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    41.
    发明专利
    未知

    公开(公告)号：DK0383002T3

    公开(公告)日：1994-07-25

    申请号：DK90100106

    申请日：1990-01-04

    Applicant: BASF AG

    Inventor： DERSCH ROLF DR ,  SCHWARTZ MANFRED DR ,  DOTZAUER BERNHARD DR ,  VINKE JOHANNES DR ,  HANCIOGULLARI HARUTYUN DR ,  BERG VOLKMAR DR

    IPC: C04B41/64 ,  C04B41/48 ,  C04B41/63 ,  C09D5/00 ,  C09D5/14 ,  E04D1/28

    Abstract: A concrete roof tile is coated with an unfilled or aggregate- and/or pigment-filled film of a copolymer containing (a) from 0.03 to 2% by weight of tin in the form of a polymerizable organotin compound (b) from 0.5 to 5% by weight of (meth)acrylic acid, (meth)acrylamide and/or vinylsulfonic acid and (c) from 0.1 to 5% by weight of carbonyl-containing monomers crosslinked with certain dicarboxodihydrazides, besides (d) at least two (meth)acrylic esters of C1-C8alkanols and/or styrene as copolymerized units in such an amount and such mixing ratios that the copolymer has a glass transition temperature of -15 to +10 DEG C. prior to crosslinking.

    42.
    发明专利
    未知

    公开(公告)号：AT107616T

    公开(公告)日：1994-07-15

    申请号：AT90100106

    申请日：1990-01-04

    Applicant: BASF AG

    Inventor： DOTZAUER BERNHARD DR ,  DERSCH ROLF DR ,  VINKE JOHANNES DR ,  HANCIOGULLARI HARUTYUN DR ,  SCHWARTZ MANFRED DR ,  BERG VOLKMAR DR

    IPC: C04B41/64 ,  C04B41/48 ,  C04B41/63 ,  C09D5/00 ,  C09D5/14 ,  E04D1/28

    Abstract: A concrete roof tile is coated with an unfilled or aggregate- and/or pigment-filled film of a copolymer containing (a) from 0.03 to 2% by weight of tin in the form of a polymerizable organotin compound (b) from 0.5 to 5% by weight of (meth)acrylic acid, (meth)acrylamide and/or vinylsulfonic acid and (c) from 0.1 to 5% by weight of carbonyl-containing monomers crosslinked with certain dicarboxodihydrazides, besides (d) at least two (meth)acrylic esters of C1-C8alkanols and/or styrene as copolymerized units in such an amount and such mixing ratios that the copolymer has a glass transition temperature of -15 to +10 DEG C. prior to crosslinking.

    Dirt-resistant concrete tiles
    43.
    发明专利
    Dirt-resistant concrete tiles 未知

    公开(公告)号：DE4041466A1

    公开(公告)日：1992-06-25

    申请号：DE4041466

    申请日：1990-12-22

    Applicant: BASF AG

    Inventor： DOTZAUER BERNHARD DR ,  WISTUBA ECKEHARDT DR ,  SCHWARTZ MANFRED DR ,  PETRI ROLF ,  BECHERT BERTOLD ,  DENU HANS-JUERGEN

    IPC: C04B41/48 ,  C04B41/62 ,  C04B41/63 ,  C09D133/06

    Abstract: A concrete tile (I) is claimed, which is coated with a copolymer (A) with Tg -25 to +30 deg.C, derived from (a) 0.1-10 wt.% monomer of formula R1CH=CR2-CO-X-R3-Z-CHR4R5 (III), (b) 85-99.9 wt.% at least 2 monomers of the type (1-24C alkyl) (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, 3-6C unsatd. nitriles, vinyl halides and/or 2-8C non-aromatic hydrocarbons with olefinic double bond(s), and (c) 0-10 wt.% other Sn-free comonomers; R1, R2 = H or 1-4C alkyl; R3 = 1-20C bridging gp.; R4 = -COR6, -COOR6 or CN; R5 = H, -COR9, -COOR9 or CN; X = O or NR7; Z = single bond, CH2, O, NR8 or -OCO-; (with R6-R9 = H, or 1-12C alkyl, aryl, alkaryl or aralkyl). Also claimed is a process for the prodn. of (I), by application of an aq. prepn. contg. (A) to at least one surface of the green concrete, and drying the prepn. by hardening the concrete. More specifically, monomer (a) is acetylacetoxyethyl (meth)acrylate, acetylacetoxybutyl (meth)acrylate, cyanoacetoxyethyl (meth)acrylate, 1,1-dibenzoyl-2-(meth)acrylamidoethane, 1-benzoyl-1-acetyl-2- (meth)acrylamidoethane, or ethyl alpha-benzoyl-beta-(meth) acrylamidopropionate, and (b) are vinylaromatics or (1-8C alkyl) (meth)acrylates; (I) is coated with a prepn. contg. copolymer (A) and up to 450 wt.% mineral additives (B) and/or colour pigments (C) (w.r.t. amt. of A); another layer of the aq. prepn. is applied to the hardened tile and dried; the amt. of prepn. used is such that the total amt. of dry coating is 50-500 g/m2.

    Moulded prods., useful esp. as ceiling boards in damp rooms - contain finely-divided fillers, and condensate(s) of high-mol.wt. poly:carboxylic acid and poly:hydric alcohol, alkanolamine or amine
    44.
    发明专利
    Moulded prods., useful esp. as ceiling boards in damp rooms - contain finely-divided fillers, and condensate(s) of high-mol.wt. poly:carboxylic acid and poly:hydric alcohol, alkanolamine or amine 未知

    公开(公告)号：DE4012947A1

    公开(公告)日：1991-10-31

    申请号：DE4012947

    申请日：1990-04-24

    Applicant: BASF AG

    Inventor： DOTZAUER BERNHARD DR ,  BECKERLE WILHELM FRIEDRICH ,  SCHWARTZ MANFRED DR

    IPC: C08L33/02 ,  C08L33/06

    Abstract: (1) Moulded prods. (I) are claimed contg., as main components, finely-divided natural or synthetic materials (II) and condensation prods. (III) of high-mol. wt. polycarboxylic acids (IV) and polyhydric alcohols, alkanolamines or amines (V). (2) (I) are produced (a) by mechanically mixing (II) with an aq. mixt. of (IV) and (V) as binder, removing excess binder, moulding the resulting prod. and drying at 100-250 deg.C. or (b) by moulding (II) with binder, coating with the above aq. mixt. and dyring as in (b). - (I) contain 0.5-15 wt.% (III) based on equiv. amts. of (IV) and (V) (w.r.t. COOH and OH/amino gps.); (III) are based on polymeric acids contg. 5-50 mol.% COOH-contg. monomer units (pref. with K-value 50-100 in DMF at 25 deg.C.), pref. condensation prods. of (IV) and polymeric polyalcohols with K-value (see above) 40-80, esp. pref. condensates of (IV), trimethylolpropane, glycerol, 2-hydroxymethylbutane-1,4-diol, diethanolamine, triethanolamine, ethylenediamine or tetramethylenediamine; or (III) are condensates of (IV) contg. at least 50 mol.% COOH-contg. monomer units, pref. polymeric acids whose Na salts have K-value 90-130 in water at 25 deg.C. with trimethylolpropane, glycerol or 2-hydroxymethyl-butane-1,4-diol.

    46.
    发明专利
    未知

    公开(公告)号：DE1769528A1

    公开(公告)日：1972-01-13

    申请号：DE1769528

    申请日：1968-06-06

    Applicant: BASF AG

    Inventor： HOLZER KLAUS DR ,  MUELLER ALFRED DR ,  DOTZAUER BERNHARD DR

    IPC: C09J7/02 ,  C09J133/06 ,  C08F29/46

    Abstract: 1,264,524. Pressure sensitive adhesive coating. BADISCHE ANILIN-& SODA-FABRIK A.G. 5 June, 1969 [6 June, 1968], No. 28522/ 69. Heading B2E. [Also in Division C3] Articles such as adhesive tapes, adhesive sheeting and film, decorative sheeting, insulating tapes and textile floor coverings are provided with a pressure-sensitive adhesive layer of a copolymer comprising (a) 60-99.85% (by weight) of units of at least one ester of acrylic or methacrylic acid and a C 4 -C 10 alkanol; (b) 0.15-3% of a combination of (i) units of at least one monoester of an α, #- olefinically unsaturated monocarboxylic acid and a glycol and (ii) units of at least one N- alkoxymethylamide of an α, #-olefinically unsaturated carboxylic acid; and (c) 0-39% of units of at least one other mono olefinically unsaturated monomer; the glass temperature of the copolymer being from -60‹C to 0‹C. The glycol monoester monomers b (i) are suitably acrylate or methacrylate esters of alkane diols, cycloalkane diols or haloderivatives of such diols. Suitable as amide monomers b (ii) are those derived, for example, from acrylic, methacrylic, crotonic, maleic, fumaric or itaconic acid. Optional monomers (c) include (meth) acrylate esters other than those used as monomer (a) above, vinyl esters of saturated monocarboxylic acids, vinyl aromatic compounds such as styrene, monovinyl heterocyclic compounds such as vinyl pyridines, vinyl imidazole, vinyl caprolactam and vinyl pyrrolidone, unsaturated carboxylic acids and amides and nitriles thereof, vinyl ethers, vinyl ketones and vinyl or vinylidene halides. The pressure-sensitive adhesive layers are applied to an appropriate substrate material using a solution of the copolymer by conventional. methods, e.g. by pouring or using rollers or coating knives. The solvent component of the copolymer solutions may be selected from alkyl acetates, liquid aromatic hydrocarbons, liquid (cyclo) aliphatic ketones, liquid aliphatic chlorohydrocarbons, dimethylformamide, and aliphatic or heterocyclic ethers. The adhesive solutions may also contain other polymer components, e.g. polyisobutylenes, modified colophony resins and polycondensates of cyclohexanone or methylcyclohexanones, and dihydro abietyl phthalate. Substrate materials to which the adhesive layer can be applied include paper, aluminium foil, sheeting and film of polyethylene, polypropylene, polyvinyl chloride, polystyrene and polyethylene glycol terephthalate, wood veneers, bitumenised board, textile floor coverings and nonwovens, expanded plastics materials of polyurethane, polyether, polyethylene, polyvinyl chloride, natural rubber and synthetic rubber foams in sheet form.

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