公开(公告)号：EP2831203A4

公开(公告)日：2015-10-21

申请号：EP13768610

申请日：2013-03-01

Applicant: UOP LLC

Inventor： BAIRD LANCE A ,  BRANDVOLD TIMOTHY A

IPC: C10G25/02 ,  B01J39/04 ,  B01J39/20 ,  B01J49/00 ,  C10G1/00 ,  C10G3/00 ,  C10G25/05 ,  C10G25/12

CPC classification number: B01J39/043 ,  B01J39/05 ,  B01J39/20 ,  B01J49/06 ,  B01J49/53 ,  B01J49/60 ,  C10B53/02 ,  C10G1/002 ,  C10G3/50 ,  C10G25/05 ,  C10G25/12 ,  Y02E50/14 ,  Y02P20/145 ,  Y02P30/20

公开(公告)号：WO2013015908A3

公开(公告)日：2013-08-08

申请号：PCT/US2012043046

申请日：2012-06-19

Applicant: UOP LLC ,  BRANDVOLD TIMOTHY A ,  KOCH MARK

Inventor： BRANDVOLD TIMOTHY A ,  KOCH MARK

IPC: C10L1/32 ,  C10G3/00

CPC classification number: C10G1/065 ,  B01J8/22 ,  B01J21/12 ,  B01J23/888 ,  B01J37/20 ,  B01J2208/00283 ,  C10G1/083 ,  C10G1/086 ,  C10G2300/1014 ,  C10G2300/1096 ,  C10G2300/44 ,  C10G2400/30 ,  Y02P30/20

Abstract: Embodiments of methods and apparatuses for producing and aromatic hydrocarbon-rich effluent from a lignocellulosic material are provided herein. The method comprises the step of combining the lignocellulosic material and an aromatic hydrocarbon-rich diluent to form a slurry. Hydrogen in the presence of a catalyst is contacted with the slurry at reaction conditions to form the aromatic hydrocarbon-rich effluent.

Abstract translation: 本文提供了用于从木质纤维素材料生产和富含芳烃的流出物的方法和设备的实施方案。 该方法包括将木质纤维素材料和富含芳烃的稀释剂组合以形成浆料的步骤。 在催化剂存在下使氢在反应条件下与淤浆接触以形成富含芳烃的流出物。

公开(公告)号：WO2013019328A3

公开(公告)日：2013-06-13

申请号：PCT/US2012043066

申请日：2012-06-19

Applicant: UOP LLC ,  KOCAL JOSEPH A ,  BRANDVOLD TIMOTHY A

Inventor： KOCAL JOSEPH A ,  BRANDVOLD TIMOTHY A

IPC: C11B1/04 ,  C11B1/10 ,  C11B1/12

CPC classification number: C10K1/00 ,  B01J23/007 ,  B01J23/02 ,  B01J29/082 ,  C10B49/22 ,  C10B53/02 ,  C10B57/06 ,  C10B57/18 ,  C10C5/00 ,  C10G2300/1014 ,  C10K1/34 ,  C10K3/026 ,  Y02E50/14 ,  Y02P30/20

Abstract: Processes for producing reduced acid lignocellulosic-derived pyrolysis oil are provided. In a process, lignocellulosic material is fed to a heating zone. A basic solid catalyst is delivered to the heating zone. The lignocellulosic material is pyrolyzed in the presence of the basic solid catalyst in the heating zone to create pyrolysis gases. The oxygen in the pyrolysis gases is catalytically converted to separable species in the heating zone. The pyrolysis gases are removed from the heating zone and are liquefied to form the reduced acid lignocellulosic-derived pyrolysis oil.

Abstract translation: 提供了生产还原酸木质纤维素衍生的热解油的方法。 在一个过程中，木质纤维素材料被送入加热区。 碱性固体催化剂被输送到加热区。 木质纤维素材料在碱性固体催化剂存在下在加热区中被热解以产生热解气体。 热解气体中的氧在加热区中催化转化成可分离的物质。 将热解气体从加热区中除去并液化以形成还原的酸木质纤维素衍生的热解油。

公开(公告)号：WO2011087676A2

公开(公告)日：2011-07-21

申请号：PCT/US2010060403

申请日：2010-12-15

Applicant: UOP LLC ,  BRANDVOLD TIMOTHY A

Inventor： BRANDVOLD TIMOTHY A

CPC classification number: C07C7/12 ,  B01J39/05 ,  B01J49/60 ,  C10G25/02 ,  C10G2300/1011 ,  C10G2300/205 ,  C10G2300/4018 ,  C10G2300/44 ,  Y02E50/32 ,  Y02P30/20

Abstract: Low metal biomass-derived pyrolysis oils and processes for producing the same are provided. Low metal biomass-derived pyrolysis oil is produced by a process of contacting metal-containing biomass-derived pyrolysis oil with an acidic ion-exchange resin having sulfonic acid groups. Low metal biomass-derived pyrolysis oil is removed from spent acidic ion-exchange resin after ion-exchange.

Abstract translation: 提供了低金属生物质衍生的热解油及其制备方法。 通过使含金属的生物质衍生的热解油与具有磺酸基的酸性离子交换树脂接触的方法制备低金属生物质衍生的热解油。 离子交换后从废酸性离子交换树脂中除去低金属生物质衍生的裂解油。

公开(公告)号：WO2009151692A3

公开(公告)日：2010-04-01

申请号：PCT/US2009037072

申请日：2009-03-13

Applicant: UOP LLC ,  ANUMAKONDA AMARENDRA ,  MCCALL MICHAEL J ,  BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

Inventor： ANUMAKONDA AMARENDRA ,  MCCALL MICHAEL J ,  BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

IPC: C10G67/02 ,  C10G5/00 ,  C10L1/08

CPC classification number: C10G45/58 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/062 ,  C10G3/42 ,  C10G3/50 ,  C10G3/52 ,  C10G45/64 ,  C10G45/72 ,  C10G47/00 ,  C10G47/36 ,  C10G65/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

Abstract: A process for controlling the concurrent production of both diesel range hydrocarbons and aviation range hydrocarbons from renewable feedstocks such as plant oils and animal oils. The process involves determining the required specification of the desired products and the desired relative yields of the product that still meet the required specifications. The necessary isomerization and selective hydrocracking zone conditions are determined in order to create a mixture of paraffins which meet the required product specifications and yields. The necessary fractionation zone conditions are determined to separate the desired products. A renewable feedstock (2) is treated by hydrogenating and deoxygenating (4) to provide an effluent (6) comprising paraffins, isomerizing and selectively hydrogenating (22) at least a portion of the paraffins at the predetermined conditions, and separating by fractionation (42) at the predetermined fractionation conditions to generate a diesel range hydrocarbon product (46) and an aviation range hydrocarbon product (45).

Abstract translation: 控制从可再生原料如植物油和动物油同时生产柴油范围碳氢化合物和航空范围烃的过程。 该过程包括确定所需产品的所需规格以及仍符合要求规格的产品所需的相对产量。 确定所需的异构化和选择性加氢裂化区条件以产生满足所需产物规格和产率的石蜡混合物。 确定所需的分馏区条件以分离所需的产物。 通过氢化和脱氧（4）处理可再生原料（4）以提供包含链烷烃的异构化和选择性氢化（22）至少一部分链烷烃的预定条件的流出物（6），并通过分馏（42 ），以产生柴油范围烃产物（46）和航空范围烃产物（45）。

公开(公告)号：WO2007073533A3

公开(公告)日：2007-11-08

申请号：PCT/US2006061832

申请日：2006-12-11

Applicant: UOP LLC ,  CHEN WENSHENG ,  BRANDVOLD TIMOTHY A ,  BRICKER MAUREEN L ,  KOCAL JOSEPH A ,  WALENGA JOEL T

Inventor： CHEN WENSHENG ,  BRANDVOLD TIMOTHY A ,  BRICKER MAUREEN L ,  KOCAL JOSEPH A ,  WALENGA JOEL T

IPC: C07C29/03

CPC classification number: C07C29/095 ,  C07C67/035 ,  C07C69/63 ,  C07C31/04

Abstract: A process for converting methane to methanol using a homogeneous catalyst has been developed. The catalyst is a metal compound having an empirical formula of M x X m where M is a metal such as Pd, Cu, Co, and Mn, X is an anion such as acetate, trifluoroacetate, sulfate, propionate, "m" is the oxidation state of M, and "x" is the anion valence of X. Generally the process involves contacting a gas stream containing methane with the homogeneous catalyst and an oxidant such as hydrogen peroxide at oxidation conditions to produce methyl trifluoroacetate. Finally, the methyl trifluoroacetate is hydrolyzed to give a methanol product stream.

Abstract translation: 已经开发了使用均相催化剂将甲烷转化为甲醇的方法。 催化剂是具有经验式M x SUB x m M的金属化合物，其中M是金属如Pd，Cu，Co和Mn，X是阴离子等 作为乙酸盐，三氟乙酸盐，硫酸盐，丙酸盐，“m”是M的氧化态，“x”是X的阴离子化合价。通常该方法包括使含有甲烷的气流与均相催化剂和氧化剂如氢气 过氧化物在氧化条件下反应生成三氟乙酸甲酯。 最后，将三氟乙酸甲酯水解，得到甲醇产物流。

公开(公告)号：WO2012173748A3

公开(公告)日：2013-05-23

申请号：PCT/US2012038955

申请日：2012-05-22

Applicant: UOP LLC ,  FREY STANLEY JOSEPH ,  GATTUPALLLI RAJESWAR ,  BRANDVOLD TIMOTHY A

Inventor： FREY STANLEY JOSEPH ,  GATTUPALLLI RAJESWAR ,  BRANDVOLD TIMOTHY A

IPC: C10G31/09 ,  B01D15/08 ,  C10G3/00

CPC classification number: C10L1/02 ,  B01J39/05 ,  B01J49/53 ,  C10B53/02 ,  C10G25/02 ,  C10G25/12 ,  C10G31/09 ,  C10G53/08 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/205 ,  Y02E50/14 ,  Y02E50/32 ,  Y02P30/20

Abstract: Embodiments of methods and apparatuses for forming a low-metal biomass-derived pyrolysis oil are provided. The method comprises the steps of filtering a biomass-derived pyrolysis oil with a high flux rate filter arrangement having a flux rate of 10 L/m2/hr or greater to form a low-solids biomass-derived pyrolysis oil. The low-solids biomass-derived pyrolysis oil is filtered with a fine filter arrangement having a pore diameter of 50 µm or less to form an ultralow-solids biomass-derived pyrolysis oil. The ultralow-solids biomass-derived pyrolysis oil is contacted with an ion-exchange resin to remove metal ions and form the low-metal biomass-derived pyrolysis oil.

Abstract translation: 提供了用于形成低金属生物质衍生的热解油的方法和装置的实施例。 该方法包括以通量为10L / m 2 /小时或更高流量的高通量速率过滤装置过滤来自生物质的热解油的步骤，以形成低固体生物质衍生的裂解油。 低固体生物质衍生的热解油用细孔直径为50μm或更小的精细过滤装置过滤以形成超低固体生物质衍生的热解油。 将超低固体生物质衍生的热解油与离子交换树脂接触以除去金属离子并形成低金属生物质衍生的裂解油。

公开(公告)号：WO2012018520A3

公开(公告)日：2012-05-10

申请号：PCT/US2011044498

申请日：2011-07-19

Applicant: UOP LLC ,  TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A ,  ABRAHAMIAN JENNIFER F

Inventor： TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A ,  ABRAHAMIAN JENNIFER F

IPC: C10G45/04 ,  C10G3/00 ,  C10G45/08 ,  C10G45/10 ,  C10L1/02

CPC classification number: C10L1/02 ,  C10L1/04 ,  Y02P30/20

Abstract: Methods for deoxygenating treated biomass-derived pyrolysis oil are provided. The treated biomass-derived pyrolysis oil is exposed to a catalyst having a neutral catalyst support such as a non-alumina metal oxide support, a theta alumina support, or both. The non-alumina metal oxide support may be a titanium oxide (TiO2) support, a silicon oxide support, a zirconia oxide (ZrO2) support, a niobium oxide (Nb2O5) support, or a support having a mixture of non-alumina metal oxides. The catalyst may include a noble metal or a Group VIII non-noble metal and a Group VIB non-noble metal on the neutral catalyst support. The treated biomass-derived pyrolysis oil is introduced into a hydroprocessing reactor in the presence of the catalyst under hydroprocessing conditions to produce low oxygen biomass-derived pyrolysis oil.

Abstract translation: 提供了用于使经处理的生物质衍生的热解油脱氧的方法。 将经处理的生物质衍生的热解油暴露于具有中性催化剂载体（例如非氧化铝金属氧化物载体，θ氧化铝载体或两者）的催化剂。 非氧化铝金属氧化物载体可以是氧化钛（TiO 2）载体，氧化硅载体，氧化锆（ZrO 2）载体，氧化铌（Nb 2 O 5）载体或具有非氧化铝金属氧化物混合物的载体 。 催化剂可以在中性催化剂载体上包含贵金属或第VIII族非贵金属和第VIB族非贵金属。 处理的生物质衍生的热解油在加氢处理条件下在催化剂存在下加入加氢处理反应器中以产生低氧生物质衍生的热解油。

公开(公告)号：WO2011126817A3

公开(公告)日：2012-03-01

申请号：PCT/US2011030259

申请日：2011-03-29

Applicant: UOP LLC ,  MARKER TERRY L ,  BRANDVOLD TIMOTHY A ,  LUEBKE CHARLES P

Inventor： MARKER TERRY L ,  BRANDVOLD TIMOTHY A ,  LUEBKE CHARLES P

IPC: C10G45/60 ,  B01J23/38 ,  B01J23/755 ,  C10G3/00

CPC classification number: C10G3/46 ,  C10G3/00 ,  C10G45/00 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/802 ,  C10L1/04 ,  Y02P30/20

Abstract: The present invention involves a process for processing an acidic biorenewable feedstock comprising olefins, in which the acidic biorenewable feedstock is diluted with a deoxygenated feed to produce a diluted biorenewable feedstock and then is sent through a guard bed comprising a hydroprocessing catalyst to cause the olefins to be saturated with hydrogen and thereby to produce a treated biorenewable feedstock. This treated biorenewable feedstock can then be treated under standard hydroprocessing condition to produce an upgraded feedstock for transportation fuels.

Abstract translation: 本发明涉及一种用于处理包含烯烃的酸性生物可再生原料的方法，其中酸性生物可再生原料用脱氧原料稀释以产生稀释的生物可再生原料，然后通过包含加氢处理催化剂的保护床，使烯烃 用氢饱和，从而产生经处理的生物可再生原料。 然后可以在标准加氢处理条件下处理经处理的生物可再生原料，以生产用于运输燃料的升级原料。

公开(公告)号：WO2011087667A3

公开(公告)日：2011-11-17

申请号：PCT/US2010060265

申请日：2010-12-14

Applicant: UOP LLC ,  FREY STANLEY J ,  MARINANGELI RICHARD E ,  BRANDVOLD TIMOTHY A ,  KOCH MARK B ,  ABRAHAMIAN VASKEN B ,  NOGA JEFFREY M ,  TRAYNOR THOMAS J

Inventor： FREY STANLEY J ,  MARINANGELI RICHARD E ,  BRANDVOLD TIMOTHY A ,  KOCH MARK B ,  ABRAHAMIAN VASKEN B ,  NOGA JEFFREY M ,  TRAYNOR THOMAS J

IPC: C10G25/02 ,  C10G7/00 ,  C10J3/00 ,  C10L1/02

CPC classification number: C10L1/02 ,  B01J39/05 ,  B01J49/53 ,  B01J49/60 ,  C10B53/02 ,  C10C5/00 ,  Y02E50/32

Abstract: Low metal, low water biomass-derived pyrolysis oils and methods for producing the same are provided. Metal- and water-containing biomass-derived pyrolysis oil is contacted with an acidic ion-exchange resin having sulfonic acid groups to produce a low metal, water-containing biomass-derived pyrolysis oil. The low metal, water-containing biomass-derived pyrolysis oil is removed from the spent ion-exchange resin after ion-exchange. The low metal, water-containing biomass-derived pyrolysis oil is distilled to produce a low metal, low water biomass-derived pyrolysis oil and a distillation product. The distillation product comprises one or both of an alcohol ion-exchange regenerant and an acidic ion-exchange regenerant which may be used to regenerate the spent ion-exchange resin. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.

Abstract translation: 提供低金属，低水生物质衍生的热解油及其制备方法。 将含金属和水的生物质衍生的热解油与具有磺酸基团的酸性离子交换树脂接触以产生低金属的含水生物质衍生的热解油。 离子交换后，从废离子交换树脂中除去低金属含水生物质衍生的热解油。 低金属，含水生物质衍生的热解油被蒸馏以产生低金属，低水生物质衍生的热解油和蒸馏产物。 蒸馏产物包含醇离子交换再生剂和可用于再生废离子交换树脂的酸性离子交换再生剂中的一种或两种。 再生的酸性离子交换树脂可以循环使用。 废酒精和酸离子交换再生剂可以被回收和再循环。