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公开(公告)号：DE3414118A1
公开(公告)日：1985-10-24
申请号：DE3414118
申请日：1984-04-14
Applicant: BASF AG
Inventor： MITULLA KONRAD DR , HAMBRECHT JUERGEN DR , ECHTE ADOLF DR , SWOBODA JOHANN DR , SIEBEL HANS-PETER DR , SCHWAAB JOSEF DR , FRANK HERBERT
Abstract: A thermoplastic molding material consists of from 10 to 90 parts by weight of a polycarbonate A and from 90 to 10 parts by weight of a graft copolymer B having a mean particle size of from 200 to 700 nm (d50 value of the integral mass distribution). The graft polymer B is formed from an elastomer (rubber) (b1), which accounts for from 10 to 80% by weight, and a grafted shell (b2), which accounts for from 90 to 20% by weight, the percentages in each case being based on (B). The elastomer (b1) is composed of from 50 to 99.9% by weight of an alkyl acrylate, where alkyl is of 1 to 8 carbon atoms, and from 0.1 to 5% by weight of a copolymerizable polyfunctional crosslinking monomer. The grafted shell (b2) is produced in three stages and contains, as graft monomers, (b2a1) from 5 to 40% by weight of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms, in the first stage, (b2a2) from 15 to 50% by weight of a mixture of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms and a copolymerizable ethylenically unsaturated monomer, in a weight ratio of from 90:10 to 60:40, in the second stage, and (b2a3) from 10 to 85% by weight of an alkyl (meth)acrylate in the third stage, the percentages in each case being based on (b2).
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Patent Agency Ranking
公开(公告)号：CA1255833A
公开(公告)日：1989-06-13
申请号：CA478835
申请日：1985-04-11
Applicant: BASF AG
Inventor： MITULLA KONRAD , HAMBRECHT JUERGEN , ECHTE ADOLF , SWOBODA JOHANN , SIEBEL PETER , SCHWAAB JOSEF , FRANK HERBERT
Abstract: - 20 - O.Z. 0050/37072 A thermoplastic molding material consists of a polycarbonate A and a graft copolymer B, the latter consisting of an elastomer (rubber) b1) and a shell b2) grafted onto the elastomer. The elastomer b1) contains, as copolymerized units, from 35 to 100% by weight of a diene from the group consisting of the conjugated dienes of 4 or 5 carbon atoms, and can contain, as copolymerized units, from 0 to 65% by weight of a monomer from the group consisting of the alkyl acrylates or alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms. The shell b2) is obtained in a conventional manner by successive polymerization of the monomers constituting the shell, in two process steps, in the presence of the elastomer b1); in a first process step, from 10 to 90% by weight of a mixture of a vinylaromatic hydrocarbon and one or more ethylenically unsaturated monomers which differ from the said hydrocarbon, in a weight ratio of from 90:10 to 60:40, are first incorporated as copolymerized units, followed by the polymerization of from 90 to 10% by weight of a monomer from the group consisting of the alkyl acrylates or of the alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms. The molding material is used for the production of shaped articles.
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公开(公告)号：CA1255832A
公开(公告)日：1989-06-13
申请号：CA478834
申请日：1985-04-11
Applicant: BASF AG
Inventor： MITULLA KONRAD , HAMBRECHT JUERGEN , ECHTE ADOLF , SWOBODA JOHANN , SIEBEL PETER , SCHWAAB JOSEF , FRANK HERBERT
Abstract: - 20- O.Z. 0050/37071 A thermoplastic molding material consists of from 10 to 90 parts by weight of a polycarbonate A and from 90 to 10 parts by weight of a graft copolymer B having a mean particle size of from 200 to 700 nm (d50 value of the integral mass distribution). The graft polymer B is formed from an elastomer (rubber) b1), which accounts for from 10 to 80% by weight, and a grafted shell b2), which accounts for from 90 to 20% by weight, the percentages in each case being based on B). The elastomer b1) is composed of from 50 to 99.9% by weight of an alkyl acrylate, where alkyl is of 1 to 8 carbon atoms, and from 0.1 to 5% by weight of a copolymerizable polyfunctional crosslinking monomer. The grafted shell b2) is produced in three stages and contains, as graft monomers, b2a1) from 5 to 40% by weight of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms, in the first stage, b2a2) from 15 to 50% by weight of a mixture of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms and a copolymerizable ethylenically unsaturated monomer, in a weight ratio of from 90:10 to 60:40, in the second stage, and b2a3) from 10 to 85% by weight of an alkyl (meth) acrylate in the third stage, the percentages in each case being based on b2).
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公开(公告)号：DE3414119A1
公开(公告)日：1985-10-24
申请号：DE3414119
申请日：1984-04-14
Applicant: BASF AG
Inventor： MITULLA KONRAD DR , HAMBRECHT JUERGEN DR , ECHTE ADOLF DR , SWOBODA JOHANN DR , SIEBEL HANS-PETER DR , SCHWAAB JOSEF DR , FRANK HERBERT
Abstract: A thermoplastic molding material consists of a polycarbonate A and a graft copolymer B, the latter consisting of an elastomer (rubber) (b1) and a shell (b2) grafted onto the elastomer. The elastomer (b1) contains, as copolymerized units, from 35 to 100% by weight of a diene from the group consisting of the conjugated dienes of 4 to 5 carbon atoms, and can contain, as copolymerized units, from 0 to 65% by weight of a monomer from the group consisting of the alkyl acrylates or alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms. The shell (b2) is obtained in a conventional manner by successive polymerization of the monomers constituting the shell, in two process steps, in the presence of the elastomer (b1); in a first process step, from 10 to 90% by weight of a mixture of a vinylaromatic hydrocarbon and one or more ethylenically unsaturated monomers which differ from the said hydrocarbon, in a weight ratio of from 90:10 to 60:40, are first incorporated as copolymerized units, followed by the polymerization of from 90 to 10% by weight of a monomer from the group consisting of the alkyl acrylates or of the alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms. The molding material is used for the production of shaped articles.
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公开(公告)号：DE3561736D1
公开(公告)日：1988-04-07
申请号：DE3561736
申请日：1985-04-01
Applicant: BASF AG
Inventor： MITULLA KONRAD DR , HAMBRECHT JUERGEN DR , ECHTE ADOLF DR , SWOBODA JOHANN DR , SIEBEL PETER DR , SCHWAAB JOSEF DR , FRANK HERBERT
Abstract: A thermoplastic molding material consists of a polycarbonate A and a graft copolymer B, the latter consisting of an elastomer (rubber) (b1) and a shell (b2) grafted onto the elastomer. The elastomer (b1) contains, as copolymerized units, from 35 to 100% by weight of a diene from the group consisting of the conjugated dienes of 4 to 5 carbon atoms, and can contain, as copolymerized units, from 0 to 65% by weight of a monomer from the group consisting of the alkyl acrylates or alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms. The shell (b2) is obtained in a conventional manner by successive polymerization of the monomers constituting the shell, in two process steps, in the presence of the elastomer (b1); in a first process step, from 10 to 90% by weight of a mixture of a vinylaromatic hydrocarbon and one or more ethylenically unsaturated monomers which differ from the said hydrocarbon, in a weight ratio of from 90:10 to 60:40, are first incorporated as copolymerized units, followed by the polymerization of from 90 to 10% by weight of a monomer from the group consisting of the alkyl acrylates or of the alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms. The molding material is used for the production of shaped articles.
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公开(公告)号：DE3561464D1
公开(公告)日：1988-02-25
申请号：DE3561464
申请日：1985-04-01
Applicant: BASF AG
Inventor： MITULLA KONRAD DR , HAMBRECHT JUERGEN DR , ECHTE ALDOLF DR , SWOBODA JOHANN DR , SIEBEL PETER DR , SCHWAAB JOSEF DR , FRANK HERBERT
Abstract: A thermoplastic molding material consists of from 10 to 90 parts by weight of a polycarbonate A and from 90 to 10 parts by weight of a graft copolymer B having a mean particle size of from 200 to 700 nm (d50 value of the integral mass distribution). The graft polymer B is formed from an elastomer (rubber) (b1), which accounts for from 10 to 80% by weight, and a grafted shell (b2), which accounts for from 90 to 20% by weight, the percentages in each case being based on (B). The elastomer (b1) is composed of from 50 to 99.9% by weight of an alkyl acrylate, where alkyl is of 1 to 8 carbon atoms, and from 0.1 to 5% by weight of a copolymerizable polyfunctional crosslinking monomer. The grafted shell (b2) is produced in three stages and contains, as graft monomers, (b2a1) from 5 to 40% by weight of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms, in the first stage, (b2a2) from 15 to 50% by weight of a mixture of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms and a copolymerizable ethylenically unsaturated monomer, in a weight ratio of from 90:10 to 60:40, in the second stage, and (b2a3) from 10 to 85% by weight of an alkyl (meth)acrylate in the third stage, the percentages in each case being based on (b2).
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