公开(公告)号：BR0309653A

公开(公告)日：2005-03-01

申请号：BR0309653

申请日：2003-05-02

Applicant: BASF AG

Inventor： HOFSTADT OTTO ,  HESSE MICHAEL ,  SCHINDLER GOETZ-PETER ,  HARTH KLAUS ,  SIMON FALK

IPC: B01J23/62 ,  B01J21/06 ,  B01J23/63 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  B01J23/24 ,  B01J23/40 ,  B01J23/70 ,  C07C5/327

Abstract: The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.

公开(公告)号：DE10237514A1

公开(公告)日：2004-02-26

申请号：DE10237514

申请日：2002-08-16

Applicant: BASF AG

Inventor： SCHINDLER GOETZ-PETER ,  HARTH KLAUS

IPC: B01J23/62 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06

Abstract: In an isothermal method for dehydrogenation of alkanes (I) to the corresponding alkenes (II) over a bed of dehydrogenation catalyst (A), the new feature is that the bed contains a catalytically inactive, inert diluent (B).

公开(公告)号：DE10217844A1

公开(公告)日：2003-11-06

申请号：DE10217844

申请日：2002-04-22

Applicant: BASF AG

Inventor： BORGMEIER FRIEDER ,  ROSOWSKI FRANK ,  SCHINDLER GOETZ-PETER

IPC: C07C253/26 ,  C07C255/08 ,  C07C255/06

Abstract: Process for production of unsaturated nitriles from corresponding alkanes comprises: (1) catalytic dehydrogenation; (2) at least partial separation of other gaseous components from the alkane and alkene; and (3) catalytic ammoxidation of the alkene to form the corresponding unsaturated nitrile. Process for production of unsaturated nitriles from corresponding alkanes comprises: (A) feeding an alkane to a dehydrogenation zone with catalytic dehydrogenation of the alkane to the corresponding alkene to form a product gas stream comprising the alkene, unreacted alkane and optionally at least one further gaseous component comprising water vapor, hydrogen, carbon oxides, low boiling point hydrocarbons (lower than that of the alkane and alkene) and noble gas; (B) at least partial separation of the other gaseous components from gas stream (A) to yield a feed gas stream comprising alkane and alkene; (C) feeding the gas stream from (B), ammonia, an oxygen containing gas and optionally water vapor into an oxidation zone with catalytic ammoxidation of the alkene to form the corresponding unsaturated nitrile, byproducts, unreacted alkane and alkene and optionally at least one of water vapor, oxygen, carbon oxides, ammonia, nitrogen and noble gas; (D) optional separation of ammonia from gas stream (C) to yield an ammonia poor gas stream (D); (E) separation of the unsaturated nitrile and byproducts from (C) and/or (D) by absorption in an aqueous absorption agent to yield a gaseous stream containing unreacted alkane and alkene and optionally at least one of oxygen, carbon oxides, ammonia, nitrogen and noble gases and an aqueous stream comprising the nitrile and byproducts with recovery of the unsaturated nitrile from the aqueous stream; and (F) recycling of the gaseous stream from (E) to the dehydrogenation zone.

公开(公告)号：DE10213492A1

公开(公告)日：2003-10-09

申请号：DE10213492

申请日：2002-03-26

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  HEIDEMANN THOMAS ,  SCHINDLER GOETZ-PETER ,  STEPHAN JUERGEN ,  MAAS HEIKO

IPC: C07C15/00 ,  C07C309/31 ,  C11D1/22 ,  C07C2/66 ,  C07C2/08 ,  C07C5/22 ,  C07C5/327 ,  C07C6/04 ,  C07C15/02 ,  C07C303/02 ,  C07C309/28

Abstract: Preparation of alkylaryl compounds comprises production of a 12C-olefin mixture and reaction of the 12C-olefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkylaromatic compounds whereby additional linear olefins are added before the reaction. A process for the preparation of alkylaryl compounds (I) comprises: (A) production of a 12C-olefin mixture by trimerization of butenes or dehydrogenation of 12C-alkanes, with optionally pre- or post isomerization, or by the production of a 12C-olefin mixture by oligomerization of ethene, followed by isomerization; and (B) reaction of the 12C-olefin mixture from (A) with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkylaromatic compounds whereby additional linear olefins are added before the reaction. Independent claims are included for: (1) a process for the production of alkylarylsulfonates (II) by sulfonation and neutralization of alkylaryl compounds (I); (2) the alkylaryl compounds (I); (3) the alkylarylsulfonates (II); and (4) washing- or cleaning agents containing the alkylarylsulfonates (II).

公开(公告)号：NO20032501A

公开(公告)日：2003-06-03

申请号：NO20032501

申请日：2003-06-03

Applicant: BASF AG

Inventor： SCHINDLER GOETZ-PETER ,  MAGIN WERNER ,  HARTH KLAUS

IPC: B01J38/14 ,  B01J23/62 ,  B01J23/90 ,  B01J23/96 ,  B01J38/12 ,  B01J38/18 ,  B01J

CPC classification number: B01J23/96 ,  B01J23/90 ,  B01J38/12 ,  B01J38/18 ,  C07C5/48 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/63 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06

公开(公告)号：NO20031351D0

公开(公告)日：2003-03-25

申请号：NO20031351

申请日：2003-03-25

Applicant: BASF AG

Inventor： SCHINDLER GOETZ-PETER ,  MACHHAMMER OTTO ,  HARTH KLAUS ,  MUELLER-ENGEL KLAUS JOACHIM ,  ZEHNER PETER

IPC: C07C5/333 ,  B01J23/58 ,  B01J23/62 ,  B01J23/63 ,  B01J23/96 ,  B01J38/14 ,  C07B61/00 ,  C07C5/32 ,  C07C11/06 ,  C07C5/48

Abstract: In a process for the heterogeneously catalyzed dehydrogenation in one or more reaction zones of one or more dehydrogenatable C 2 -C 30 -hydrocarbons in a reaction gas mixture comprising them, with at least part of the heat of dehydrogenation required being generated directly in the reaction gas mixture in at least one reaction zone by combustion of hydrogen, the hydrocarbon or hydrocarbons and/or carbon in the presence of an oxygen-containing gas, the reaction gas mixture comprising the dehydrogenatable hydrocarbon or hydrocarbons is brought into contact with a Lewis-acid dehydrogenation catalyst which has essentially no Brönsted acidity.

公开(公告)号：DE10131297A1

公开(公告)日：2003-01-09

申请号：DE10131297

申请日：2001-06-29

Applicant: BASF AG

Inventor： PROLL THEO ,  MACHHAMMER OTTO ,  SCHINDLER GOETZ-PETER ,  MUELLER-ENGEL KLAUS JOACHIM

IPC: C07C45/34 ,  B01J27/199 ,  C07B61/00 ,  C07C45/33 ,  C07C45/35 ,  C07C47/22 ,  C07C51/235 ,  C07C57/055 ,  C07C253/26 ,  C07C255/08 ,  C07B41/00 ,  C07B43/04 ,  C07C45/28 ,  C07C57/04

Abstract: Production of partial oxidation products and/or partial ammoxidation products of an olefinic hydrocarbon comprises intermittent operation in a non-operational phase by at least partial non-operation of the dehydration stage whereby the oxidation- and/or ammoxidation zone is continued to be operated and the deficiency in olefinic hydrocarbon feedstock is compensated by another source. A process for the production of partial oxidation products and/or partial ammoxidation products of at least one olefinic hydrocarbon (I) comprises (A) partial dehydration and/or oxy-dehydration of a paraffinic hydrocarbon in a first reaction zone to form a product mixture comprising unreacted paraffinic hydrocarbon and olefinic hydrocarbon (I). (B) separation of the product mixture from (A) into paraffinic and olefinic components optionally in a separation zone and feeding of either the olefinic or paraffinic component to an oxidation and/or ammoxidation zone to form at least one partial oxidation and/or ammoxidation product that contains an olefinic hydrocarbon (I). (C) separation of the product mixture from (B) in a processing zone and recycle of at least a portion of unreacted paraffinic hydrocarbon to the reaction zone of step (A) and (D) from time to time in a non-operational phase at least partial non-operation of the first reaction zone whereby the oxidation- and/or ammoxidation zone (B) is continued to be operated and the deficiency in olefinic hydrocarbon feedstock is at least partially compensated by another source of olefinic hydrocarbon and optionally paraffinic hydrocarbon arising from sources other than reaction zone (A) is at least partially recycled to the oxidation and/or ammoxidation zone (B).

公开(公告)号：DE10047642A1

公开(公告)日：2002-04-11

申请号：DE10047642

申请日：2000-09-26

Applicant: BASF AG

Inventor： SCHINDLER GOETZ-PETER ,  MACHHAMMER OTTO ,  HARTH KLAUS ,  MUELLER-ENGEL KLAUS JOACHIM ,  ZEHNER PETER

IPC: C07C5/333 ,  B01J23/58 ,  B01J23/62 ,  B01J23/63 ,  B01J23/96 ,  B01J38/14 ,  C07B61/00 ,  C07C5/32 ,  C07C11/06 ,  C07B35/04

Abstract: The invention relates to a method for the heterogenically catalysed dehydrogenation of one or several C2-C30 hydrocarbons that can be dehydrogenated, in one or several reaction zones, in a reaction gas mixture containing said hydrocarbons. According to said method, at least one portion of the required dehydrogenation heat is generated directly in the reaction gas mixture in at least one reaction zone by the combustion of hydrogen, the hydrocarbon(s) and/or of carbon in the presence of a gas containing oxygen, said reaction gas mixture, which contains the hydrocarbon(s) that can be dehydrogenated, being brought into contact with a Lewis-acidic dehydrogenation catalyst that essentially exhibits no Brönsted acidity.

公开(公告)号：DE10028582A1

公开(公告)日：2001-12-20

申请号：DE10028582

申请日：2000-06-14

Applicant: BASF AG

Inventor： MACHHAMMER OTTO ,  SCHINDLER GOETZ-PETER ,  TENTEN ANDREAS ,  HARTH KLAUS ,  ZEHNER PETER ,  MUELLER-ENGEL KLAUS JOACHIM ,  ROSOWSKI FRANK ,  BORGMEIER FRIEDER

IPC: C07C27/14 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C45/33 ,  C07C45/35 ,  C07C47/22 ,  C07C51/215 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05 ,  C07C57/07 ,  C07C45/78

Abstract: Molecular nitrogen is used as a diluent gas in the partial oxidation stage of a 3-stage method for the production of acrolein and acrylic acid from propane by: (A) partial gas-phase dehydrogenation; (B) removal of hydrogen and partial gas-phase oxidation of propene; and (C) separation of product and recycling of unreacted propane to stage (A). Acrolein and acrylic acid are produced from propane by: (A) partial gas-phase dehydrogenation of propane in presence of a heterogeneous catalyst to form a mixture (A) containing molecular hydrogen, propene and unreacted propane; (B) removing at least some of the hydrogen from the components other than propane and propene to give a mixture (A'), feeding (A') into oxidation reactor(s) and subjecting the propylene to selective, gas-phase partial oxidation in presence of heterogeneous catalyst to give a gas mixture (B) containing acrolein and acrylic acid; and (C) separating the required product and recycling unreacted propane (at least) to stage (A). In this process, molecular nitrogen is used as diluent gas in the partial oxidation stage (B).

公开(公告)号：BRPI0606630A2

公开(公告)日：2010-01-19

申请号：BRPI0606630

申请日：2006-01-16

Applicant: BASF AG

Inventor： SCHINDLER GOETZ-PETER ,  CRONE SVEN ,  BORGMEIER FRIEDER ,  DUDA MARK ,  SIMON FALK ,  KLANNER CATHARINA

IPC: C07C5/333 ,  C07C11/167

Abstract: A process for preparing butadiene, comprising A) providing a stream (a) comprising n-butane; B) feeding stream (a) comprising into at least one first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to obtain a stream (b) comprising n-butane, 1-butene, 2-butene, butadiene, hydrogen and low-boiling secondary constituents; C) feeding stream (b) and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating n-butane, 1-butene and 2-butene to obtain a stream (c) comprising n-butane, 2-butene, butadiene, low-boiling secondary constituents, carbon oxides and steam, wherein stream (c) has a higher content of butadiene than stream (b); D) removing the low-boiling secondary constituents and steam to obtain a stream (d) substantially consisting of n-butane, 2-butene and butadiene; E) separating stream (d) into a stream (e1) consisting substantially of n-butane and 2-butene and a stream (e2) consisting substantially of butadiene by extractive distillation; F) recycling stream (e1) into the first dehydrogenation zone.