Abstract:
IMPROVED CATALYSTS FOR THE POLYMERIZATION OF OLEFINS WHICH COMPRISES AN ORGANOMETALLIC COMPOUND AND THE REACTION PRODUCED OF A LIQUID HALOGENATED DERIVATIVE OF A TRANSITION METAL AND A SOLID SUPPORT CONSITUTED BY AN OXIDE OF CALCIUM AND/OR MAGNESIUM ARE PROVIDED. THE SOLID SUPPORTS FOR THE IMPROVED CATALYSTS ARE OBTAINED BY THE HEAT TREATMENT OF AN OPTIONALLY HYDRATED, CARBONATE OR BASIC CARBONATE OF CALCIUM OR MAGNESIUM AT A TEMPERATURE BETWEEN 350 AND 1000*C.
Abstract:
OLEFINS ARE POLYMERIZED AND COPOLYMERIZED BY BEING CONTACTED WITH A CATALYST OF THE FOLLOWING COMPONENTS: (A) A GROUP IV, V OR VI METAL OR A HYDRIDE OR AN ORGANOMETALLIC COMPOUND THEREOF; (B) AN ALKOXY HALIDE OF TITANIUM, ZIRCONIUM OR VANADIUM AND (C) A HALIDE OF A GROUP III OR V ELEMENT. THERE CANTHUS BE OBTAINED POLYOLEFINS WHICH ARE MORE LINEAR AND CRYSTALLINE THAN THOSE OF THE PRIOR ART.
Abstract:
A method of polymerizing and copolymerizing olefins with a novel catalyst comprising (a) the reaction product of an inorganic compound of a polyvalent metal having a valence of at least three, e.g., TiC14, and a solid, bivalent metal hydroxylated inorganic phosphate, e.g., Ca5(PO4)3OH, or hydroxychloride, e.g., Mg(OH)C1, (b) a metal, a hydride, or an organometallic compound of metals of Groups IVB , VB and VIB, e.g., Sn(C4H9)4, and (c) a Group IIIB or VB halide, e.g., A1C13.