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    PROCESS FOR THE PREPARATION OF POLY(PHENYLENE ETHERS) AND THEIR USE FOR THE PRODUCTION OF MOULDED ARTICLES
    44.
    发明专利
    PROCESS FOR THE PREPARATION OF POLY(PHENYLENE ETHERS) AND THEIR USE FOR THE PRODUCTION OF MOULDED ARTICLES 未知

    公开(公告)号：DE3560286D1

    公开(公告)日：1987-07-30

    申请号：DE3560286

    申请日：1985-04-01

    Applicant: BASF AG

    Inventor： MUENCH VOLKER DR ,  HAMBRECHT JUERGEN DR ,  HIMMELE WALTER DR ,  ECHTE ADOLF DR ,  SWOBODA JOHANN DR

    IPC: C08G65/44 ,  C08L71/04

    Abstract: High molecular weight polyphenylene ethers are prepared from monohydric phenols by an oxidative coupling reaction with oxygen in the presence of a solvent and of a catalyst complex consisting of a copper salt and an organic amine of the general formula where R1 is C2-C20-alkylidene, preferably C2-C12-alkylidene, or alkenylidene, R2 is H or C1-C12-alkyl, preferably C1-C4-alkyl, or C5-C8-cycloalkyl, each of which is unsubstituted or substituted by functional groups, and n is an integer from 1 to 4, preferably 1 or 2. Preferred functional groups are -OR3, -NHR3 or -SR3, in which R3 is H C1-C12-alkyl or C5-C8-cycloalkyl, and the most suitable amines are 3-tert.-butoxypropylamine, 4-tert.-butoxybutylamine, 3-tert.-butoxy-2-methylpropylamine, 3-tert.-butoxy-2,3-dimethylpropylamine, 3-tert.-butoxy-2-methyloctylamine and N-methyl-N-(4-tert.-butoxybutyl)-amine. The polyphenylene ethers can be processed to moldings by a thermoplastic method.

    CYCLOHEXANE 1,3-DIONE DERIVATIVES
    46.
    发明专利
    CYCLOHEXANE 1,3-DIONE DERIVATIVES 未知

    公开(公告)号：DE3365427D1

    公开(公告)日：1986-09-25

    申请号：DE3365427

    申请日：1983-05-13

    Applicant: BASF AG

    Inventor： JAHN DIETER DR ,  BECKER RAINER DR ,  KEIL MICHAEL DR ,  HIMMELE WALTER DR ,  WUERZER BRUNO DR

    IPC: A01N35/06 ,  A01N37/44 ,  C07C131/00 ,  C07C101/34 ,  C07C97/07

    Abstract: Cyclohexane-1,3-dione derivatives of the formula I I where R1 is cycloalkyl of 3 to 12 carbon atoms which may or may not be olefinically monounsaturated to tetraunsaturated, can be substituted by not more than 3 methyl or ethyl groups, one vinyl, methylvinyl or allyl group, 1 or 2 chlorine atoms or one alkoxy group of 1 to 4 carbon atoms and can be bridged by an alkylene chain of not more than 4 carbon atoms, X is alkylene of 1 to 5 carbon atoms, which can be monounsaturated or diunsaturated, interrupted by not more than 2 sulfur or oxygen atoms and substituted by not more than 3 alkyl groups of 1 to 3 carbon atoms, R2 is hydrogen of alkoxycarbonyl where alkoxy is of 1 to 2 carbon atoms, R3 is alkyl of 1 to 4 carbon atoms, R4 is alkyl of 1 to 3 carbon atoms, alkenyl of 3 or 4 carbon atoms, propargyl or haloalkenyl of 3 or 4 carbon atoms and 1 to 3 halogen atoms, and the salts of these compounds, processes for their preparation, herbicides containing these compounds, and their use.

    50.
    发明专利
    未知

    公开(公告)号：DE3414237A1

    公开(公告)日：1985-10-24

    申请号：DE3414237

    申请日：1984-04-14

    Applicant: BASF AG

    Inventor： MUENCH VOLKER DR ,  HAMBRECHT JUERGEN DR ,  HIMMELE WALTER DR ,  ECHTE ADOLF DR ,  SWOBODA JOHANN DR

    IPC: C08G65/44

    Abstract: High molecular weight polyphenylene ethers are prepared from monohydric phenols by an oxidative coupling reaction with oxygen in the presence of a solvent and of a catalyst complex consisting of a copper salt and an organic amine of the general formula where R1 is C2-C20-alkylidene, preferably C2-C12-alkylidene, or alkenylidene, R2 is H or C1-C12-alkyl, preferably C1-C4-alkyl, or C5-C8-cycloalkyl, each of which is unsubstituted or substituted by functional groups, and n is an integer from 1 to 4, preferably 1 or 2. Preferred functional groups are -OR3, -NHR3 or -SR3, in which R3 is H C1-C12-alkyl or C5-C8-cycloalkyl, and the most suitable amines are 3-tert.-butoxypropylamine, 4-tert.-butoxybutylamine, 3-tert.-butoxy-2-methylpropylamine, 3-tert.-butoxy-2,3-dimethylpropylamine, 3-tert.-butoxy-2-methyloctylamine and N-methyl-N-(4-tert.-butoxybutyl)-amine. The polyphenylene ethers can be processed to moldings by a thermoplastic method.

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