公开(公告)号：CA974345A

公开(公告)日：1975-09-09

申请号：CA124724

申请日：1971-10-07

Applicant: SOLVAY

Inventor： REGINATO LUIGI ,  BIENFAIT CHARLES ,  STEVENS JACQUES

IPC: C08F4/64 ,  C08F4/68 ,  C08F10/00

公开(公告)号：CA968099A

公开(公告)日：1975-05-20

申请号：CA165905

申请日：1973-03-12

Applicant: SOLVAY

Inventor： REGINATO LUIGI ,  BIENFAIT CHARLES ,  STEVENS JACQUES

IPC: C08F4/00 ,  C08F4/42 ,  C08F4/60 ,  C08F4/62 ,  C08F10/00

公开(公告)号：CA946099A

公开(公告)日：1974-04-23

申请号：CA96348

申请日：1970-10-22

Applicant: SOLVAY

Inventor： STEVENS JACQUES ,  GEORGE MICHEL

IPC: C08F10/00

公开(公告)号：CA943525A

公开(公告)日：1974-03-12

申请号：CA72661

申请日：1970-01-20

Applicant: SOLVAY

Inventor： STEVENS JACQUES ,  GEORGE MICHEL

IPC: C08F4/42 ,  C08F4/64 ,  C08F4/68 ,  C08F10/00

公开(公告)号：GB1269067A

公开(公告)日：1972-03-29

申请号：GB3863569

申请日：1969-08-01

Applicant: SOLVAY

Inventor： STEVENS JACQUES ,  WEYNBERGH ROBERT VAN

IPC: C08F4/00 ,  C08F2/00 ,  C08F4/60 ,  C08F10/00

Abstract: 1,269,067. Product control in supported catalytic olefin polymerization. SOLVAY & CIE. 1 Aug., 1969 [26 Aug., 1968], No. 38635/69. Heading C3P. Olefin polymers with a broad molecular weight distribution (C D ) and a low melt index (M.I.) are obtained by polymerization in the presence of an organometallic compound-transition metal compound catalyst on an inert support, in which process C D is controlled by varying the hydrogen concentration from 20 to 50 gms. per kg. of olefin and the desired low M.I. is obtained by carrying out the polymerization at 40‹ to 65‹ C. and/or by using an agent for increasing molecular weight, e.g. an alcohol, ether or acid. In examples and comparative examples, ethylene is homo- or co-polymerized with butene-1 in the presence of (C 2 H 5 ) 3 Al or (i-C 4 H 9 ) 3 Al/TiCl 4 -MgO or hydromagnesite/H 2 , and optionally octanol.

公开(公告)号：CA884300A

公开(公告)日：1971-10-26

申请号：CA884300D

Applicant: SOLVAY

Inventor： DELBOUILLE ANDRE ,  GOBILLON YVES ,  STEVENS JACQUES