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公开(公告)号:CA1273826A
公开(公告)日:1990-09-11
申请号:CA503788
申请日:1986-03-11
Applicant: STANDARD OIL CO OHIO
Inventor: GRASSELLI ROBERT K , TENHOVER MICHAEL A , HARRIS JONATHAN H
IPC: C22C38/00 , B22F9/00 , C01B3/00 , C22C5/00 , C22C14/00 , C22C19/00 , C22C45/02 , C22C45/10 , C22C45/00 , B22F7/00
Abstract: Novel materials having the ability of reversible store hydrogen are amorphous metal alloy of the formula AaMbM'c wherein A is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt; M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; and M' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; and wherein a ranges from greater than zero to about 0.80; b ranges from zero to about 0.70; and c ranges from about 0.08 to about 0.95; characterized in that 1) a substantial portion of A is disposed on the surface of said material and/or 2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
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公开(公告)号:DE3671476D1
公开(公告)日:1990-06-28
申请号:DE3671476
申请日:1986-07-14
Applicant: STANDARD OIL CO OHIO
Inventor: HENDERSON RICHARD S , TENHOVER MICHAEL A , SHREVE GARY A
Abstract: Amorphous chromium-metalloid alloys exhibiting corrosion resistance in acid environments are described. The alloys contain a relatively low amount of a metalloid selected from the group of B, C, P, N, S, Sb and As. Additional metalloid elements such as Al, Si and Ge may also be present to enhance other properties of the amorphous alloy.
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公开(公告)号:PH23655A
公开(公告)日:1989-09-27
申请号:PH33577
申请日:1986-03-25
Applicant: STANDARD OIL CO OHIO
Inventor: HENDERSON RICHARD S , TENHOVER MICHAEL A , GRASSEILLI ROBERT K , HARRIS JONATHAN H
Abstract: Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formula A8MbM min c wherein A is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt; M is at least one element selected from the group consisting of: Ru, Pb, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; and M min is at least one element selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; and wherein a ranges from about 0.005 to about 0.80; b ranges from about 0.05 to about 0.70; and c ranges from about 0.08 to about 0.95.
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公开(公告)号:HK64189A
公开(公告)日:1989-08-18
申请号:HK64189
申请日:1989-08-10
Applicant: STANDARD OIL CO OHIO
Inventor: HENDERSON RICHARD S , TENHOVER MICHAEL A , GRASSELLI ROBERT K , HARRIS JONATHAN H
Abstract: Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formula A8MbM min c wherein A is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt; M is at least one element selected from the group consisting of: Ru, Pb, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; and M min is at least one element selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; and wherein a ranges from about 0.005 to about 0.80; b ranges from about 0.05 to about 0.70; and c ranges from about 0.08 to about 0.95.
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35.
公开(公告)号:CA1233047A
公开(公告)日:1988-02-23
申请号:CA475705
申请日:1985-03-04
Applicant: STANDARD OIL CO OHIO
Inventor: TENHOVER MICHAEL A , HENDERSON RICHARD S , GRASSELLI ROBERT K
Abstract: Amorphous metal alloy powders are synthesized by solid state decomposition reactions. At least one precursor compound is thermally decomposed at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The decomposition product comprises an intimate mixture of the elements of the alloy and, after heat-treating if necessary, exhibits amorphous characteristics. Amorphous metal alloy shapes are synthesized by providing an intimate mixture of the components of the amorphous alloy, which mixture includes at least one ductile component. The mixture may be subjected to well-known forming techniques at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The ductile component of the mixture acts as a binder matrix to provide strength and uniform properties to the formed object.
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公开(公告)号:ZA8604911B
公开(公告)日:1987-03-25
申请号:ZA8604911
申请日:1986-07-02
Applicant: STANDARD OIL CO OHIO
Inventor: TENHOVER MICHAEL A , HENDERSON RICHARD S , GRASSELLI ROBERT K
IPC: C22C38/48 , C22C1/00 , C22C45/00 , C22C45/04 , C23C16/06 , C23C16/08 , C23C16/16 , C23C16/30 , C21D
CPC classification number: C23C16/30 , C23C16/06 , Y10T428/12576 , Y10T428/12903 , Y10T428/12944 , Y10T428/12951 , Y10T428/31678
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公开(公告)号:BR8603100A
公开(公告)日:1987-02-17
申请号:BR8603100
申请日:1986-07-02
Applicant: STANDARD OIL CO OHIO
Inventor: TENHOVER MICHAEL A , HENDERSON RICHARD S , GRASSELLI ROBERT K
IPC: C22C38/48 , C22C1/00 , C22C45/00 , C22C45/04 , C23C16/06 , C23C16/08 , C23C16/16 , C23C16/30 , C23C16/18 , C23C28/02
Abstract: A process is disclosed for the formation of amorphous multimetallic alloy coatings. More specifically, a chemical vapor deposition process is described wherein precursor compounds are induced to decompose upon a substrate under controlled parameters so as to form a coating on the substrate that is a substantially amorphous multi-metallic alloy. Preferred amorphous alloy compositions are also taught that are ideally synthesized by the claimed process.
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公开(公告)号:BR8602909A
公开(公告)日:1987-02-17
申请号:BR8602909
申请日:1986-06-24
Applicant: STANDARD OIL CO OHIO
Inventor: TENHOVER MICHAEL A , HENDERSON RICHARD S , HARRIS JONATHAN H , GRASSELLI ROBERT K
Abstract: Amorphous metal alloys having the formula M¹ a M² b M³ c whereM¹ is Fe, Co, Ni, Pd and combinations thereof;M² is Ti, Zr, Hf, V, Nb, Ta and combinations thereof;M³ is Rh, Os, Ir, Pt and combinations thereof;a ranges from about 0 to 60;b ranges from 10 to 70; andc ranges from about 5 to 70, with the proviso that a + b + c = 100.These alloys have utility as anodes in electrolytic processes and a process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having an amorphous metal alloy anode of the formula M¹ a M² b M³ c .
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公开(公告)号:AU5946086A
公开(公告)日:1987-01-22
申请号:AU5946086
申请日:1986-07-01
Applicant: STANDARD OIL CO OHIO
Inventor: HENDERSON RICHARD S , TENHOVER MICHAEL A , GRASSELLI ROBERT K
Abstract: An amorphous metal alloy composition exhibiting corrosion resistance in acidic environments of the formula:wherein M is at least one metal selected from the group consisting of Mo, W, Nb and Ta;R is at least one element selected from the group consisting of N, P As, S and Se; and wherein a ranges from about greater than 0.4 to about 0.6;b ranges from about 0.15 to about less than 0.4; andc ranges from zero to about 0.16.d ranges from zero to about 0.2; ande ranges from zero to about 0.3; with the proviso that the sum of (c + d + el ranges from about 0.04 to about 0.35.
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公开(公告)号:AU5949586A
公开(公告)日:1987-01-08
申请号:AU5949586
申请日:1986-07-02
Applicant: STANDARD OIL CO OHIO
Inventor: TENHOVER MICHAEL A , HENDERSON RICHARD S , GRASSELLI ROBERT K
IPC: C22C38/48 , C22C1/00 , C22C45/00 , C22C45/04 , C23C16/06 , C23C16/08 , C23C16/16 , C23C16/30 , C23C16/18 , C22C38/58 , C22C38/00 , C22C38/22 , C22C30/00 , C22C27/00 , C22C27/06 , C22C22/00 , C22C19/00
Abstract: A process is disclosed for the formation of amorphous multimetallic alloy coatings. More specifically, a chemical vapor deposition process is described wherein precursor compounds are induced to decompose upon a substrate under controlled parameters so as to form a coating on the substrate that is a substantially amorphous multi-metallic alloy. Preferred amorphous alloy compositions are also taught that are ideally synthesized by the claimed process.
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