Process for coating substrates with aqueous polymer dispersions
    391.
    发明授权
    Process for coating substrates with aqueous polymer dispersions 失效
    用聚合物水分散体涂覆基材的方法

    公开(公告)号:US4573429A

    公开(公告)日:1986-03-04

    申请号:US638222

    申请日:1984-08-06

    CPC classification number: B05D1/02 B05B9/00 B05D1/002 B05D2201/02

    Abstract: A process for providing a substrate such as a polyethylene terephthalate container with a gas barrier coating of a copolymer of vinylidene chloride is disclosed. The process includes locating the container to be coated in close proximity to one or more airless spray nozzles and impacting the outside surface of the container with a stream of a stabilized aqueous polymer dispersion such as an aqueous polyvinylidene chloride dispersion. The impacting force of the stable polyvinylidene chloride dispersion on the surface of the container is sufficient to cause selective destabilization of the dispersion at the surface interface to form a gel layer containing the polymer in the continuous phase. This gel layer serves as an adhesive layer for an overlying layer of the aqueous polymer dispersion as a continuous uniform coating. The resulting wet coating does not sag or run off. The coating on the container is then dried in a controlled atmosphere to complete the gel formation throughout its thickness whereupon it is further dried to remove the water from the coating and to collapse the gel to form a film without distorting the container. The dried coating is smooth, uniform and uniformly transparent. In operation, the overspray can be collected and returned to achieve greater than 95% material efficiency. The process can be carried out in a continuous manner to provide a continuously moving series of containers with a uniformly transparent, gas barrier polyvinylidene chloride coating at production rates suitable for commercial applications.

    Abstract translation: 公开了一种用于提供诸如聚对苯二甲酸乙二醇酯容器之类的衬底与偏二氯乙烯共聚物的阻气涂层的方法。 该方法包括将要涂覆的容器定位在一个或多个无空气喷嘴附近,并用稳定的聚合物水分散体流如聚偏二氯乙烯分散体冲击容器的外表面。 稳定的聚偏二氯乙烯分散体在容器表面上的冲击力足以引起表面界面处的分散体的选择性不稳定,以形成含有连续相中聚合物的凝胶层。 该凝胶层作为连续均匀涂层的水性聚合物分散体的上层的粘合剂层。 所得到的湿涂层不会下垂或流失。 然后将容器上的涂层在受控的气氛中干燥以在其整个厚度上完成凝胶形成,然后进一步干燥以从涂层中除去水并使凝胶塌缩以形成膜而不使容器变形。 干燥的涂层光滑,均匀且均匀透明。 在运行中,可以收集和返回过喷,以达到95%以上的物料效率。 该方法可以以连续的方式进行,以适于商业应用的生产速率提供具有均匀透明的阻气聚偏二氯乙烯涂层的连续移动的容器系列。

    COATING MATERIAL, COATING FILM, LAYERED PRODUCT, AND FLEXIBLE FLAT CABLE

    公开(公告)号:US20240228814A9

    公开(公告)日:2024-07-11

    申请号:US18546014

    申请日:2022-03-15

    Inventor: Shoko NAKAJIMA

    CPC classification number: C09D123/12 B05D7/54 C09D7/20 B05D2201/02 B05D2507/02

    Abstract: Disclosed is a coating material comprising 100 parts by mass of an acid-modified polypropylene (A) and at least 450 parts by mass of organic solvents (B), wherein the acid-modified polypropylene has a melting point of 90° C. or lower and the organic solvents (B) comprises 80-99 mass % aromatic hydrocarbon solvent (B1) and 20-1 mass % one or more solvents (B2) selected from the group consisting of ester-based solvents, ketone-based solvents, and alcohol-based solvents, the sum of the proportion of the ingredient (B1) and the proportion of the ingredient (B2) being 100 mass %. The coating material may further contain a compound (C) having, in the molecule, two or more functional groups capable of forming a chemical bond with a carboxyl group, in an amount of 0.1-20 parts by mass. The compound (C) having, in the molecule, two or more functional groups capable of forming a chemical bond with a carboxyl group may be one having no hydrolyzable group. Also disclosed are: a coating film formed from the coating material; a layered product comprising the coating film and a substrate film; and a flexible flat cable including the layered product.

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