公开(公告)号：NO783835L

公开(公告)日：1978-04-20

申请号：NO783835

申请日：1978-11-15

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES FERGUSON ,  SHAW WILFRID GARSIDE ,  APPLEQUIST MICHAEL DUANE

IPC: B01J23/28 ,  B01J23/54 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/19 ,  B01J27/198 ,  B01J27/199 ,  B01J27/24 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07C67/00 ,  C07C

公开(公告)号：NO773569L

公开(公告)日：1978-04-20

申请号：NO773569

申请日：1977-10-18

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES FERGUSON ,  SHAW WILFRID GARSIDE

IPC: C07C57/04 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C

Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.

公开(公告)号：DE2654188A1

公开(公告)日：1977-07-14

申请号：DE2654188

申请日：1976-11-30

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/18 ,  B01J23/22 ,  B01J23/28 ,  B01J23/887 ,  B01J37/02 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

Abstract: A process for obtaining acrylic acid or methacrylic acid from acrolein or methacrolein, respectively, comprising the steps of mixing the aldehyde, molecular oxygen and water vapor in a molar ratio within the range of 1/0.5-5/0-20, respectively; contacting said mixture with a catalyst at a temperature of about 200º to 500º c, said catalyst having a composition represented by the empirical formula ** (formula) ** wherein x is a metal selected from the group consisting of antimony and germanium, or both, and where a is a number from 6 to about 18, b, c and d are, individually, from about 0.1 to about 6, and e is the number of oxygen atoms required to meet the valence requirements of the other metals present; and recover the unsaturated acid. (Machine-translation by Google Translate, not legally binding)

公开(公告)号：MX9202957A

公开(公告)日：1994-01-31

申请号：MX9202957

申请日：1992-06-17

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE

IPC: C08F10/06

公开(公告)号：BR9202497A

公开(公告)日：1994-01-18

申请号：BR9202497

申请日：1992-07-07

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/192 ,  B01J27/199 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：AT54133T

公开(公告)日：1990-07-15

申请号：AT86302818

申请日：1986-04-16

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE ,  CALLAHAN JAMES LOUIS

IPC: C07B61/00 ,  B01J23/00 ,  B01J27/00 ,  C07C67/39 ,  C07C69/54

公开(公告)号：DE3481705D1

公开(公告)日：1990-04-26

申请号：DE3481705

申请日：1984-12-10

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE

IPC: B01J23/00 ,  B01J23/28 ,  B01J23/887 ,  C07C47/00 ,  C07C47/07 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04 ,  C07C53/08

Abstract: A vapor phase catalytic process for making acrylic acid from acrolein by oxidation thereof with molecular oxygen, optionally in the presence of steam. A new catalyst comprising a complex oxide catalyst of Mo, V and Zr.

公开(公告)号：MX159633A

公开(公告)日：1989-07-20

申请号：MX18796281

申请日：1981-06-24

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  KUCH PHILIP LAWRENCE ,  PAPARIZOS CHRISTOS

IPC: C07C57/055 ,  B01J23/76 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00 ,  B01J27/14 ,  C07C121/32

Abstract: Compositions of the empirical formula: Mo12P0.1-3M0.1-3Cu0.1-2V0.1-2X0.01-2YaOb (I) where M is at least one of K, Rb and Cs; X is at least one of Ba, La, Ga, Al, Ag, Cd, Ti, Tl, Hg, Pb and Zn; Y is at least one of Fe, Co, Ni, Sr, Mn, In, Ta, Ge, S and Be when a>0; a is a number of 0 to about 2; and b is a number that satisfies the valence requirements of the other elements present, are excellent catalysts for the oxidation of methacrolein to methacrylic acid.

公开(公告)号：FI62959C

公开(公告)日：1983-04-11

申请号：FI257074

申请日：1974-09-03

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: C07C27/14 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  B01J27/198 ,  B01J27/199 ,  C07B35/04 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/20 ,  C07C47/22 ,  C07C51/25 ,  C07C57/05 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/84

Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.

公开(公告)号：AT363913B

公开(公告)日：1981-09-10

申请号：AT388279

申请日：1979-05-28

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY ,  MILBERGER ERNEST CARL ,  WOODBURY DAVID ROY ,  DOLHYJ SERGE ROMAN

IPC: B01J23/30