-
41.
公开(公告)号:DE3560287D1
公开(公告)日:1987-07-30
申请号:DE3560287
申请日:1985-04-01
Applicant: BASF AG
Inventor: MUENCH VOLKER DR , HAMBRECHT JUERGEN DR , HIMMELE WALTER DR , ECHTE ADOLF DR , SWOBODA JOHANN DR
-
公开(公告)号:DE3462510D1
公开(公告)日:1987-04-09
申请号:DE3462510
申请日:1984-07-03
Applicant: BASF AG
Inventor: BERGER ROSEMARIE , DREHER HERMANN DR , HAMBRECHT JUERGEN DR , HEIL EDUARD , REFFERT RUDI WILHELM , SWOBODA JOHANN DR , ECHTE ADOLF DR , SIEBEL PETER DR
IPC: C08G65/46
Abstract: The catalyst is removed in the preparation of high molecular weight polyphenylene ethers from monohydric phenols, which are alkyl-substituted at the two ortho-positions but not at the para-position and may or may not be alkyl-substituted at the meta-position, by an oxidative coupling reaction with oxygen at from 15 DEG to 50 DEG C. in the presence of a catalyst complex obtained from a copper salt and an organic amine, in the presence of from 1 to 20 parts by weight of a solvent per part by weight of the monomeric phenol, and in the presence or absence of an activator, and removal of the metal component of the catalyst from the polyphenylene ether solution with a complex-forming or chelate-forming compound in aqueous solution, in the presence or absence of reducing and stabilizing substances and assistants for accelerating the interphase reactions and for phase separation, by a method in which the continuous removal of the copper catalyst is carried out in one or more mixer-settler stages at a phase volume ratio of the organic phase to the aqueous phase of from 1:0.1 to 1:1.0, preferably from 1:0.4 to 1:0.6.
-
公开(公告)号:DE3514870A1
公开(公告)日:1986-11-06
申请号:DE3514870
申请日:1985-04-25
Applicant: BASF AG
Inventor: MUENCH VOLKER DR , NAARMANN HERBERT DR , ECHTE ADOLF DR , HAMBRECHT JUERGEN DR , TAUBITZ CHRISTOF DR
Abstract: The invention relates to a thermoplastic moulding composition comprising: A a copolymer based on ABS, which is formed from an elastomer (rubber) based exclusively on butadiene, onto which a copolymer of a vinylaromatic monomer having 8 to 9 carbon atoms and acrylonitrile has been grafted, and a copolymer (hard matrix) built up from 50 to 90 % by weight of a vinylaromatic monomer having 8 to 9 carbon atoms and from 50 to 10 % by weight of acrylonitrile, and, in each case based on 100 parts by weight of A, B from 200 to 20 parts by weight of a poly(oxamide) having a viscosity index, VI, of from 8 to 80 ml/g which contains the structural unit of the formula (I) as a recurring copolymerised unit in the polymer chain, in which the radical R is a substituted or unsubstituted C2-C25-alkylidene, C5-C30-cycloalkylidene, C2-C80-oxaalkylidene group or a substituted or unsubstituted, monocyclic or polycyclic arylidene group, in which the arylidene radicals may be linked to one another via bifunctional groups. The moulding composition can contain conventional flameproofing agents C and/or a halogen-free component D (synergist for C) and conventional additives E. It is preferably used for the production of mouldings.
-
公开(公告)号:DE3510877A1
公开(公告)日:1986-10-02
申请号:DE3510877
申请日:1985-03-26
Applicant: BASF AG
Inventor: HOENL HANS DR , ECHTE ADOLF DR
IPC: C08F287/00 , C08L25/00 , C08L51/00 , C08L51/04 , C08L53/02
-
公开(公告)号:DE3363924D1
公开(公告)日:1986-07-10
申请号:DE3363924
申请日:1983-07-18
Applicant: BASF AG
Inventor: REFFERT RUDI WILHELM , HAMBRECHT JUERGEN DR , ECHTE ADOLF DR , SCHUSTER HANS H DR , DREHER HERMANN DR
IPC: C08G65/46
-
公开(公告)号:DE3427405A1
公开(公告)日:1986-01-30
申请号:DE3427405
申请日:1984-07-25
Applicant: BASF AG
-
公开(公告)号:DE3414119A1
公开(公告)日:1985-10-24
申请号:DE3414119
申请日:1984-04-14
Applicant: BASF AG
Inventor: MITULLA KONRAD DR , HAMBRECHT JUERGEN DR , ECHTE ADOLF DR , SWOBODA JOHANN DR , SIEBEL HANS-PETER DR , SCHWAAB JOSEF DR , FRANK HERBERT
Abstract: A thermoplastic molding material consists of a polycarbonate A and a graft copolymer B, the latter consisting of an elastomer (rubber) (b1) and a shell (b2) grafted onto the elastomer. The elastomer (b1) contains, as copolymerized units, from 35 to 100% by weight of a diene from the group consisting of the conjugated dienes of 4 to 5 carbon atoms, and can contain, as copolymerized units, from 0 to 65% by weight of a monomer from the group consisting of the alkyl acrylates or alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms. The shell (b2) is obtained in a conventional manner by successive polymerization of the monomers constituting the shell, in two process steps, in the presence of the elastomer (b1); in a first process step, from 10 to 90% by weight of a mixture of a vinylaromatic hydrocarbon and one or more ethylenically unsaturated monomers which differ from the said hydrocarbon, in a weight ratio of from 90:10 to 60:40, are first incorporated as copolymerized units, followed by the polymerization of from 90 to 10% by weight of a monomer from the group consisting of the alkyl acrylates or of the alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms. The molding material is used for the production of shaped articles.
-
公开(公告)号:DE3405876A1
公开(公告)日:1985-08-22
申请号:DE3405876
申请日:1984-02-18
Applicant: BASF AG
Inventor: PORTUGALL MICHAEL DR , ECHTE ADOLF DR , ILLERS KARL HEINZ DR , OSCHMANN WERNER DR
Abstract: The invention relates to glass-clear, thermoplastic moulding compositions comprising (A) a polymer of vinyl chloride, (B) a copolymer made from (b1) a methylstyrene and (b2) acrylonitrile, and (C) optionally assistants and additives, characterised in that the moulding compositions contain, as component (B), a copolymer which contains, as the methylstyrene (b1), p-methylstyrene copolymerised in a certain amount. The result is moulding compositions having good heat distortion resistance and excellent optical transparency.
-
公开(公告)号:DE3169997D1
公开(公告)日:1985-05-23
申请号:DE3169997
申请日:1981-09-10
Applicant: BASF AG
Inventor: BRANDSTETTER FRANZ DR , ECHTE ADOLF DR , NAARMANN HERBERT DR , PRIEBE EDMUND DR
-
公开(公告)号:DE3169996D1
公开(公告)日:1985-05-23
申请号:DE3169996
申请日:1981-09-10
Applicant: BASF AG
Inventor: BRANDSTETTER FRANZ DR , ECHTE ADOLF DR , GAUSEPOHL HERMANN DR , NAARMANN HERBERT DR
IPC: C08L25/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08L71/04
Abstract: Thermoplastic molding materials based on styrene polymers which have been made impact-resistant and on polyphenylene ethers, wherein the particles of the soft component of the styrene polymer which has been made impact-resistant have a mean diameter of more than 1 micron, and wherein the proportion of particles which have a diameter of less than 0.6 micron is not less than 40% by weight and the proportion of particles which have a diameter of from 0.6 to 3 microns is less than 3% by weight.
-
-
-
-
-
-
-
-
-