-
公开(公告)号：JPS63100441A
公开(公告)日：1988-05-02
申请号：JP3578287
申请日：1987-02-20
Applicant: AGENCY IND SCIENCE TECHN , TOYO GOSEI KOGYO KK
Inventor： ICHIMURA KUNIHIRO , YONEZAWA TERUHIKO , KIKUCHI HIDEO , TOCHISAWA TETSUAKI , HAYASHI KEIICHI
Abstract: PURPOSE:To obtain excellent preservation and stability of the titled material for a long period, and at the same time, to prevent dissolution of a photoresist in case of providing a thin film of the titled material on the photoresist by using a specific compd. for a photodiscoloring compd., and by incorporating a combination of said compd. and a water soluble high polymer binder to the titled material. CONSTITUTION:The titled material comprises at least one kind of the photodiscoloring compd. selected from the compd. having two constituting units shown by formula I and the water soluble high polymer binder. In formula I, Z is a residual group capable of forming a nitrogen contg. aromatic heterocyclic ring together with nitrogen atom, X is a monovalent anionic residual group, (n) is an integer of >=1, another end of an ethylenic unsatd. group is bound to an aromatic ring group. Thus, the excellent characteristics of the titled material, such as excellent stability for long period, and less tendency for dissolving the photoresist in case of providing the thin film of the titled material on the photoresist, and unnecessity of a step of removing said thin film before processing the image, etc., ate obtd.
-
公开(公告)号：JPS63100440A
公开(公告)日：1988-05-02
申请号：JP3578187
申请日：1987-02-20
Applicant: AGENCY IND SCIENCE TECHN , TOYO GOSEI KOGYO KK
Inventor： ICHIMURA KUNIHIRO , YONEZAWA TERUHIKO , KIKUCHI HIDEO , TOCHISAWA TETSUAKI , HAYASHI KEIICHI
Abstract: PURPOSE:To obtain excellent preservation and stability of the titled material for a long period, and at the same time, to prevent dissolution of a photoresist in case of providing a thin film of the titled material on the photoresist by using a specific compd. for a photodiscoloring compd., and by incorporating a combination of said compd. and a water soluble high polymer binder to the titled material. CONSTITUTION:The titled material comprises at least one kind of the photodiscoloring compd. and the water soluble high polymer binder. In formula I, A is an aromatic cyclic group which may be substituted, R1 is hydrogen atom, alkyl, alkenyl or aralkyl group, Z is a residual group capable of forming a nitrogen contg. aromatic heterocyclic ring together with nitrogen atom, X is a monovalent anionic residual group, (n) is an integer of >=1. Thus, the excellent characteristics of the titled material, such as excellent stability for long period, and less tendency for dissolving the photoresist in case of providing the thin film of the titled material on the photoresist, and unnecessity of a step of removing said thin film before processing the image, etc., are obtd.
-
公开(公告)号：JPS62257882A
公开(公告)日：1987-11-10
申请号：JP10107686
申请日：1986-05-02
Applicant: AGENCY IND SCIENCE TECHN , TOYO GOSEI KOGYO KK
Inventor： ICHIMURA KUNIHIRO , YONEZAWA TERUHIKO , KIKUCHI HIDEO , SAITO TERUMITSU
Abstract: PURPOSE:To obtain a thermal recording layer having excellent water resistance and chemical resistance, by using a photosensitive polyvinyl alcohol having a structural unit of a specified general formula, as a binder. CONSTITUTION:A thermal recording layer provided, on a base, with a thermal recording layer comprising a color forming substance, a color developer and a binder as main constituents is produced as follows. For example, the color forming substance and the color developer are separately dispersed in a particle size of not more than several micrometers by a ball mill or the like while using a binder, the two dispersed liquids thus obtained are mixed with each other, and an adhesive, a filler, a surfactant or the like is appropriately added to the resultant mixture to obtain a coating liquid for forming a thermal color forming layer. The coating liquid is applied to a sheet form base such as a paper or a plastic sheet. A photosensitive polyvinyl alcohol having a structural unit of general formula I, wherein R is a quaternary aromatic nitrogen- containing heterocyclic ring residue, R is hydrogen or a lower alkoxyl, m is 0 or 1, n is an integer of 1-6, is used as the binder. The applied material is irradiated with UV rays without heating, thereby providing the thermal recording layer with excellent water resistance and chemical resistance.
-
公开(公告)号：JPS62257881A
公开(公告)日：1987-11-10
申请号：JP10107586
申请日：1986-05-02
Applicant: AGENCY IND SCIENCE TECHN , TOYO GOSEI KOGYO KK
Inventor： ICHIMURA KUNIHIRO , YONEZAWA TERUHIKO , KIKUCHI HIDEO , SAITO TERUMITSU
Abstract: PURPOSE:To provide excellent water resistance and chemical resistance and lower the possibility of adhesion of scum to a thermal head at the time of recording, by using a photosensitive polyvinyl alcohol having a structural unit of a specified general formula, as a film forming high molecular weight compound in an overcoat layer. CONSTITUTION:A thermal recording material is produced as follows. For example, a color forming substance and a color developer are separately dispersed in a particle size of not more than several micrometers by a ball mill or the like while using a binder, the two dispersed liquids thus obtained are mixed with each other, and an adhesive, a filler, a surfactant or the like is appropriately added to the resultant mixture to obtain a coating liquid for forming a thermal color forming layer. The coating liquid is applied to a sheet form base such as a paper and a plastic sheet, and is dried at a relatively low temperature to provide a thermal recording layer. A film forming high molecular weight compound comprising a photosensitive polyvinyl alcohol having a structural unit of general formula I, wherein R is a quaternary aromatic nitrogen-containing heterocyclic ring residue, R is hydrogen or a lower alkoxyl, m is 0 or 2, and n is an integer of 1-6, is applied to the thermal recording layer, and after drying, it is irradiated with UV rays by using a high pressure mercury lamp or the like to provide an overcoat layer, thereby obtaining the thermal recording material.
-
公开(公告)号：JPS62250440A
公开(公告)日：1987-10-31
申请号：JP9519586
申请日：1986-04-24
Applicant: AGENCY IND SCIENCE TECHN , MURAKAMI SCREEN KK
Inventor： ICHIMURA KUNIHIRO , YAMAOKA TSUGIO , INOUE KAZUO
Abstract: PURPOSE:To obtain the titled composition capable of giving good solvent and moisture resisting properties, and forming a cured film having sufficient abrasion and print resisting properties after photopolymerizing it by incorporating a prescribed inorg. solid matter to a partially saponified vinylacetate polymer having a photocross-linkable group and a hydrophobic polymer emulsion. CONSTITUTION:The photosensitive resin composition is composed of an aqueous emulsion contg. the partially saponified vinylacetate polymer which has a styrbazolium group and 70-99mol% saponification degree, and the hydrophobic polymer emulsion. The aqueous emulsion contains 1-50wt% of water insoluble inorg. solid matter based on the solid component contained in the aqueous emulsion. Thus, the partially saponified vinylacetate polymer, which forms a continuous phase, is cross-linked and cured in the presence of the styrbazolium group as the photocross-linking group, and the emulsified ethylenic unsatd. compd. polymerizes, and binds with the hydrophobic polymer emulsion particles at an interface between the partially saponified vinylacetate polymer and the ethylenical unstd. emulsion particles, thereby forming a strong hardened film.
-
Patent Agency Ranking
公开(公告)号：JPS6225750A
公开(公告)日：1987-02-03
申请号：JP16529385
申请日：1985-07-26
Applicant: AGENCY IND SCIENCE TECHN , TOYO GOSEI KOGYO KK
Inventor： ICHIMURA KUNIHIRO , YONEZAWA TERUHIKO , KIKUCHI HIDEO , TOCHISAWA TETSUAKI , HAYASHI KEIICHI , SUGIURA HITOSHI
Abstract: PURPOSE:To enhance storage stability of a printing plate material by forming a photosensitive layer made of photosensitive polyvinyl alcohol having a specified substituted styryl group on a metallic support. CONSTITUTION:The photosensitive layer formed on the metallic support is made of polyvinyl alcohol having as photosensitive units the substituted styryl groups each represented by the formula shown on the right in which R is a quaternized aromatic N-containing heterocyclic group; R is H or lower alkoxy; m is 0 or 1; and n is 1-6. For example, this compound is the acetal compound of polyvinyl alcohol with 1-methyl-2-(p-formylstyryl)pyridinium or 1-methyl-2-(p-formylstyryl)quinolinium. Accordingly, this polyvinyl alcohol derivative has the substituted styryl groups as like stilbazolium, and it is an environmental nonpollutant, and superior in storage stability.
-
公开(公告)号：JPS61195691A
公开(公告)日：1986-08-29
申请号：JP3829485
申请日：1985-02-27
Applicant: AGENCY IND SCIENCE TECHN
Inventor： SUEHIRO TETSURO , ICHIJO HISAO , NAGASAWA JUNICHI , ICHIMURA KUNIHIRO , YAMAUCHI AIZO
Abstract: PURPOSE:To improve the yield of a fatty acid triglyceride in the production of the triglyceride by contacting a fatty acid with different kind of a fatty acid triglyceride, by using a lipase included in a hydrated gel particle of a specific polyvinyl alcohol, as an enzyme. CONSTITUTION:A polyvinyl alcohol derivative having a stilbazolium group and obtained by the reaction of a polyvinyl alcohol or a partially saponified vinyl acetate with styrylpyridinium is dissolved together with a lipase in water, and the aqueous solution is added to a hydrophobic medium, and irradiated with actinic light to effect the photo-crosslinking of the polyvinyl alcohol derivative having stilbazolium group and obtain a lipase included in the resultant hydrated gel particle. A fatty acid triglyceride and a fatty acid is made to contact with each other in a solvent in the presence of the above lipase as an enzyme to obtain a fatty acid triglyceride having different fatty acid residue.
-
公开(公告)号：JPS61184534A
公开(公告)日：1986-08-18
申请号：JP2450085
申请日：1985-02-13
Applicant: AGENCY IND SCIENCE TECHN , TOYO GOSEI KOGYO KK
Inventor： ICHIMURA KUNIHIRO , TOCHISAWA TETSUAKI , YAMAZAWA YOJI
Abstract: PURPOSE:To produce simply and economically an aqueous soln. by introducing a substituted styryl residue having a specified structure, using an acidic ion exchange resin as a catalyst for an acetal formation reaction or an acetal exchange reaction to carry out such a reaction, and treating the resulting mixture with a basic ion exchange resin. CONSTITUTION:Polyvinyl alcohol or modified polyvinyl alcohol and a compound having a substituted styryl residue represented by the formula (where R is a quat. chloraromatic N-contg. heterocyclic residue, R is H or lower alkoxyl, n is an integer of 1-6, and m=0 or 1) are dissolved in an aqueous medium, an acidic ion exchange resin is added, and they are stirred at a constant temp. At this time, the ion exchange resin and a very small amount of the styryl compound release protons by ion exchange, making the reactive soln. acidic, so an acetal formation reaction or an acetal exchange reaction proceeds. After the reaction is finished, a basic ion exchange resin is added and stirred at a constant temp. The pH of the liq. reaction product rises, and when the product is made neutral, the ion exchange capacity is increased to capture the unreacted substituted styryl compound by ion exchange. Thus, an aqueous soln. of a photosensitive resin is produced in simple and very economical stages.
-
公开(公告)号：JPH11326638A
公开(公告)日：1999-11-26
申请号：JP14510098
申请日：1998-05-11
Applicant: AGENCY IND SCIENCE TECHN , ICHIMURA KUNIHIRO
Inventor： ICHIMURA KUNIHIRO
IPC: G02B5/30 , B29D11/00 , G02F1/1335
Abstract: PROBLEM TO BE SOLVED: To provide a liquid crystal alignment layer, which highly stabilizes the molecule aligned state with light with respect to heat, light or further electric field, is formable to a large area at a uniform film thickness, does not make a production process complicated, is not restricted in utilization as an optical element and is arbitrarily controllable in an alignment direction and a process for producing the same as well as the optical element using this liquid crystal alignment layer. SOLUTION: This liquid crystal alignment layer is constituted by subjecting a resin film containing a dichromatic photoreactive component unit, more preferably a latent liquid crystal or crystal resin film to photoirradiation with linearly polarized light or irradiation with non-polarized light from a diagonal direction and further preferably subjecting this film to a heat treatment and forming a non-photoreactive liquid crystal material layer thereon. This process for producing the liquid crystal alignment layer consists in subjecting the latent liquid crystal or crystal resin film containing the dichromatic photoreactive component unit to the photoirradiation with the linearly polarized light or the irradiating with the non- polarized light from the diagonal direction, then subjecting this film to the heat treatment and forming the non-photoreactive liquid crystal material layer on this resin film.
-
50.发明专利
公开(公告)号：JPH1195223A
公开(公告)日：1999-04-09
申请号：JP25037397
申请日：1997-09-16
Applicant: AGENCY IND SCIENCE TECHN
Inventor： TAMAOKI TAKASHI , KAWANISHI YUJI , AKIYAMA AKIHISA , ICHIMURA KUNIHIRO
IPC: G02F1/1337
Abstract: PROBLEM TO BE SOLVED: To provide a tilt oriented film for liquid crystals which has high productivity and allows arbitrary setting of a tilt angle without requiring the use of a polarizing element at the time of production and a liquid crystal orientation method and a liquid crystal cell. SOLUTION: This tilt oriented film is formed by irradiating a resin film contg. an isomerization reaction constitution unit with light of non-polarized light from a diagonal direction or is formed by irradiating the resin film which contains the isomerization reaction constitution unit and induces liquid crystal perpendicular orientation with the light of the non-polarized light from the diagonal direction. The liquid crystal orientation treatment method consists in irradiating the resin film contg. the isomerization reaction constitution unit with the light of the non-polarized light from the diagonal direction or irradiating the resin film which contains the isomerization reaction constitution unit and induces the liquid crystal perpendicular orientation with the light of the non-polarized light from the diagonal direction. The liquid crystal cell is constituted by arranging a substrate formed any of the tilt oriented films for liquid crystals described above and a substrate formed with the oriented films for liquid crystals which is the same as the oriented film described above or different therefrom so as to face each other and holding the liquid crystals between these substrates.
-
-
-
-
-
-
-
-
-
Search Results
100
records
(took 0.033 seconds)
