Abstract:
The invention relates to a method for producing phosphorous-containing polymers, by reacting organic polymers, which contain carbon-carbon double bonds, with dialkyl phosphites in the presence of organic compounds forming free radicals under reaction conditions, by covalent bonding of phosphorous atoms of the dialkyl phosphite to a carbon atom of the organic polymer.
Abstract:
Disclosed are expandable thermoplastic polymer particles containing A) 45 to 97.8 percent by weight of a styrene polymer, B1) 1 to 45 percent by weight of a polyolefin having a melting point ranging from 105 to 140°C, B2) 0 to 25 percent by weight of a polyolefin having a melting point below 105°C, C1) 0.1 to 25 percent by weight of a block polymer or graft polymer that has a minimum mean molecular weight Mw of 100,000 g/mol and contains a) at least one block S comprising 95 to 100 percent by weight of vinyl aromatic monomers and 0 to 5 percent by weight of dienes, and b) at least one copolymer block (S/B) A comprising 63 to 80 percent by weight of vinyl aromatic monomers and 20 to 37 percent by weight of dienes having a glass transition temperature TgA ranging from 5 to 30°C, wherein the total percentage by weight of all blocks S ranges from 50 to 70 percent by weight relative to the block polymer or graft polymer A, C2) 0 to 20 percent by weight of a styrene-butadiene or styrene-isoprene block copolymer that differs from C1, C3) 0.1 to 9.9 percent by weight of a styrene-ethylene-butylene block copolymer, D) 1 to 15 percent by weight of a blowing agent, E) 0 to 5 percent by weight of a nucleation agent, wherein A) to E) total 100 percent by weight.
Abstract:
A block copolymer with a weight-average molecular weight M w of at least 100 000 g/mol, comprising a) at least one block S formed from 95 to 100% by weight of vinylaromatic monomers and 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B) A formed from 63 to 80% by weight of vinylaromatic monomers and 20 to 37% by weight of dienes with a glass transition temperature Tg A in the range from 5 to 30°C, and c) at least one copolymer block (S/B) B formed from 20 to 60% by weight of vinylaromatic monomers and 40 to 80% by weight of dienes with a glass transition temperature Tg B in the range from 0 to ‑80°C, where the proportion by weight of the sum of all blocks S is in the range from 50 to 70% by weight, and the proportion by weight of the sum of all blocks (S/B) A and (S/B) B is in the range from 30 to 50% by weight, based in each case on the block copolymer A, and also mixtures thereof and the use thereof.
Abstract:
A mixture which comprises a)from 95 to 30% by weight of a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90°C, b) from 5 to 45% by weight of a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from -70° to 0°C, c) from 0 to 40% by weight of polystyrene C, and d) from 0 to 30% by weight of a block copolymer D comprising at least one copolymer block (B/S)A which is respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90°C, and at least one diene block B or a copolymer block (B/S)B which is respectively composed of from 1 to 60% by weight of vinylaromatic monomers and of from 99 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from -100° to 0°C, d) from 0 to 6% by weight of a plastifying agent, and its use for the production of packaging for electronics components.
Abstract:
The present invention relates to a method for producing functionalized isotactic polystyrene, functionalized isotactic polystyrene that can be produced according to the method of the invention, the use of the functionalized isotactic polystyrene according to the invention as a macromonomer, a method for producing a macroinitiator, a macroinitiator that can be produced according to the method mentioned above, the use of the macroinitiator for controlled radical polymerization, the use of the functionalized isotactic polystyrene according to the invention as a macromonomer, preferably in the copolymerization with olefins, the ROMP with cycloolefins or for coupling with silicon segments, a method for epoxidating the functionalized isotactic polystyrene according to the invention, epoxidized isotactic polystyrene that can be produced according to the method mentioned above, and a method for producing soft thermoplastic elastomers (TPE) by metathesis polymerization of the functionalized isotactic polystyrene according to the invention using suitable polymers, which comprise terminal double bounds, and soft thermoplastic elastomer that can be produced according to the invention.
Abstract:
Disclosed are expandable styrene polymers (EPS) containing, in relation to the styrene polymer, a) 0.05 to 5 percent by weight of an organic bromine compound containing a minimum of 50 percent by weight of bromine as a flameproofing agent, b) 0.05 to 2 percent by weight of a flameproofing synergist, c) 1 to 5 percent by weight of a metallic salt as an acid collector. Also disclosed is a method for producing said expandable styrene polymers.
Abstract:
A mixture which comprises a)from 95 to 30% by weight of a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90°C, b) from 5 to 45% by weight of a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from -70° to 0°C, c) from 0 to 40% by weight of polystyrene C, and d) from 0 to 30% by weight of a block copolymer D comprising at least one copolymer block (B/S)A which is respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90°C, and at least one diene block B or a copolymer block (B/S)B which is respectively composed of from 1 to 60% by weight of vinylaromatic monomers and of from 99 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from -100° to 0°C, d) from 0 to 6% by weight of a plastifying agent, and its use for the production of packaging for electronics components.
Abstract:
The invention relates to a mixture, comprising a) 5 to 50 wt. % of a block copolymer (A), with one or more block copolymers (B/S)A, each made from 65 to 95 wt. % vinylaromatic monomers and 35 to 5 wt. % dienes with a glass transition temperature TgA in the range 40° to 90 °C, b) 95 to 50 wt. % of a block copolymer B, with at least one hard block (S) made from vinylaromatic monomers and one or more copolymer blocks (B/S)B, each made from 20 to 60 wt. % vinylaromatic monomers and 80 to 40 wt. % dienes and a glass temperature TgB in the range -70° to 0 °C, c) 0 to 45 wt. % of a block copolymer (C) different from (A) and (B), or polystyrol and d) 0 to 6 wt. % of a plastifier and the use thereof for the production of shrink films.