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    HIGH EFFICIENCY PROCESSES FOR OLEFINS, ALKYNES, AND HYDROGEN CO-PRODUCTION FROM LIGHT HYDROCARBONS SUCH AS METHANE
    34.
    发明申请
    HIGH EFFICIENCY PROCESSES FOR OLEFINS, ALKYNES, AND HYDROGEN CO-PRODUCTION FROM LIGHT HYDROCARBONS SUCH AS METHANE 审中-公开
    烯烃，烷烃和氢等烃类作为甲烷的氢生产的高效工艺

    公开(公告)号：US20140058149A1

    公开(公告)日：2014-02-27

    申请号：US13947485

    申请日：2013-07-22

    Applicant: UOP LLC

    Inventor： Antoine Negiz ,  Robert B. James ,  Carl J. Stevens ,  Paul T. Barger

    IPC: B01J19/10

    CPC classification number: B01J19/10 ,  B01J4/002 ,  B01J12/005 ,  B01J19/26 ,  C07C1/04 ,  C07C2/78 ,  C07C5/09 ,  C10G9/38 ,  C10G69/06 ,  C10G2400/20 ,  C10K3/00 ,  F23C3/00 ,  F23C6/042 ,  F23C2201/102 ,  Y02P30/40 ,  C07C11/04 ,  C07C9/04 ,  C07C11/24

    Abstract: High efficiency processes for producing olefins, alkynes, and hydrogen co-production from light hydrocarbons are disclosed. In one version, the method includes the steps of combusting hydrogen and oxygen in a combustion zone of a pyrolytic reactor to create a combustion gas stream, transitioning a velocity of the combustion gas stream from subsonic to supersonic in an expansion zone of the pyrolytic reactor, injecting a light hydrocarbon into the supersonic combustion gas stream to create a mixed stream including the light hydrocarbon, transitioning the velocity of the mixed stream from supersonic to subsonic in a reaction zone of the pyrolytic reactor to produce acetylene, and catalytically hydrogenating the acetylene in a hydrogenation zone to produce ethylene. In certain embodiments, the carbon efficiency is improved using methanation techniques.

    Abstract translation: 公开了从轻烃生产烯烃，炔烃和氢共生产的高效方法。 在一个方案中，该方法包括在热解反应器的燃烧区中燃烧氢和氧以产生燃烧气体流，在燃烧反应器的膨胀区中将燃烧气体流从亚音速转变为超音速的步骤， 将轻质烃注入到超音速燃烧气体流中以形成包含轻质烃的混合物流，将混合物流从热解反应器的反应区域中的超音速转化为亚音速，产生乙炔，并在乙炔中催化氢化乙炔 氢化区产生乙烯。 在某些实施方案中，使用甲烷化技术提高了碳效率。

    Combustion method and apparatus for NOx reduction
    35.
    发明授权
    Combustion method and apparatus for NOx reduction 失效
    用于NOx还原的燃烧方法和装置

    公开(公告)号：US06792895B2

    公开(公告)日：2004-09-21

    申请号：US10618639

    申请日：2003-07-15

    Applicant: Toshihiro Kayahara ,  Noboru Takubo

    Inventor： Toshihiro Kayahara ,  Noboru Takubo

    IPC: F22D102

    CPC classification number: F23G7/07 ,  F23C9/08 ,  F23C2201/102 ,  F23C2201/401 ,  F23C2202/10 ,  F23C2203/20 ,  F23L7/002

    Abstract: Combustion method and apparatus for NOx reduction which are capable of achieving NOx reduction with the value of exhaust NOx under 10 ppm, as well as CO reduction at the same time. The combustion method for fulfilling NOx reduction and CO reduction by suppressing temperature of combustion gas derived from a burner comprises a NOx reduction step for suppressing combustion gas temperature in such a manner that suppression of NOx generation is preferred to reduction of exhaust CO value, thereby keeping NOx value not more than a specified value, and a CO reduction step for thereafter reducing exhaust CO value resulting from the NOx reduction step to not more than a specified value.

    Abstract translation: NOx还原的燃烧方法和装置能够以10ppm以下的排气NOx的值实现NOx还原，同时还原CO。 通过抑制来自燃烧器的燃烧气体的温度来实现NOx还原和CO还原的燃烧方法包括：NOx还原步骤，用于抑制燃烧气体温度，使得抑制NOx生成优选减少排气CO值，从而保持 NOx值不大于指定值，以及CO还原步骤，其后将由NOx还原步骤得到的排气CO值减少到规定值以下。

    Low NOx combustor for gas turbine engine
    36.
    发明授权
    Low NOx combustor for gas turbine engine 失效
    用于燃气轮机的低NOx燃烧器

    公开(公告)号：US06240731B1

    公开(公告)日：2001-06-05

    申请号：US09001889

    申请日：1997-12-31

    Applicant: James B. Hoke ,  Irving Segalman ,  Kenneth S. Siskind ,  Reid D. C. Smith

    Inventor： James B. Hoke ,  Irving Segalman ,  Kenneth S. Siskind ,  Reid D. C. Smith

    IPC: F23R314

    CPC classification number: F23C7/004 ,  F23C6/045 ,  F23C7/02 ,  F23C2201/102 ,  F23D11/107 ,  F23D2206/10 ,  F23D2900/11101 ,  F23R3/06 ,  Y02E20/344

    Abstract: A method of combusting fuel in the combustor of a gas turbine engine is disclosed which includes injecting fuel and a first predetermined amount of airflow into the combustion chamber to form a fuel-rich, highly mixed, uniform distribution fuel-air spray pattern flowing downstream in the combustion chamber and introducing a second predetermined amount of airflow into the fuel air spray pattern from combustor air inlets positioned at a first predetermined distance downstream from the combustor dome with the first predetermined distance being greater than 0.75 times the dome height and said second predetermined amount of airflow being sufficient to cause rapid mixing and quenching of the rich fuel-air mixture to a lean fuel-air mixture. A combustor for a gas turbine engine is also disclosed which includes sidewalls and a dome wall to form a combustion chamber, a fuel injector/air swirler assembly for injecting a fuel air spray, a first and second array of air inlets for introducing airflow into the combustion chamber sufficient to cause rapid combustion and rapidly resulting lean-fuel air mixture, the first array being positioned a predetermined distance downstream from the dome wall with the predetermined distance being greater than 0.75 times the dome height and the second array of air inlets being positioned downstream from the first array.

    Abstract translation: 公开了一种在燃气涡轮发动机的燃烧器中燃烧燃料的方法，其包括将燃料和第一预定量的气流喷射到燃烧室中以形成在下游流动的富燃料，高度混合均匀的分配燃料 - 空气喷雾图案 燃烧室，并且从位于燃烧器穹顶下游的第一预定距离处的燃烧器空气入口将第二预定量的气流引入燃料空气喷射图案，其中第一预定距离大于穹顶高度的0.75倍，并且所述第二预定量 的气流足以使富燃料 - 空气混合物快速混合并骤冷至贫燃料 - 空气混合物。 还公开了一种用于燃气涡轮发动机的燃烧器，其包括侧壁和用于形成燃烧室的圆顶壁，用于喷射燃料空气喷射的燃料喷射器/空气旋流器组件，用于将气流引入到空气入口中的第一和第二排空气入口 燃烧室足以引起快速燃烧和快速产生的稀燃燃料空气混合物，第一阵列定位在距圆顶壁下游一预定距离处，预定距离大于圆顶高度的0.75倍，第二阵列的空气入口被定位 从第一个阵列的下游。

    Method and system for reducing NO.sub.x and fuel emissions in a furnace
    38.
    发明授权
    Method and system for reducing NO.sub.x and fuel emissions in a furnace 失效
    降低炉内NOx和燃料排放的方法

    公开(公告)号：US5759022A

    公开(公告)日：1998-06-02

    申请号：US543663

    申请日：1995-10-16

    Applicant: Richard R. Koppang ,  David K. Moyeda

    Inventor： Richard R. Koppang ,  David K. Moyeda

    IPC: C03B5/235 ,  F23C6/04 ,  F23L7/00 ,  F23L15/02 ,  F23D14/00

    CPC classification number: F23L7/007 ,  C03B5/235 ,  F23C6/042 ,  F23L15/02 ,  F23C2201/102 ,  Y02E20/322 ,  Y02E20/344 ,  Y02E20/348 ,  Y02P40/535

    Abstract: In a method of this invention, a first oxidant flow including oxygen and/or air, is injected into an exhaust gas flow from a primary burn zone in a furnace combustion chamber. The first oxidant flow is injected into the exhaust gas flow in a secondary burn zone downstream from the primary burn zone, but inside of the furnace chamber so that heat released from combustion of the first oxidant flow can be used for the purpose to which the furnace is applied. Also, the injection of the first oxidant flow into the secondary burn zone combusts fuel pollutants that might otherwise be released from the furnace into the atmosphere. The method can also include mixing a gaseous hydrocarbon fuel flow with the exhaust gas flow from the secondary burn zone to reduce the NO.sub.x, level in the exhaust gas. Also, the method can include mixing a second oxidant flow including air and/or oxygen, with the exhaust gas, preferably after reducing the NO.sub.x. If the furnace is a regenerative type, the air flow can be mixed with the exhaust gas flow in proximity to the entrance of a regenerator to heat the regenerator. The invention also includes a related system.

    Abstract translation: 在本发明的方法中，将包含氧和/或空气的第一氧化剂流注入来自炉燃烧室中的初级燃烧区的废气流中。 第一氧化剂流被注入到主燃烧区下游的第二燃烧区域中的废气流中，但是在炉室的内部注入，使得从第一氧化剂流的燃烧释放的热可以用于炉的目的 被申请;被应用。 而且，将第一氧化剂流注入次级燃烧区域燃烧燃料污染物，否则燃料污染物可能会从炉中释放到大气中。 该方法还可以包括将气态碳氢化合物燃料流与来自二次燃烧区的废气流混合以减少废气中的NOx。 此外，该方法可以包括将包括空气和/或氧气的第二氧化剂流与废气混合，优选在还原NOx之后。 如果炉是再生型，则可以将气流与靠近再生器入口的废气流混合以加热再生器。 本发明还包括相关系统。

    Method of operating a firing installation
    39.
    发明授权
    Method of operating a firing installation 失效
    操作点火装置的方法

    公开(公告)号：US5545032A

    公开(公告)日：1996-08-13

    申请号：US439241

    申请日：1995-05-11

    Applicant: Peter Jansohn ,  Tino-Martin Marling ,  Thomas Sattelmayer

    Inventor： Peter Jansohn ,  Tino-Martin Marling ,  Thomas Sattelmayer

    IPC: F23C99/00 ,  F23C6/04 ,  F23C9/00 ,  F23D17/00 ,  F23M3/00

    CPC classification number: F23C6/04 ,  F23C9/00 ,  F23D17/002 ,  F23C2201/102 ,  F23C2201/30 ,  F23C2900/06041 ,  F23C2900/07002 ,  F23C2900/09002

    Abstract: In a firing installation which is designed to minimize the pollutant emissions during the use of both a liquid and a gaseous fuel, an annular chamber (12) is arranged downstream of a first combustion stage (1) on the head side of a second combustion stage (2) arranged downstream. The first combustion stage (1) is operated as a lean stage with a burner (100), while the second combustion stage (2) is operated as a near-stiochiometric stage. The wall of the annular chamber (12) has a number of openings (13) for the inflow of a mixture (14) of recycled flue gas (4) and fuel (15). The combustion air (115) for the burner (100) is likewise a mixture (6) of air (3) and recycled flue gas (4). The hot gases from this first combustion stage (1) are moderated before entering the second combustion stage (2), self-igniting combustion taking place in this second combustion stage (2) starting from the annular chamber (12).

    Abstract translation: 在设计成在使用液体和气体燃料期间最小化污染物排放的点火装置中，环形室（12）设置在第二燃烧阶段的头部侧的第一燃烧阶段（1）的下游， （2）布置在下游。 第一燃烧阶段（1）作为具有燃烧器（100）的贫燃阶段操作，而第二燃烧阶段（2）作为近刻度阶段操作。 环形室（12）的壁具有用于流入再循环废气（4）和燃料（15）的混合物（14）的多个开口（13）。 用于燃烧器（100）的燃烧空气（115）同样是空气（3）和循环烟气（4）的混合物（6）。 来自第一燃烧阶段（1）的热气体在进入第二燃烧阶段（2）之前被缓和，在该第二燃烧阶段（2）中从环形室（12）开始发生自燃。

    HIGH EFFICIENCY PROCESSES FOR OLEFINS, ALKYNES, AND HYDROGEN CO-PRODUCTION FROM LIGHT HYDROCARBONS SUCH AS METHANE
    40.
    发明申请
    HIGH EFFICIENCY PROCESSES FOR OLEFINS, ALKYNES, AND HYDROGEN CO-PRODUCTION FROM LIGHT HYDROCARBONS SUCH AS METHANE 审中-公开
    烯烃，烷烃和氢等烃类作为甲烷的氢生产的高效工艺

    公开(公告)号：WO2014031371A1

    公开(公告)日：2014-02-27

    申请号：PCT/US2013/054469

    申请日：2013-08-12

    Applicant: UOP LLC

    Inventor： NEGIZ, Antoine ,  JAMES, Robert B. ,  STEVENS, Carl J. ,  BARGER, Paul T.

    IPC: B01J19/10 ,  C07C11/24 ,  C07C11/04 ,  C07C5/09 ,  C07C9/04 ,  C01B3/02

    CPC classification number: B01J19/10 ,  B01J4/002 ,  B01J12/005 ,  B01J19/26 ,  C07C1/04 ,  C07C2/78 ,  C07C5/09 ,  C10G9/38 ,  C10G69/06 ,  C10G2400/20 ,  C10K3/00 ,  F23C3/00 ,  F23C6/042 ,  F23C2201/102 ,  Y02P30/40 ,  C07C11/04 ,  C07C9/04 ,  C07C11/24

    Abstract: High efficiency processes for producing olefins, alkynes, and hydrogen co-production from light hydrocarbons are disclosed. In one version, the method includes the steps of combusting hydrogen and oxygen in a combustion zone of a pyrolytic reactor to create a combustion gas stream, transitioning a velocity of the combustion gas stream from subsonic to supersonic in an expansion zone of the pyrolytic reactor, injecting a light hydrocarbon into the supersonic combustion gas stream to create a mixed stream including the light hydrocarbon, transitioning the velocity of the mixed stream from supersonic to subsonic in a reaction zone of the pyrolytic reactor to produce acetylene, and catalytically hydrogenating the acetylene in a hydrogenation zone to produce ethylene. In certain embodiments, the carbon efficiency is improved using methanation techniques.

    Abstract translation: 公开了从轻烃生产烯烃，炔烃和氢共生产的高效方法。 在一个方案中，该方法包括在热解反应器的燃烧区中燃烧氢气和氧气以产生燃烧气体流，在燃烧反应器的膨胀区中将燃烧气体流从亚音速转变为超音速的步骤， 将轻质烃注入到超音速燃烧气体流中以产生包含轻质烃的混合物流，将混合物流从热解反应器的反应区域中的超音速转化为亚音速，产生乙炔，并催化氢化乙炔 氢化区产生乙烯。 在某些实施方案中，使用甲烷化技术提高了碳效率。

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