feeding them to a liquid tank 28 for mixing. After 15 minutes when the operation of the pumps 24 and 25 are stabilized, only the liquids fed by the pumps 24 and 25 in which the quantity of flow is stabilized remain in the liquid chamber 28 of an overflow chamber to stabilize its mixture ratio. Since effective chlorine concentration is measured through the use of the output of a spectroscope assembly 34 at this time, it is possible to highly accurately monitor the effective chlorine concentration even by intermittent measurements and extend the lives of the pumps 24-27 by this.

公开(公告)号：JP2003080254A

公开(公告)日：2003-03-18

申请号：JP2001271855

申请日：2001-09-07

Applicant: Shimadzu Corp ,  株式会社島津製作所

Inventor： AKIYAMA OSAMU

IPC: G01N33/18 ,  C02F1/46 ,  G01N21/33

Abstract: PROBLEM TO BE SOLVED: To provide an apparatus for producing electrolytic water in which concentration monitoring based on spectrophotometry can be achieved without influencing a measured result even when the output characteristics of a light source changes with long-time use.
SOLUTION: The electrolytic water sampled from the intake of an electrolysis vessel 11 is mixed and agitated by a second water tank 67 via a first water tank 61, and sent to the flow cell 31 of a measuring part 30a. Light from a light source 32 passes through an optical filter 34a, is selected as 292 nm wavelength and is reflected in part by a beamsplitter 33. Reflected light is used as control luminous flux, and light passing through the beamsplitter 33 passes through the sample of the flow cell 31 and is used as sample luminous flux. Signals from each photocell 36 and 37a are received by a data processing part 38a, corrected on the basis of the difference between the signals to detect absorbancy, and effective chlorine concentration is displayed on an output part 39.
COPYRIGHT: (C)2003,JPO

Abstract translation: 要解决的问题：提供一种生产电解水的装置，其中即使当光源的输出特性随着长时间的使用而改变时，也可以在不影响测量结果的情况下实现基于分光光度法的浓度监测。 解决方案：从电解容器11的入口取样的电解水通过第一水箱61由第二水箱67混合搅拌并送到测量部分30a的流动池31。 来自光源32的光通过滤光器34a，被选择为292nm波长，并且被分束器33部分地反射。反射光用作控制光通量，并且通过分束器33的光穿过分光镜33的样品 流动池31被用作样品光通量。 来自每个光电管36和37a的信号由数据处理部分38a接收，根据检测吸收率的信号之间的差异进行校正，并且有效氯浓度显示在输出部分39上。