43.
    发明专利
    未知

    公开(公告)号:DE3150234A1

    公开(公告)日:1983-06-30

    申请号:DE3150234

    申请日:1981-12-18

    Applicant: BASF AG

    Abstract: A mixture of Z- and E-2-[2-methylprop-1-en-1-yl]-4-methyltetrahydropyran isomers, of the formulae Z-I and E-I containing not less than 85% of Z-I and not more than 15% of E-I, is prepared by a process wherein 2-[2-methylprop-1-en-1-yl]-4-methylenetetrahydropyran of the formula II II is hydrogenated over a platinum dioxide or platinum/charcoal catalyst in the presence of a strongly acidic cation exchanger. The product is a useful fragrance material which also occurs naturally and is known as rose oxide.

    47.
    发明专利
    未知

    公开(公告)号:DE2925043A1

    公开(公告)日:1981-01-15

    申请号:DE2925043

    申请日:1979-06-21

    Applicant: BASF AG

    Abstract: 2-(1-methyl-eth-1-en-1-yl)-,2-(1-methyl-prop-1-en-1-yl)-, 2-(eth-1-en-1-yl)- and 2-(prop-1-en-1-yl)-4-methyl-2,3-dihydro-6H-pyrans substituted in the 2-position of the side chain by hydroxymethyl, acyloxymethyl, alkoxycarbonylmethyl, halomethyl or formyl. The novel 4-methyl-2,3-dihydro-6H-pyrans are obtained by reaction of 3-methyl-but-3-en-1-ol with an appropriately substituted unsaturated aldehyde in the presence of an acid catalyst. The products possess very interesting organoleptic properties.

    49.
    发明专利
    未知

    公开(公告)号:DE2831676A1

    公开(公告)日:1980-02-07

    申请号:DE2831676

    申请日:1978-07-19

    Applicant: BASF AG

    Abstract: Bis-epoxy-dialkoxy-alkanes are valuable intermediates for the preparation of the sought-after aromatic 2,5-dimethyl-4-hydroxy-2,3-dihydrofuran-3-one. The novel bis-epoxy-dialkoxy-alkanes are obtained by reacting the corresponding alpha , alpha '-dihalo-1,2-diketones with an alkali metal hydroxide or an alkali metal alkoxide and an alkanol at from -20 DEG to +100 DEG C. To prepare the 2,5-dialkyl-4-hydroxy-2,3-dihydro-furan-3-ones, which are valuable aromatics, the novel bis-epoxy-dialkoxy-alkanes are heated with strong mineral acids or strong organic acids at from 60 DEG to 120 DEG C.

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