公开(公告)号：EP0628034B1

公开(公告)日：2000-12-20

申请号：EP93903976.4

申请日：1993-02-16

Applicant: BASF Aktiengesellschaft

Inventor： HAMPRECHT, Gerhard ,  MAYER, Horst ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias ,  KARDORFF, Uwe ,  WALTER, Helmut

IPC: C07D251/16 ,  A01N47/36

CPC classification number: A01N47/36 ,  C07D251/16

Abstract: N-[(1,3,5-triazine-2-yl)aminocarbonyl]benzene sulphonamide herbicides of generic formula (I), wherein R1 represents methyl or ethyl; R2 represents hydrogen or methyl; R3 represents optionally substituted alkyl, or a group OR?5 or SR5¿, in which R5 represents optionally fluorine substituted alkyl, except difluoromethoxy, or nitro, hydroxy; R4 represents hydrogen, methyl, ethyl, methoxy, ethoxy, methylthio, ethylthio, C¿1?-C2 halogen alkoxy, fluorine, chlorine, except 6-chlorine and 6-fluorine when R?3¿ represents an alkyl or C¿1?-C2 alkoxy; as well as their agriculturally usable salts and process for their manufacture and use.

公开(公告)号：EP0788479A1

公开(公告)日：1997-08-13

申请号：EP95936508.0

申请日：1995-10-17

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： HEISTRACHER, Elisabeth ,  PLATH, Peter ,  VON DEM BUSSCHE-HÜNNEFELD, Christoph-Sweder ,  HAMPRECHT, Gerhard ,  KLINTZ, Ralf ,  SCHÄFER, Peter ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut ,  GERBER, Matthias ,  MISSLITZ, Ulf

IPC: C07D403 ,  A01N37 ,  A01N43 ,  C07C205 ,  C07C229 ,  C07D209 ,  C07D417 ,  C07F7

CPC classification number: C07D209/48 ,  A01N37/46 ,  C07C205/56 ,  C07C229/44 ,  C07F7/0812

Abstract: Disclosed are substituted phthalimido-cinnamic acid derivatives of formula (I), wherein R1 is H, C¿1?-C4-alkyl; R?2¿ is H, halogen; R3 is CN, NO¿2?, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkoxy, C1-C6-alkoxy halide; R?4¿ is H, CN, NO¿2?, halogen, C1-C6-alkyl; R?5¿ is H, C¿1?-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, substituted C1-C6-alkyl; R?6¿ is one of the radicals indicated under R5 or CN, NO¿2?, C1-C6-alkoxy, C1-C6-alkoxy halide, C1-C6-alkyl thio, C1-C6 alkyl thio halide, C3-C6-cycloalkyl, sustituted alkyl, C3-C6-alkenyl halide, (C1-C6-alkoxy)-carbonyl, COOH, (C1-C6-alkyl amino)carbonyl, di-(C1-C6-alkyl)amino carbonyl, (C1-C6-alkyl) carbonyl, (C1-C6-alkyl halide) carbonyl, optionally substituted aryl, hetaryl, aryl C1-C6 alkyl or hetaryl C1-C6 alkyl; or R?5 and R6¿ together are an alkylene chain, in which a methylene unit can be substituted a C¿1?-C4-alkyl imino group; R?7¿ is H, C¿1?-C6-alkyl, C3-C6-alkenyl, C3-C6 alkinyl, C2-C6 alkyl halide, C1-C6 cyanoalkyl, C1-C6 alkoxy C2-C6 alkyl, C1-C6-alkyl thio C2-C6 alkyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl, optionally substituted phenyl or benzyl; X is O, S or N(R?8¿), as well as the salts of formula (I). Disclose also is their use as herbicides and for desication/defoliation of plants.

公开(公告)号：EP0777654A1

公开(公告)日：1997-06-11

申请号：EP95930493.0

申请日：1995-08-18

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： HEISTRACHER, Elisabeth ,  RÜB, Lothar ,  VON DEM BUSSCHE-HÜNNEFELD, Christoph-Sweder ,  HAMPRECHT, Gerhard ,  KLINTZ, Ralf ,  SCHÄFER, Peter ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias ,  WALTER, Helmut

IPC: C07D231 ,  A01N43

CPC classification number: A01N43/56

Abstract: N-Phenyltetrahydroindazoles of formula (I), where R1 is H or C¿1-4?-alkyl; R?2¿ is halogen, C¿1-4?-alkyl or C1-4-haloalkyl; R?3¿ is H or halogen; R4 is NO¿2?, halogen, C1-4-alkyl or C1-4-haloalkyl; R?5 is -XR6¿; X is -O-, -S-, -SO- or -SO¿2-; R?6 is -Alk-R7; Alk is a substituted or unsubstituted methylene, ethylene, propylene, butylene or pentamethylene chain, where one chain member can carry a spiro-linked 2- to 5-membered C chain or where 2 ring members can be bridged via a C¿1-5?-alkylene chain; R?7¿ is CN, SCN, halogen or -YR11, where Y is -O-, -S-, -SO- or -SO¿2-; R?10 is H, OH, C¿1?-C4-alkyl, C1-C4-haloalkyl, C3-C5-cycloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C5-cycloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, -NH-R?12¿, -N(C¿1?-C4-alkyl)-R?12¿, -N(C¿3?-C4-alkenyl)-R?12¿, -N(C¿3?-C4-alkynyl)-R?12¿, pyrrolidin-1-yl, piperid-1-yl, morpholin-4-yl, azepan-1-yl, (i) unsubstituted or substituted phenyl, benzyl, phenoxy or benzyloxy; R11 is C¿1-6?-alkyl, C1-6-haloalkyl or C1-6-cycloalkyl; R?12¿ is H, OH, C¿1-4?-alkyl, C3-4-alkenyl, C3-4-alkynyl, C3-6-cycloalkyl, C1-4-alkoxy, C3-4-alkenyloxy, C3-4-alkenyloxy, C3-4-alkynyloxy, or substituted or unsubstituted phenyl or benzyl; and the agriculturally utilizable salts of formula (I), with the provisoes that the simultaneous meaning of R?6¿ as dihalomethyl, R?2 and R4¿ as chlorine and R3 as halogen is excluded; the simultaneous meaning of X as oxygen and R?7 as -OR11 or C¿1-C6-alkylthio is excluded; Alk must not carry a spiro-linked three-membered ring if R7 is halogen and R11 is not C¿1-6?-alkyl if R?1¿ is H, R2 is C¿1-4?-haloalkyl, R?3¿ is F, R4 is halogen and R?7 is -OR11¿. Use: as herbicides; for desiccating/defoliating plants.

公开(公告)号：EP0775136A1

公开(公告)日：1997-05-28

申请号：EP95927734.0

申请日：1995-07-27

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： PLATH, Peter ,  VON DEYN, Wolfgang ,  ENGEL, Stefan ,  KARDORFF, Uwe ,  KÖNIG, Hartmann ,  RANG, Harald ,  GERBER, Matthias ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto

IPC: A01N43 ,  A01P13 ,  C07D417

CPC classification number: C07D417/06 ,  A01N43/80

Abstract: The disclosure is of 5-hydroxypyrazol-4-yl-carbonyl-substituted saccharin derivatives of formula (I), in which the substituents have the following meanings: L,M stand for hydrogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, chlorine, cyano, methylsulphonyl, nitro or trifluoromethyl; Z stands for hydrogen, C1-C4 alkyl, C3-C8 cycloalkyl, C3-C6-alkenyl, C3-C5-alkinyl, C1-C4 acyl, benzyl or phenyl (the phenyl rings optionally being each substituted by a halogen or C1-C4 alkyl); Q stands for a CO-J group; J stands for a 5-hydroxypyrazol ring linked at position 4 and of formula (II), in which R1 represents C¿1?-C4 alkyl, and R?2¿ represents hydrogen or methyl. Also disclosed are the salts of formula (I) compounds commonly used in agriculture.

公开(公告)号：EP0775125A1

公开(公告)日：1997-05-28

申请号：EP95929016.0

申请日：1995-07-27

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： PLATH, Peter ,  VON DEYN, Wolfgang ,  ENGEL, Stefan ,  KARDORFF, Uwe ,  NÜBLING, Christoph ,  KÖNIG, Hartmann ,  RANG, Harald ,  GERBER, Matthias ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto

IPC: C07D275 ,  A01N43

CPC classification number: C07D275/06 ,  A01N43/80

Abstract: The invention concerns saccharine derivatives of the formula (I) in which the substituents are defined as follows: L, M hydrogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, chlorine, cyano, methylsulphonyl, nitro or trifluoromethyl; Z hydrogen, C1-C4 alkyl, C3-C8 cycloalkyl, C3-C6 alkenyl, C3-C5 alkinyl, C1-C4 acyl, benzyl or phenyl, wherein any of the phenyl rings may be substituted by halogen or C1-C4 alkyl; R1 cyclopropyl, 1-methylcyclopropyl, 1-methylthiocyclopropyl or tert.-butyl. The invention also concerns salts of such compounds usually used in agriculture.

公开(公告)号：EP0625975B1

公开(公告)日：1996-08-14

申请号：EP93917360.5

申请日：1993-01-30

Applicant: BASF Aktiengesellschaft

Inventor： MISSLITZ, Ulf ,  MEYER, Norbert ,  KAST, Juergen ,  BOTT, Kaspar ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto ,  KARDORFF, Uwe ,  GERBER, Matthias

IPC: C07D309/06 ,  C07D335/02 ,  C07C251/54 ,  C07C323/47 ,  A01N43/16 ,  A01N43/18 ,  A01N35/10

CPC classification number: A01N43/18 ,  A01N35/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/56 ,  A01N43/80 ,  C07C251/54 ,  C07C323/47 ,  C07C2601/16 ,  C07D261/08 ,  C07D309/06 ,  C07D333/22 ,  C07D335/02

Abstract: Cyclohexenone oxime ethers of formula (I) where R1 = C1-C6 alkyl; W = a C2-C4 alkylene chain optionally substituted by C1-C3 alkyl; X = NO2, CN, halogen, C1-C4 alkyl, C1-C4 halogen alkyl; n = 0-3 or 1-5 if all the X subsituents are halogen; R2 = C1-C4-alkoxy-C1-C6-alkyl, C1-C4-alkythio-C1-C6-alkyl, optionally substituted C3-C7 cycloalkyl, optionally substituted C5-C7 cycloalkenyl, optionally substituted 5-membered saturated heterocyclic ring containing 1 or 2 oxygen and/or sulphur atoms, optionally substituted 6 or 7-membered heterocyclic ring with 1 or 2 non-adjacent oxygen and/or sulphur atoms which may be saturated or singly or doubly unsaturated, optionally substituted aromatic 5-membered heterocyclic ring containing one to two N atoms and one O or S atom, phenyl or pyridyl both of which may bear 1-3 substituents: halogen, NO2, CN, alkyl, alkoxy, alkylthio, halogen alkyl, alkenyloxy, alkinyloxy and/or -NRaRb; Ra = H, alkyl, alkenyl, or alkinyl and Rb = H, alkyl, alkenyl, alkinyl, acyl or optionally substituted benzoyl; and their agriculturally usable salts, and esters of C¿1?-C10 carboxylic acids and inorganic acids of compounds (I).

Abstract translation: PCT号 PCT / EP93 / 00215秒。 371 8月11日，1994年二段。 102（e）中的日期1994年8月11日提交的PCT 1993年1月30日的PCT公布。 号 WO93 / 16063的PCT公布。 日期8月19日1993.Cyclohexenone肟醚I I R1 = C1-C6烷基; W = unsubstituiertem或C1-C3烷基取代的C2-C4亚烷基链; X = NO 2，CN，卤素，C1-C4烷基，C1-C4卤代烷基; N = 0-3或1-5个，如果所有的X是卤素; R2 = C1-C4烷氧基C1-C6烷基，C1-C4烷硫基C1-C6烷基，substituiertem奥德unsubstituiertem C3-C7环烷基，substituiertem奥德unsubstituiertem C5-C7环烯基，substituiertem奥德unsubstituiertem 5- 元饱和杂环含有1或2个氧和/或硫原子，substituiertem奥德unsubstituiertem 6-或7-元杂环具有1个或2个非相邻的氧和/或硫原子间隔，且是饱和的或单 - 或多二不饱和，substituiertem奥德unsubstituiertem 5元杂芳族含1个或2个N原子和一个O或S原子，苯基或吡啶基，这两者都是unsubstituiertem或承担1-3个卤素，NO2，CN，烷基，烷氧基，烷基硫代，卤代烷基，链烯氧基，炔氧基和 /或-NRaRb的取代基; RA = H，烷基，烯基或炔基和R b = H，烷基，烯基，炔基，酰基或substituiertem奥德unsubstituiertem苯甲酰基; 及其农业利用的盐和式I化合物与C 1 -C 10羧酸和无机酸的酯。

公开(公告)号：EP0716653A1

公开(公告)日：1996-06-19

申请号：EP94925477.0

申请日：1994-08-25

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： SCHÄFER, Peter ,  KLINTZ, Ralf ,  HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias ,  WALTER, Helmut

IPC: A01N43 ,  C07D239 ,  C07D405 ,  C07D409 ,  C07D411

CPC classification number: C07D239/54 ,  A01N43/54 ,  C07D405/10 ,  C07D409/10 ,  C07D411/10

Abstract: Substituted 1-amino-3-phenyluracils (I), where the variables have the following meanings: R1 = H, F, Cl; Y = O, S; W = -CH=N-OH, -CH=N-O-(alkyl), -CH=N-O-(alkylene)-O-(alkyl), -CH=N-O-CH¿2?-COOH, -CH=N-O-CH(alkyl)-COOH, -CH=N-O-CH2-CO-O-(alkyl), -CH=N-O-CH(alkyl)-CO-O-(alkyl), -CH=N-O-CH2-CO-O-(alkylene)-O-(alkyl), -CH=N-O-CH(alkyl)-CO-O-(alkylene)-O-(alkyl), -CH=CH-CO-O-(alkyl), -CH=CH-CO-O-(alkylene)-O-(alkyl), -CH=C(Cl)-CO-O-(alkyl), -CH=C(Br)-CO-O-(alkyl), -CH=C(Cl)-CO-O(alkylene)-O-(alkyl), -CH=C(Br)-CO-O-(alkylene)-O-(alkyl), -CH=C(CH3)-CO-O-(alkyl), -CH=C(CH3)-CO-O-(alkylene)-O-(alkyl), -CH[X?1¿-(alkyl)][X2-(alkyl)] or a radical (a), (b), X1-X6 = O, S; R2-R11 = H, alkyl, vinyl, alkoxycarbonyl are described. Use: herbicides; desiccation/defoliation of plants.

公开(公告)号：EP0680481A1

公开(公告)日：1995-11-08

申请号：EP94905039.0

申请日：1994-01-12

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： PLATH, Peter ,  RENTZEA, Costin ,  MEYER, Norbert ,  KAST, Juergen ,  KARDORFF, Uwe ,  GERBER, Matthias ,  WALTER, Helmut ,  LANDES, Andreas ,  WESTPHALEN, Karl-Otto

IPC: A01N43 ,  C07D221 ,  C07D491

CPC classification number: C07D491/04 ,  A01N43/42 ,  A01N43/90 ,  C07D221/08

Abstract: A process is disclosed for controlling undesirable plant growth and for regulating plant growth, by applying to the plants derivatives of azaanthraquinones and/or azaxanthones having formula (I), in which X, Y, Z and the residues R1 to R5 have the following meanings: R1 is hydrogen, methyl; R2-R5 are (a) hydrogen, (b) halogen, (c) nitro, (d) COOR6, in which R6 stands for C¿1?-C4-alkyl, (e) CONH2 and CONR?6R7¿, in which R?6 and R7¿ stand for C¿1?-C4-alkyl, (f) C1-C8-alkyl, which may bear one to three of the following substituents: halogen, hydroxy, C1-C6-alkoxy, (g) C3-C6-alkenyl, (h) C1-C4-alkoxy, (i) hydroxy, (j) amino or NR?6R7¿, (k) phenyl, which may bear one to five halogen atoms or one to three of the following substituents: nitro, C¿1?-C4-alkoxy, C1-C4-alkyl or C1-C4alkyl halide; X, Y are N, N?+-O-¿ or CH, with the proviso that only a nitrogen atom or a N-oxide group be contained in the ring; Z is oxygen, sulphur or a C = O group; A is oxygen or sulphur. Also disclosed are new azaanthraquinones and azaxanthones and herbicidal and bioregulatory agents containing the same.

公开(公告)号：EP0666848A1

公开(公告)日：1995-08-16

申请号：EP94900070.0

申请日：1993-10-19

Applicant: BASF Aktiengesellschaft

Inventor： KLINTZ, Ralf ,  HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  SCHAEFER, Peter ,  KARDORFF, Uwe ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias ,  WALTER, Helmut

IPC: A01N37 ,  A01N43 ,  C07C233 ,  C07C323 ,  C07C327 ,  C07D211

CPC classification number: C07C233/54 ,  A01N37/46 ,  C07D211/84 ,  C07D211/88 ,  C07D211/90

Abstract: Substituted N-phenylglutarimides (I), wherein X1, X2 = O, S; R1 = halogen, NO¿2?, CN, CF3; R?2¿ = H, halogen; R?3, R4, R5¿ = H, halogen, CN, alkyl, cycloalkyl, alkenyl, alkinyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkyl thio halide, cyanoalkyl, alkoxy carbonyl, possibly substituted phenyl or benzyl, or 2 substituents of a C atom of the glutarimide ring are linked via a possibly substituted chain, or 2 substituents of adjacent C atoms of the glutarimide ring are linked via a possibly substituted chain; A = CHR6-CHR7-CO-B or CR6=CR8-CO-B; R6 = H, C¿1?-C6-alkyl or C1-C6-alkyl halide; R?7¿ = halogen, alkyl halide, OH, alkoxy or alkyl carbonyl alkoxy; R8 = H, halogen, CN, alkyl, alkyl halide, OH, alkoxy, alkyl carbonyl, alkoxy carbonyl or alkyl carbonyloxy; B = H, alkyl, alkenyl, alkinyl, alkyl halide, cycloalkyl, alkoxy alkyl, dialkoxy alkyl, alkyl thioalkyl, OR?9, SR9, NR10, R11; R9¿ = H, alkyl, alkenyl, alkinyl, cycloalkyl, alkyl halide, cyanoalkyl, alkenyl halide, alkoxy carbonyl alkyl, alkoxyalkyl, alkyl thioalkyl, alkylimino, alkylimino alkyl, possibly substituted phenyl or benzyl; R10, R11 = H, alkyl, alkenyl, alkinyl, cycloalkyl, alkyl halide, alkyl carbonyl, alkoxy carbonyl, alkoxy alkyl, possibly substituted phenyl, or R?10 und R11¿ together with the common N atom = saturated or unsaturated 4- to 7- membered heterocycle with 1-2 other heteroatoms, as well as salts of (I) that are tolerable to plants; their preparation and use as herbicides and desiccants/defoliants, as well as preproducts for preparing the N-phenylglutarimides (I).

公开(公告)号：EP0599892A1

公开(公告)日：1994-06-08

申请号：EP92916831.0

申请日：1992-08-05

Applicant: BASF Aktiengesellschaft

Inventor： MISSLITZ, Ulf ,  MEYER, Norbert ,  KAST, Juergen ,  BRATZ, Matthias ,  HARREUS, Albrecht ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias

IPC: A01N31 ,  A01N35 ,  A01N39 ,  A01N41 ,  A01N43 ,  A01P13 ,  C07C317 ,  C07C323 ,  C07D261 ,  C07D333

CPC classification number: C07D333/28 ,  A01N35/10 ,  A01N39/00 ,  C07C317/30 ,  C07C323/47 ,  C07C2601/02 ,  C07C2601/14 ,  C07C2601/16 ,  C07D333/16

Abstract: Des oximéthers de cyclohexénone ont la formule générale (I), dans laquelle n vaut 0 à 5; m vaut 0 à 2; R1 désigne alkyle C1-C6; R2 désigne alkyle C1-C4 ou benzyle; A désigne alcylène C1-C6 éventuellement substitué, alcénylène C3-C6 éventuellement substitué, alcinylène C3-C6 éventuellement substitué, une chaîne alcylène C3-C6 ou alcénylène C4-C6 éventuellement substituée, dans lesquels un groupe méthylène peut être susbstitué par O, S, SO, SO2 ou -N(Ra)-; Ra désigne H, alkyle C1-C4, alcényle C3-C6, alcinyle C3-C6; Z désigne phényle, un hétéroaromate à 5 éléments ou un hétéroaromate à 6 éléments ayant de 1 à 4 atomes de N; X désigne NO2, CN, halogène, alkyle C1-C4, alkyle halogéné C1-C4, alcoxy C1-C4, alkylthio C1-C4, alcoxy halogéné C1-C4, COOH, alcoxycarbonyle C1-C4, benzyloxycarbonyle éventuellement substitué, phényle éventuellement substitué, pyridyle éventuellement substitué, -NRbRc; Rb désigne H, alkyle C1-C4, alcényle C3-C6, alcinyle C3-C6; Rc désigne H, alkyle C1-C4, alcényle C3-C6, alcinyle C3-C6, acyle C1-C6, benzoyle éventuellement substitué. Ces composés (I), ainsi que leurs sels et esters d'acides carboxyliques C1-C10 et d'acides anorganiques utiles en agriculture, sont utiles comme herbicides.

Abstract translation: 环己烯酮肟醚具有式（I），其中n为0至5; m为0〜2; R1代表C1-C6烷基; R2代表C1-C4烷基或苄基; A代表C 1 -C 6亚烷基，C 3 -C 6亚烯基，C 3 -C 6亚炔基，C 3 -C 6亚烷基或C 4 -C 6亚烯基链，所有这些元素任选被取代。 在它们的每一个中，亚甲基可被O，S，SO，SO 2或-N（R a） - 取代。 R a代表H，C 1 -C 4烷基，C 3 -C 6烯基，C 3 -C 6炔基; Z代表具有1至4个N原子的苯基，5元杂芳族化合物或6元杂芳族化合物; X代表NO 2，CN，卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷氧基，COOH，C 1 -C 4烷氧基羰基，任选取代的苄氧基羰基，任选取代的苯基， 取代的吡啶基，-NRbRc; R b代表H，C 1 -C 4烷基，C 3 -C 6烯基，C 3 -C 6炔基，R c代表H，C 1 -C 4烷基，C 3 -C 6烯基，C 3 -C 6炔基C 1 -C 6酰基，任选取代的苯甲酰基。 具有式（I）的化合物，以及它们在农业中有用的C1-C10羧酸和无机酸的盐和酯，适用作除草剂。