Method for reducing the quantity of residual monomers in aqueous dispersions of polymers

    公开(公告)号:AU5854699A

    公开(公告)日:2000-03-27

    申请号:AU5854699

    申请日:1999-08-25

    Applicant: BASF AG

    Abstract: A process for reducing the amount of residual monomer in aqueous polymer dispersions operates by aftertreatment with an initiator system essentially comprisinga) from 0.001 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion,a1) of an oxidizing agent where R1 is hydrogen or a C1-C8-alkyl or a C6-C12-aryl group, and/ora2) of a compound which in aqueous medium releases hydrogen peroxide, andb) from 0.005 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion,b1) of an alpha-hydroxycarbonyl compound where R2 and R3 independently of one another are hydrogen and/or a C1-C12-alkyl group which may contain functional groups and/or may be olefinically unsaturated, or R2 and R3 optionally, by way of methylene groups, form a ring structure which may contain functional groups and/or may be olefinically unsaturated, and/orb2) of a compound which in aqueous medium releases such alpha-hydroxycarbonyl compounds, andc) advantageously, catalytic amounts of a polyvalent metal ion which is able to exist in a plurality of valence states.

    DISPERSION RESINS CONTAINING ITACONIC ACID FOR IMPROVING WET ABRASION RESISTANCE

    公开(公告)号:CA2322590A1

    公开(公告)日:1999-09-23

    申请号:CA2322590

    申请日:1999-03-15

    Applicant: BASF AG

    Abstract: The invention relates to aqueous pigment preparations containing i) at least one copolymer P of ethylenically unsaturated monomers M in the form of an aqueous polymer dispersion which contains between 0.1 and 1.5 weight %, in relation to the total weight of the copolymer P, of polymerised itaconic acid as acid monomer M1, its salts and/or anhydride, where up to 50 weight % of the itaconic acid can be substituted by another monomer having at least one acid group or a neutralised acid group, and whose glass transition temperature TG lies between -10 and +50 ~C; ii) at least one inorganic pigment; iii) possibly inorganic fillers; and iv) standard additives. The invention also relates to the use of the copolymers P containing itaconic acid for improving the wetabrasion resistance of polymer-bound coatings containing pigments.

    45.
    发明专利
    未知

    公开(公告)号:AT178339T

    公开(公告)日:1999-04-15

    申请号:AT95937840

    申请日:1995-10-25

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/04180 Sec. 371 Date May 5, 1997 Sec. 102(e) Date May 5, 1997 PCT Filed Oct. 25, 1995 PCT Pub. No. WO96/14355 PCT Pub. Date May 17, 1996An aqueous polymer emulsion contains a dispersed polymer A, which is obtainable by free radical aqueous emulsion polymerization of different monomer compositions in two successive stages and has ureido groups, and a polyaldehyde compound.

    46.
    发明专利
    未知

    公开(公告)号:ES2116772T3

    公开(公告)日:1998-07-16

    申请号:ES95934636

    申请日:1995-09-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03770 Sec. 371 Date Apr. 3, 1997 Sec. 102(e) Date Apr. 3, 1997 PCT Filed Sep. 23, 1995 PCT Pub. No. WO96/10588 PCT Pub. Date Apr. 11, 1996A process for the preparation of an aqueous polymer emulsion, in which an aqueous emulsion of a polymer which contains at least one chemically bonded monomer having at least one ethylenically unsaturated group is produced in a manner known per se so that the total content of free monomers having at least one ethylenically unsaturated double bond, ie. monomers of this type which are not chemically bonded, in the aqueous polymer emulsion is from >0 to

    47.
    发明专利
    未知

    公开(公告)号:DE59502275D1

    公开(公告)日:1998-06-25

    申请号:DE59502275

    申请日:1995-09-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03770 Sec. 371 Date Apr. 3, 1997 Sec. 102(e) Date Apr. 3, 1997 PCT Filed Sep. 23, 1995 PCT Pub. No. WO96/10588 PCT Pub. Date Apr. 11, 1996A process for the preparation of an aqueous polymer emulsion, in which an aqueous emulsion of a polymer which contains at least one chemically bonded monomer having at least one ethylenically unsaturated group is produced in a manner known per se so that the total content of free monomers having at least one ethylenically unsaturated double bond, ie. monomers of this type which are not chemically bonded, in the aqueous polymer emulsion is from >0 to

    49.
    发明专利
    未知

    公开(公告)号:NO971524L

    公开(公告)日:1997-06-03

    申请号:NO971524

    申请日:1997-04-03

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03770 Sec. 371 Date Apr. 3, 1997 Sec. 102(e) Date Apr. 3, 1997 PCT Filed Sep. 23, 1995 PCT Pub. No. WO96/10588 PCT Pub. Date Apr. 11, 1996A process for the preparation of an aqueous polymer emulsion, in which an aqueous emulsion of a polymer which contains at least one chemically bonded monomer having at least one ethylenically unsaturated group is produced in a manner known per se so that the total content of free monomers having at least one ethylenically unsaturated double bond, ie. monomers of this type which are not chemically bonded, in the aqueous polymer emulsion is from >0 to

Patent Agency Ranking