Weather resistant thermoplastic moulding materials for e.g. car parts

    公开(公告)号:DE19508312A1

    公开(公告)日:1996-09-12

    申请号:DE19508312

    申请日:1995-03-09

    Applicant: BASF AG

    Abstract: Thermoplastic moulding materials (I) contg. (A) 30-90 wt% thermoplastic polymer with a Tg of more than 20 deg C; (B) 10-70 wt% of a graft copolymer derived from (b1) 30-90 wt% grafting base with a Tg of below 10 deg C, based on (b11) 50-99.94 wt% (1-30C alkyl) acrylate(s), (b12) 0-49.9 wt% unsatd. comonomer and (b13) 0.01-10 wt% of a mixt. of dihydro-dicyclo- pentadienyl acrylate (DCPA) and other difunctional crosslinking monomer(s), and (b2) 10-70 wt% of a grafted shell derived from (b21) 50-95 wt% vinylaromatic monomer and (b22) 5-50 wt% polar comonomer(s), i.e. (meth)acrylonitrile, (1-20C alkyl) (meth)acrylate(s), maleic anhydride, (meth)acrylamide and/or vinyl 1-8C alkyl ether(s); (C) 0-50 wt% fibrous and/or particulate filler(s); and (D) 0-30 wt% normal additives etc.

    Thermoplastic aromatic polycarbonate moulding compsns. - contain polyphenylene ether] graft copolymer, styrene] copolymer and vinyl]-aromatic polymer

    公开(公告)号:DE4200247A1

    公开(公告)日:1993-07-15

    申请号:DE4200247

    申请日:1992-01-08

    Applicant: BASF AG

    Abstract: Compsns. (I) comprise (A) 50-90% (all pts.wt.) at least one aromatic polycarbonate; (B) 3-25% at least one polyphenylene ether; (C) 3-25% at least one graft polymer comprising (C1) 40-80 % graft core of rubber-eleastic polymer with Tg below 10 deg. C (C2) 20-60% graft shell comprising (C2.1) 50-95% opt. substd. styrene of formula (1) (where R1 is 1-8C alkyl or H; R2 is 1-8C alkyl; and n is 0-3) and/or Me (meth)acrylate (C2.2) 5-50% (meth)acrylonitrile, Me (meth)acrylate, maleic anhydride, and/or N-(1-8C alkyl)- or N-(6-20C aryl)-maleimide; (D) 3-40% thermoplastic copolymer of (D1) 50-95% at least one styrene of formula (1) (D2) 5-50% (meth)acrylonitrile, Me (meth)acrylate, maleic anhydride, and/or N-(1-8C alkyl)- or N-(6-20C aryl)-maleimide; and (E) 1-20% at least one vinyl aromatic polymer. Opt. (I) also contain (F) up to 20% at least one P cpd. of formula (2) (where R3, R4, R5 are halogen-free 1-8C alkyl or halogen-free 6-20C aryl opt. substd. by 1 or 2 (1-4C) alkyl; (G) up to 2% tetrafluoroethylene polymer; (H) up to 25% rubber different from (C). USE/ADVANTAGE - Prepn. of fibres, films, and shaped articles (claimed) for use in e.g., motor car mfr., building, office machines, and electrical and household appts., partic. by extrusion, injection moulding, calendering, blow moulding, pressing, or sintering. (I) have balanced property profile, partic. increased heat-dimensional stability.

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