公开(公告)号：FI791285A

公开(公告)日：1979-10-22

申请号：FI791285

申请日：1979-04-19

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ

IPC: B01J27/18 ,  B01J23/24 ,  B01J23/31 ,  B01J23/34 ,  B01J23/54 ,  B01J23/835 ,  B01J23/85 ,  B01J23/89 ,  B01J27/057 ,  B01J27/186 ,  B01J27/188 ,  B01J35/00 ,  C07C45/35 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J

公开(公告)号：PT69523A

公开(公告)日：1979-05-01

申请号：PT6952379

申请日：1979-04-20

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ

IPC: B01J27/18 ,  B01J23/24 ,  B01J23/31 ,  B01J23/34 ,  B01J23/54 ,  B01J23/835 ,  B01J23/85 ,  B01J23/89 ,  B01J27/057 ,  B01J27/186 ,  B01J27/188 ,  B01J35/00 ,  C07C45/35 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J

公开(公告)号：NO782715L

公开(公告)日：1979-02-13

申请号：NO782715

申请日：1978-08-09

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  SURESH DEV DHANARAJ ,  GRASSELLI ROBERT KARL

IPC: B01J23/24 ,  B01J23/31 ,  B01J23/88 ,  B01J27/057 ,  B01J27/192 ,  B01J35/00 ,  B01J37/02 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  B01J

Abstract: Process for forming multi-component oxide catalysts. According to the invention the key catalytic phase of the catalyst is preformed and the elements of the host-catalyst phase are added together or separately. The key catalytic phase contains a molybdate or a tungstate of Bi, Te, Sb, Sn Cu or mixtures thereof. A representative catalyst is 50% [Bi2Mo3O12] 1/2 [K0.1Ni2.5Co4.5Fe3P0.5Mo10.5 Ox] + 50% SiO2 In the production of this catalyst a preformed bismuth molybdate slurry is added to a host-catalyst slurry. The mixture was then dried, calcined, ground and calcined once again.

公开(公告)号：FI782425A

公开(公告)日：1979-02-11

申请号：FI782425

申请日：1978-08-08

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  SURESH DEV DHANARAJ ,  GRASSELLI ROBERT KARL

IPC: B01J23/24 ,  B01J23/31 ,  B01J23/88 ,  B01J27/057 ,  B01J27/192 ,  B01J35/00 ,  B01J37/02 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  B01J

Abstract: Process for forming multi-component oxide catalysts. According to the invention the key catalytic phase of the catalyst is preformed and the elements of the host-catalyst phase are added together or separately. The key catalytic phase contains a molybdate or a tungstate of Bi, Te, Sb, Sn Cu or mixtures thereof. A representative catalyst is 50% [Bi2Mo3O12] 1/2 [K0.1Ni2.5Co4.5Fe3P0.5Mo10.5 Ox] + 50% SiO2 In the production of this catalyst a preformed bismuth molybdate slurry is added to a host-catalyst slurry. The mixture was then dried, calcined, ground and calcined once again.

公开(公告)号：DE69512292T2

公开(公告)日：2000-01-05

申请号：DE69512292

申请日：1995-03-13

Applicant: STANDARD OIL CO OHIO

Inventor： BARTEK JOSEPH P ,  BRAZDIL JAMES FRANK

IPC: B01J23/18 ,  B01J23/22 ,  B01J37/02 ,  C07C253/24

公开(公告)号：ES2137453T3

公开(公告)日：1999-12-16

申请号：ES95301698

申请日：1995-03-13

Applicant: STANDARD OIL CO OHIO

Inventor： BARTEK JOSEPH P ,  BRAZDIL JAMES FRANK

IPC: B01J23/18 ,  B01J23/22 ,  B01J37/02 ,  C07C253/24

公开(公告)号：DE69512292D1

公开(公告)日：1999-10-28

申请号：DE69512292

申请日：1995-03-13

Applicant: STANDARD OIL CO OHIO

Inventor： BARTEK JOSEPH P ,  BRAZDIL JAMES FRANK

IPC: B01J23/18 ,  B01J23/22 ,  B01J37/02 ,  C07C253/24

公开(公告)号：DE69102258D1

公开(公告)日：1994-07-07

申请号：DE69102258

申请日：1991-11-26

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  LYNCH CHARLES STAFFORD ,  GLAESER LINDA CLAIRE ,  TOFT MARK ANTHONY

IPC: B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/34 ,  B01J23/843 ,  B01J23/847 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C253/24 ,  C07C255/08

Abstract: Disclosed is a process for making an activated antimony and vanadium-containing catalyst in oxide form having an atomic ratio of Sb:V in the range from 0.8-4, which comprises calcining such an oxidic vanadium and antimony-containing composition at a temperature of over 750 DEG C, and thereafter contacting said calcined catalyst with a hydroxy compound in liquid form selected from (1) cyclohexanol, (2) cyclopentanol, (3) a monohydroxy, acyclic hydrocarbon having 1-8 C atoms, and (4) a dihydroxy, acyclic hydrocarbon having 2-4 carbon atoms, and separating as a liquid said compound from said catalyst insofar as it is present beyond the amount wetting said catalyst, and thereafter drying said catalyst.

公开(公告)号：MX9102713A

公开(公告)日：1994-04-29

申请号：MX9102713

申请日：1991-12-19

Applicant: STANDARD OIL CO OHIO

Inventor： TOFT MARK ANTHONY ,  LYNCH CHARLES STAFFORD ,  GLAESER LINDA CLAIRE ,  BRAZDIL JAMES FRANK

IPC: B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/34 ,  B01J23/843 ,  B01J23/847 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C253/24 ,  C07C255/08 ,  C08F4/20

Abstract: Disclosed is a process for making an activated antimony and vanadium-containing catalyst in oxide form having an atomic ratio of Sb:V in the range from 0.8-4, which comprises calcining such an oxidic vanadium and antimony-containing composition at a temperature of over 750 DEG C, and thereafter contacting said calcined catalyst with a hydroxy compound in liquid form selected from (1) cyclohexanol, (2) cyclopentanol, (3) a monohydroxy, acyclic hydrocarbon having 1-8 C atoms, and (4) a dihydroxy, acyclic hydrocarbon having 2-4 carbon atoms, and separating as a liquid said compound from said catalyst insofar as it is present beyond the amount wetting said catalyst, and thereafter drying said catalyst.

公开(公告)号：DE3882075T2

公开(公告)日：1993-11-11

申请号：DE3882075

申请日：1988-04-14

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  TOFT MARK ANTHONY ,  GLAESER LINDA CLAIRE

IPC: B01J23/22 ,  B01J23/24 ,  B01J23/84 ,  B01J23/847 ,  B01J23/86 ,  B01J23/88 ,  B01J27/057 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08 ,  B01J23/28

Abstract: Ammoxidation of C3 to C5 paraffins with NH3 and O2 using (1) a mole ratio of paraffin:NH3 in the range from 2 to 16 and a mole ratio of alkane:O2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.