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公开(公告)号:DE19702424A1
公开(公告)日:1998-07-30
申请号:DE19702424
申请日:1997-01-24
Applicant: BASF AG
Inventor: FISCH HERBERT DR , WEBER MARTIN DR , SAUERER WOLFGANG DR , WELZ MARTIN
IPC: B41M5/26 , C08L67/02 , C08L69/00 , C08L77/00 , C08L101/00 , C08L25/02 , C08J7/18 , C08L25/06 , C08L59/00 , C08L67/00 , H01S3/225
Abstract: The invention concerns a method of inscribing by means of high-energy radiation mouldings based on thermoplastic polymers A) or mixtures of these polymers with up to 70 wt %, relative to the total weight of the components, of further additives and processing aids. The invention is characterized in that a vinylaromatic polymer B) is used as additive for improving inscribability, this polymer having been modified by the incorporation of at least one functional group selected from the series comprising carbonyl, carboxylic acid, acid anhydride, acid amide, acid imide, carboxylic acid ester, carboxylate, amino, hydroxyl, epoxy, oxazolin, urethane, urea, lactam or benzyl halide groups.
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公开(公告)号:DE19638256A1
公开(公告)日:1998-03-26
申请号:DE19638256
申请日:1996-09-19
Applicant: BASF AG
IPC: C08F265/04 , C08L25/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L53/02 , C08J5/18 , C08L51/06 , C08L25/06 , C08L25/16 , C08J5/00 , C08L33/20 , C08J3/20 , D06N3/04
Abstract: Thermoplastic moulding compounds contain: (A) 30 to 98 wt % of a graft polymer which consists of (ak) 30 to 90 wt % of a cross-linked acrylic rubber graft nucleus; (as) 10 to 70 wt % of a graft shell made of (as/1) 50 to 100 wt % of a styrene compound, of an acrylic or methacrylic acid (C1-C8-alkyl)ester, or of a mixture of the styrene compound and the acrylic or methacrylic acid (C1-C8-alkyl)ester; and (as/2) 0 to 50 wt % of one or several other monomers; (B) 1 to 50 wt % of a thermoplastic polymer; and (C) 1 to 70 wt % of a rubber elastic block copolymer.
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公开(公告)号:DE19615230A1
公开(公告)日:1997-10-23
申请号:DE19615230
申请日:1996-04-18
Applicant: BASF AG
Inventor: GAREIS BRIGITTE DR , SCHNEIDER HANS-MICHAEL DR , WEBER MARTIN DR
IPC: C08K3/32 , C08K5/5399 , C08L51/04 , C08L55/02 , C08L67/02 , C08L69/00 , C08J3/20 , C08J5/00 , C08J5/18 , D01F6/62 , C08L59/02 , C08G79/02 , C09K21/14 , H01H71/02
Abstract: Fireproofed thermoplastic moulding masses contain: (A) 5 to 99 % by weight of a thermoplastic polymer; (B) 0.1 to 50 % by weight of a phosphazene of general formula (I) (PN2-xH1-y)z, in which x, y and z independently stand for the following numeric values: 1 > x > 0.05; 1 > y > 0.05; and z > 1; and (C) 0 to 70 % by weight of other additives and processing aids, the sum of the percentages by weight of components (A) to (C) being 100 %.
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44.
公开(公告)号:DE19542519A1
公开(公告)日:1997-05-22
申请号:DE19542519
申请日:1995-11-15
Applicant: BASF AG
Inventor: WEBER MARTIN DR , NIKOLAI HARTMUT , GUENTHERBERG NORBERT DR
IPC: C08L25/02 , C08L33/06 , C08L51/00 , C08L51/06 , B29C45/16 , B29C47/30 , C08K3/26 , C08L25/00 , C09D125/00 , C09D133/06 , C09D151/06
Abstract: - Moulding composition contains (A) 1-97 wt.% graft copolymer of (a1) 30-90 wt.% graft substrate, obtained by copolymerisation of (a11) 80-99.99 wt.% 1-10 carbon (C) alkyl acrylate, (a12) 0.01-20 wt.% crosslinking monomer and (a13) 0-40 wt.% other monomer and (a2) 10-70 wt.% grafted component of (a21) 50-100 wt.% vinyl-aromatic compound(s) of formula (I) and/or 1-10 C alkyl (meth)acrylate(s) and (a22) 0-50 wt.% other monomer; (B) 1-97 wt.% polymer, having a glass transition temperature Tg of 10 deg C, of (c1) 50-100 wt.% (I), (c2) 0-50 wt.% (meth)acrylonitrile and (c3) 0-50 wt.% other monomer and (D) 0-40 wt.% additives; in which R = hydrogen (H) or 1-10 C alkyl; R = 1-10 C alkyl; n = 0, 1, 2 or 3.
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公开(公告)号:DE19540312A1
公开(公告)日:1997-04-30
申请号:DE19540312
申请日:1995-10-28
Applicant: BASF AG
Inventor: WEBER MARTIN DR , WEIS ROBERT DR , HECKMANN WALTER DR , HINGMANN ROLAND DR , MC KEE GRAHAM EDMUND DR
Abstract: Moulding materials (MM), containing (A) 1-96.5 wt% halogen- free polycarbonate(s), (B) 1-96.5 wt% halogen-free graft copolymer consisting of (b1) 40-80 wt% rubber-elastic grafting base with a Tg of below 0 deg C and (b2) 20-60 wt% grafted shell derived from (b21) 50-95 wt% vinylaromatic monomers of formula (I), in which R = H or 1-8C alkyl; R = 1-8C alkyl; n = 0, 1, 2 or 3; and/or MMA, and (b22) 5-50 wt% (meth)acrylonitrile, MMA and/or maleic anhydride, (C) 1-96.5 wt% halogen-free thermoplastic copolymer with an average mol. wt. (Mw) of less than 400,000, derived from (c1) 50-95 wt% monomer (I) and/or MMA and (c2) 5-50 wt% comonomer(s) as in (b22), (D) 0.5-30 wt% halogen-free thermoplastic copolymer with a Mw of at least 800,000 and a wide mol. wt. distribution, derived from (d1) 50-95 wt% monomer(s) (I), (d2) 5-50 wt% comonomers as in (b22) and (d3) 0-15 wt% mono-unsaturated comonomers with at least one polar functional group, (E) 1-25 wt% halogen-free phosphorus compound(s) and (F) 0-50 wt% additives. Also claimed are mouldings, film and fibres containing MM.
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公开(公告)号:DE19524585A1
公开(公告)日:1997-01-09
申请号:DE19524585
申请日:1995-07-06
Applicant: BASF AG
Inventor: WEBER MARTIN DR , HOFMANN JUERGEN , WEIS ROBERT DR , HECKMANN WALTER DR , HINGMANN ROLAND DR , WUENSCH JOSEF DR , MC KEE GRAHAM EDMUND DR
IPC: C08F2/14 , C08F12/00 , C08F12/06 , C08L25/00 , C08L25/06 , C08L71/12 , C08L101/00 , D01F6/46 , D01F6/66 , D01F6/94 , C08L53/02 , C08L21/00 , C08K5/49 , D01F1/07
Abstract: Halogen-free antidrip agents for thermoplastic molding compounds contain polymers based on vinyl aromatic monomers with molecular weights (Mw) of at least 800 000 g/mol and a narrow molecular weight distribution.
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公开(公告)号:DE19513848A1
公开(公告)日:1996-10-17
申请号:DE19513848
申请日:1995-04-12
Applicant: BASF AG
Inventor: WEBER MARTIN DR , FISCH HERBERT DR , PIPPER GUNTER , GOTTSCHALK AXEL DR
IPC: C08J5/18 , C08L71/00 , C08L71/10 , C08L71/12 , C08L77/00 , C08L77/06 , C08L79/08 , D01F6/74 , D01F6/80 , D01F6/90 , H01B3/38
Abstract: Thermoplastic moulding materials (I) contg. (A) 1-99 wt% partly aromatic copolyamide contg. (a1) 30-44 mole% terephthalic acid (TPA) units, (a2) 6-25 mole% isophthalic acid (IPA) units, (a3) 43-49.5 mole% hexamethylenediamine (HMDA) units and (a4) 0.5-7 mole% units derived from 6-30C cyclic aliphatic diamines; (B) 1-99 wt% polyether-imide; (C) 0-30 wt% polymeric component with OH gps.; (D) 0-60 wt% fibrous and/or particulate fillers; (E) 0-40 wt% impact modifying rubber; and (F) 0-40 wt% conventional additives, etc.. Also claimed are fibres, films and moulded prods. obtd. from (I).
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公开(公告)号:DE19501998A1
公开(公告)日:1996-07-25
申请号:DE19501998
申请日:1995-01-24
Applicant: BASF AG
Inventor: GOTTSCHALK AXEL DR , FISCH HERBERT DR , PIPPER GUNTER , WEBER MARTIN DR
IPC: C08G69/26 , C08L25/04 , C08L33/10 , C08L51/04 , C08L55/02 , C08L77/00 , C08L77/06 , C08L25/00 , C08L33/06 , D01F6/90 , D01F6/56 , D01F6/52
Abstract: A thermoplastic moulding material (I) contains: (A) 5-94 wt.% of a partly aromatic, partly crystalline copolyamide derived from: (a1) 30-44 mole% terephthalic acid (TPA) units; (a2) 6-20 mole% isophthalic acid (IPA) units; (a3) 43-49.5 mole% hexamethylenediamine (HMDA) units; and (a4) 0.5-7 mole% units derived from 6-30C cyclic aliphatic diamines; (B) 5-94 wt.% ABS, ASA or SAN polymer and/or a polymer of (1-18C alkyl) (meth)acrylate; (C) 1-30 wt.% of a coupling agent contg. 0.1-10 wt.% functional monomers (w.r.t. 100 wt.% C.); (D) 0-30 wt.% of a rubber-elastic polymer; (E) 0-45 wt.% of a fibrous and/or particulate filler; and (F) 0-30 wt.% of conventional additives and processing aids. Also claimed are moulded prods. obtd. from (I).
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公开(公告)号:DE4444378A1
公开(公告)日:1996-06-20
申请号:DE4444378
申请日:1994-12-14
Applicant: BASF AG
Inventor: WEBER MARTIN DR , FISCH HERBERT DR , PIPPER GUNTER , GOTTSCHALK AXEL DR
IPC: C08L33/24 , C08L77/00 , C08L77/06 , C08L101/06 , C08L21/00
Abstract: Thermoplastic moulding materials (I) contain (A) 1-98.5 wt.% partly aromatic copolyamide, (B) 1-98.5 wt.% polymethacrylimide, (C) 0.5-30 wt.% polymeric component with OH gps., (D) 0-60 wt.% fibrous and/or particulate filler(s), (E) 0-40 wt.% impact-modifying rubber and (F) 0-40 wt.% conventional additives etc. Also claimed are fibres, film and mouldings made from (I).
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公开(公告)号:DE59302212D1
公开(公告)日:1996-05-23
申请号:DE59302212
申请日:1993-01-15
Applicant: BASF AG
Inventor: WEBER MARTIN DR , MUEHLBACH KLAUS DR , SEITZ FRIEDRICH DR
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