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公开(公告)号:BR0209297A
公开(公告)日:2004-07-13
申请号:BR0209297
申请日:2002-05-02
Applicant: BASF AG
Inventor: BORGMEIER FRIEDER
IPC: C07C51/215 , C07B61/00 , C07C45/33 , C07C45/35 , C07C57/05
Abstract: Acrylic acid is prepared by heterogeneously catalyzed partial oxidation of propane by a process in which the steam content of the reaction gas starting mixture is reduced in the course of the process.
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公开(公告)号:DE10261186A1
公开(公告)日:2004-07-08
申请号:DE10261186
申请日:2002-12-20
Applicant: BASF AG
Inventor: DIETERLE MARTIN , BORGMEIER FRIEDER , MUELLER-ENGEL KLAUS JOACHIM , HIBST HARTMUT
IPC: B01J23/22 , B01J23/28 , C07C57/055
Abstract: A heterogeneously catalyzed gas-phase partial oxidation of acrolein to acrylic acid over a catalytically active multimetal oxide material which contains the elements molybdenum and vanadium, tellurium or antimony, and elements consisting of niobium, tantalum, tungsten or titanium, whose X-ray diffraction pattern has no reflections with the peak position 2 theta = 50 +/- 0.30 but has reflections whose peaks are at specified diffraction angles. Heterogeneously catalyzed gas-phase partial oxidation of acrolein to acrylic acid over a catalytically active multimetal oxide material which contains the elements molybdenum and vanadium, tellurium or antimony, and elements consisting of niobium, tantalum, tungsten or titanium, whose X-ray diffraction pattern has no reflections with the peak position 2 theta = 50 +/- 0.30 but has reflections h, i and k whose peaks are at the diffraction angles (2 theta) 22.2 +/- 0.5 degrees (h), 27.3 +/- 0.50 (i) and 28.2 +/- 0.50 (k). The reflection (h ) is the one with the strongest intensity within the X-ray diffraction pattern and having a full width at half height of not more than 0.50; the intensity (Pi) of the reflection (i) and the intensity (Pk) of the reflection (k) fulfill the relationship that R is 0.65-0.85, where R is the intensity ratio defined by the formula R = Pi/(Pi + Pk); and the full width at half height of the reflection (i) and of the reflection (k) is in each case at most 10. The catalytically active multimetal oxide material is of formula (I). Mo1VaM1bM2cM3dOn (I). M1 = element(s) from the group consisting of Te and Sb; M2 = element(s) from the group consisting of Nb, Ti, W, Ta and Ce; M3 = element(s) consisting of Pb, Ni, Co, Bi, Pd, Ag, Pt, Cu, Au, Ga, Zn, Sn, In, Re, Ir, Sm, Sc, Y, Pr, Nd or Tb; a = 0.01-1; b = 0-1; c = 0-1; d = 0-0.5; n = number that is determined by the valency and frequency of the elements other than oxygen in formula (I).
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公开(公告)号:DE10321398A1
公开(公告)日:2004-05-27
申请号:DE10321398
申请日:2003-05-12
Applicant: BASF AG
Inventor: HIBST HARTMUT , COX GERHARD , BORGMEIER FRIEDER
IPC: B01J23/00 , B01J23/20 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/652 , B01J23/887 , B01J27/057 , B01J35/00 , B01J37/00 , B01J37/08 , C01G39/00 , C01G1/02 , B01J23/16 , C01G31/02 , C01G39/02
Abstract: Multi-metal oxides containing molybdenum and vanadium also contain lanthanides, transition elements and/or Group 3-6 elements and have an X-ray diffraction pattern with lattice spacings (d(A)) as follows: 3.06 +/- 0.2; 3.17 +/- 0.2; 3.28 +/- 0.2; 3.28 +/- 0.2; 3.99 +/- 0.2; 9.82 +/- 0.4; 11.24 +/- 0.4; and 13.28 +/- 0.5. Multi-metal oxides containing molybdenum and vanadium also contain other metals and have an X-ray diffraction pattern with lattice spacings (d(A)) as follows: 3.06 +/- 0.2; 3.17 +/- 0.2; 3.28 +/- 0.2; 3.28 +/- 0.2; 3.99 +/- 0.2; 9.82 +/- 0.4; 11.24 +/- 0.4; and 13.28 +/- 0.5, the oxides being of formula (I); Aa(Mo5-b-cVbXcOd)1 (I); A = NH4, Na, K, Rb, Cs and/or Tl; X = La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, Nb, Ta, W, Mn, Re, Fe, Co, Ni, Cr, Ru, Rh, Pd, Os, Ir, Pt, Cu, Ag, Au, Zn, Cd, Hg, B, Al, Ga, In, C, Si, Ge, Sn, Pb, P, As, Sb, Bi, S, Se and/or Te; a = 0-1-1; b = 0.25-4.5; and c = 0-4.5, with the proviso that (b + c) at most 4.5. An Independent claim is also included for preparation of the above multi-metal oxide.
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公开(公告)号:AU2003271723A8
公开(公告)日:2004-05-04
申请号:AU2003271723
申请日:2003-10-14
Applicant: BASF AG
Inventor: MULLER-ENGEL KLAUS JOACHIM , BORGMEIER FRIEDER , HIBST HARTMUT , DIETERLE MARTIN
IPC: B01J23/00 , B01J23/20 , B01J23/31 , B01J23/652 , B01J23/887 , B01J27/057 , B01J35/00 , B01J37/00 , B01J37/02 , C01G1/02 , C01G31/02 , C07C51/215 , C07C253/24 , H01L21/302 , H01L21/461
Abstract: A multimetal oxide material contains the elements Mo, V and Te and/or Sb and at least one of the elements Nb, Ti, W, Ta and Ce and promoters and has a specific X-ray diffraction pattern. Moreover, such a multimetal oxide material is used as a catalyst for heterogeneously catalyzed gas-phase partial oxidations of hydrocarbons.
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公开(公告)号:DE10248584A1
公开(公告)日:2004-04-29
申请号:DE10248584
申请日:2002-10-17
Applicant: BASF AG
Inventor: BORGMEIER FRIEDER , DIETERLE MARTIN , HIBST HARTMUT
Abstract: A heterogeneously catalyzed gas-phase partial oxidation of acrolein to acrylic acid over a catalytically active multimetal oxide material which contains the elements molybdenum and vanadium, tellurium or antimony, and elements consisting of niobium, tantalum, tungsten or titanium, whose X-ray diffraction pattern has no reflections with the peak position 2 theta = 50 +/- 0.30 but has reflections whose peaks are at specified diffraction angles. Heterogeneously catalyzed gas-phase partial oxidation of acrolein to acrylic acid over a catalytically active multimetal oxide material which contains the elements molybdenum and vanadium, tellurium or antimony, and elements consisting of niobium, tantalum, tungsten or titanium, whose X-ray diffraction pattern has no reflections with the peak position 2 theta = 50 +/- 0.30 but has reflections h, i and k whose peaks are at the diffraction angles (2 theta) 22.2 +/- 0.5 degrees (h), 27.3 +/- 0.50 (i) and 28.2 +/- 0.50 (k). The reflection (h ) is the one with the strongest intensity within the X-ray diffraction pattern and having a full width at half height of not more than 0.50; the intensity (Pi) of the reflection (i) and the intensity (Pk) of the reflection (k) fulfill the relationship that R is 0.65-0.85, where R is the intensity ratio defined by the formula R = Pi/(Pi + Pk); and the full width at half height of the reflection (i) and of the reflection (k) is in each case at most 10. The catalytically active multimetal oxide material is of formula (I). Mo1VaM1bM2cM3dOn (I). M1 = element(s) from the group consisting of Te and Sb; M2 = element(s) from the group consisting of Nb, Ti, W, Ta and Ce; M3 = element(s) consisting of Pb, Ni, Co, Bi, Pd, Ag, Pt, Cu, Au, Ga, Zn, Sn, In, Re, Ir, Sm, Sc, Y, Pr, Nd or Tb; a = 0.01-1; b = 0-1; c = 0-1; d = 0-0.5; n = number that is determined by the valency and frequency of the elements other than oxygen in formula (I).
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公开(公告)号:DE10119933A1
公开(公告)日:2002-10-24
申请号:DE10119933
申请日:2001-04-23
Applicant: BASF AG
Inventor: BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT , MUELLER-ENGEL KLAUS JOACHIM , UNVERRICHT SIGNE , COX GERHARD
Abstract: Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).
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公开(公告)号:DE10046672A1
公开(公告)日:2002-03-28
申请号:DE10046672
申请日:2000-09-20
Applicant: BASF AG
Inventor: BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT , MUELLER-ENGEL KLAUS , UNVERRICHT SIGNE , COX GERHARD
IPC: B01J23/00 , B01J23/28 , B01J27/057 , B01J37/02 , C07C45/33 , C07C45/35 , C07C57/05 , B01J23/18 , B01J23/22 , B01J27/02
Abstract: Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).
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公开(公告)号:DE10034825A1
公开(公告)日:2002-01-31
申请号:DE10034825
申请日:2000-07-18
Applicant: BASF AG
Inventor: BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT , MUELLER-ENGEL KLAUS JOACHIM , UNVERRICHT SIGNE , COX GERHARD
Abstract: Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).
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公开(公告)号:BRPI0315223B1
公开(公告)日:2015-12-15
申请号:BR0315223
申请日:2003-10-09
Applicant: BASF AG
Inventor: BORGMEIER FRIEDER , HIBST HATMUT , DIETERLE MARTIN
IPC: B01J23/00 , B01J23/20 , B01J23/31 , B01J23/652 , B01J23/887 , B01J27/057 , B01J35/00 , B01J37/00 , B01J37/02 , C01G1/02 , C01G31/02 , C07C51/215 , C07C253/24 , H01L21/302 , H01L21/461
Abstract: "massa de óxido multimetálico, processos para a oxidação e amoxidação em fase gasosa parcial heterogeneamente catalisada, e para preparação de uma massa de óxido multimetálico, e, uso de pelo menos uma massa de óxido multimetálico". uma massa de óxido multimetálico, que contêm os elementos mo, v, assim como n te e/ ou sb, e pelo menos um dos elementos nb, ti, w, ta e ce, assim como promotores, e apresenta um padrão de difração de raio x específico. além disso, o uso de uma tal massa de óxido multimetálico como catalisador para oxidações parciais em fase gasosa heterogeneamente catalisadas de hidrocarbonetos.
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公开(公告)号:BRPI0606400A2
公开(公告)日:2009-11-17
申请号:BRPI0606400
申请日:2006-01-04
Applicant: BASF AG
Inventor: CRONE SVEN , MACHHAMMER OTTO , SCHINDLER GOETZ-PETER , BORGMEIER FRIEDER
Abstract: A process for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the fed gas stream a comprising propane, if appropriate steam and, if appropriate, an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, carbon monoxide, carbon dioxide, steam, if appropriate hydrogen and, if appropriate, oxygen; C) product gas stream b is cooled, if appropriate condensed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) product gas stream c is contacted in a first absorption zone with a selective, inert absorbent which selectively absorbs propene to obtain an absorbent stream d1 laden substantially with propene and a gas stream d2 comprising propane, methane, ethane, ethene, carbon monoxide, carbon dioxide and hydrogen; E) if appropriate, the absorbent stream d1 is decompressed to a lower pressure in a first desorption zone to obtain an absorbent stream e1 laden substantially with propene and a gas stream e2 comprising propene, and gas stream e2 is recycled into the first absorption zone, F) from the absorbent stream d1 or e1 laden substantially with propene, in at least one second desorption zone, by decompression, heating and/or stripping the absorbent stream d1 or e1, a gas stream f1 comprising propene is released and the selective absorbent is recovered.
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