公开(公告)号：JP2005264014A

公开(公告)日：2005-09-29

申请号：JP2004079601

申请日：2004-03-19

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： OSHIMA NOBORU ,  EHATA SATOSHI

IPC: C08J5/18 ,  C08F232/00 ,  C08J7/00 ,  C08K5/00 ,  C08L45/00

Abstract: PROBLEM TO BE SOLVED: To provide a cycloolefinic resin composition which is capable of forming a crosslink or a quasi-crosslink due to a carboxylic group generated in the molecule of a commercially producible cycloolefinic addition polymer under a specific condition. SOLUTION: The cycloolefinic resin composition contains component A which is a cycloolefinic addition polymer obtained by addition-polymerizing a cycloolefinic monomer having a -(CHR 2 ) k -C(O)OR 1 group (wherein, R 1 is a trialkylsilyl group containing at least one 1-15C alkyl group, cycloalkyl group or aryl group or 2-10C alkyl group; R 2 is a hydrogen atom, a 1-10C alkyl group, a cycloalkyl group or an aryl group; and k is an integer of 0-5) and a cycloolefinic monomer not having such a group and component B which is a thermo acid generator generating an acid at ≥50°C. The method of treatment of the molding comprises bringing the molding containing the resin composition into contact with water or steam with a temperature of ≥90°C. The film and the sheet are obtained by the method. COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 待解决的问题：提供一种环烯烃树脂组合物，其能够在特定条件下由于在可商购的环烯烃加成聚合物的分子中产生的羧基而形成交联或准交联。 解决方案：环烯烃树脂组合物含有组分A，其是通过加成聚合具有 - （CHR 2）2 - 的环烯单体而获得的环烯加成聚合物，-C （O）OR 1 基团（其中，R SP> 1是含有至少一个1-15C烷基，环烷基或芳基或2-10C烷基的三烷基甲硅烷基 R 2是氢原子，1-10C烷基，环烷基或芳基; k是0-5的整数）和不具有这种基团的环烯烃单体和 组分B，其是在≥50℃产生酸的热酸发生剂。 处理成型的方法包括将含有树脂组合物的模塑物与≥90℃的温度的水或蒸汽接触。 通过该方法获得膜和片材。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2005126514A

公开(公告)日：2005-05-19

申请号：JP2003361785

申请日：2003-10-22

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： OSHIMA NOBORU ,  EHATA SATOSHI ,  OKITA KENZO ,  SAKABE NOBUYUKI ,  HAYASHI TOSHIHITO

IPC: C08K5/00 ,  C08F4/70 ,  C08F232/08 ,  C08L45/00

Abstract: PROBLEM TO BE SOLVED: To provide a cycloolefin copolymer in which a structural unit (a) derived from a specific cycloolefin compound having a methoxysilyl group and a structural unit (b) derived from another cycloolefin compound are randomly arranged in a uniform composition distribution, wherein the copolymer has good optical transparency and heat resistance and a small coefficient of linear expansion and is used as a suitable material for a sheet or film for an optical material, and to provide a crosslinked cycloolefin copolymer obtained by crosslinking the copolymer and methods for producing these copolymers. SOLUTION: The cycloolefin addition copolymer comprises 70-98 mol% of a structural unit (a) derived from bicyclo[2.2.1]hept-2-ene and 2-20 mol% of a structural unit (b) derived from a specific cycloolefin compound having a methoxysilyl group, wherein the copolymer has a number average molecular weight of 30,000-300,000 and is soluble in toluene and cyclohexane at 25°C. COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 待解决的问题：提供一种环烯烃共聚物，其中衍生自具有甲氧基甲硅烷基的特定环烯烃化合物的结构单元（a）和由另一种环烯烃化合物衍生的结构单元（b））以均匀组成随机排列 分布，其中共聚物具有良好的光学透明性和耐热性，并且具有小的线膨胀系数，并且被用作用于光学材料的片材或膜的合适材料，并且提供通过交联共聚物获得的交联环烯烃共聚物和方法 用于制备这些共聚物。 解决方案：环烯加成共聚物包含70-98mol％的衍生自双环[2.2.1]庚-2-烯和2-20mol％结构单元（b）的结构单元（a），衍生自 具有甲氧基甲硅烷基的特定环烯烃化合物，其中共聚物的数均分子量为30,000-300,000，并且在25℃下可溶于甲苯和环己烷。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2003212927A

公开(公告)日：2003-07-30

申请号：JP2002015388

申请日：2002-01-24

Applicant: JSR CORP

Inventor： MARUYAMA YOICHIRO ,  OSHIMA NOBORU ,  SAWADA KATSUTOSHI

IPC: G02B5/02 ,  C08F32/00 ,  C08J5/18 ,  G02B1/04 ,  G02B5/30

Abstract: PROBLEM TO BE SOLVED: To obtain an optically transparent material (transparent resin film) which has excellent optical transparency, heat resistance and is improved in problems such as dimensional stability, adhesiveness, solvent and chemical resistances, brittleness and easy breaking of the film. SOLUTION: The optically transparent material contains a cycloolefinic addition copolymer having a specific reactive silyl group represented by structural formulas (1) and (2), [in formula (1) A 1 to A 4 are each independently a hydrogen atom, halogen atom, 1-20C alkyl group, alkenyl group, cycloalkyl group, aryl group or reactive silyl group represented by formula (2) and at least one of the A 1 to A 4 is the reactive silyl group; X is -CH 2 - or -O-; m is 0 or 1]. COPYRIGHT: (C)2003,JPO

公开(公告)号：JP2003096087A

公开(公告)日：2003-04-03

申请号：JP2001295453

申请日：2001-09-27

Applicant: JSR CORP

Inventor： OKITA KENZO ,  OSHIMA NOBORU ,  MARUYAMA YOICHIRO ,  HAYASHI TOSHIHITO

IPC: C07F7/18 ,  C08F232/00 ,  C08G61/08

Abstract: PROBLEM TO BE SOLVED: To obtain a cyclic olefin with a reactive silyl group which maintains adhesiveness and crosslinking performance as a crosslinking point in the reactive silyl group, prevents inhibiting polymerization in the polymerizing process, decomposing in the catalyst-removing process and producing a gelled polymer, and provides a polymer good in preservation stability as a polymer solution. SOLUTION: The cyclic olefin has the reactive silyl group represented by formula (1) [wherein, at least one of A to A is the reactive silyl group represented by formula (2)].

公开(公告)号：JP2003048998A

公开(公告)日：2003-02-21

申请号：JP2001192803

申请日：2001-06-26

Applicant: Jsr Corp ,  ジェイエスアール株式会社

Inventor： OSHIMA NOBORU ,  MARUYAMA YOICHIRO ,  HIRAI TAKESHI

IPC: G02F1/1333 ,  C08F232/08 ,  C08J5/00 ,  C08K3/22 ,  C08K5/5415 ,  C08L45/00

Abstract: PROBLEM TO BE SOLVED: To provide a liquid crystal oriented film-formed substrate having good heat resistance, solvent resistance and dimensional stability and excellent in transparency, and to provide a liquid crystal display element using the same. SOLUTION: This liquid crystal oriented film-formed substrate comprises a cyclic olefin-based copolymer containing a recurring unit of cyclic olefin having alkoxysilyl group or its hydrolyzed/condensed residue (a), a recurring unit of other cyclic olefin than the above one (b) and, if necessary, a recurring unit represented by CH2 -CHR (c), wherein the cyclic olefin-based copolymer has 1,000-1,000,000 number-average molecular weight and comprises a crosslinked product crosslinked with siloxane bond. The liquid crystal display element is provided by using the substrate.

Abstract translation: 要解决的问题：提供具有良好的耐热性，耐溶剂性和尺寸稳定性以及透明性优异的液晶取向膜形成基板，并提供使用该液晶取向膜形成基板的液晶显示元件。 解决方案：该液晶取向膜形成基材包括含有具有烷氧基甲硅烷基的环状烯烃的重复单元或其水解/缩合残基（a）的环状烯烃系共聚物，其它环状烯烃的重复单元（b ），如果需要，由CH 2 -CHR 7（c）表示的重复单元，其中环状烯烃系共聚物的数均分子量为1,000-1,000,000，并且包含与硅氧烷键交联的交联产物。 通过使用该基板来提供液晶显示元件。

公开(公告)号：JP2003040929A

公开(公告)日：2003-02-13

申请号：JP2001227248

申请日：2001-07-27

Applicant: Jsr Corp ,  ジェイエスアール株式会社

Inventor： OKITA KENZO ,  OSHIMA NOBORU

IPC: C08F2/38 ,  C08F4/70 ,  C08F32/08

Abstract: PROBLEM TO BE SOLVED: To provide a norbornene-based cyclic olefin addition polymer, modified in a molecular weight, and having an aromatic substituent at an end of a molecular chain. SOLUTION: When addition-polymerizing a cyclic olefin in a hydrocarbon solvent in the presence of (i) a compound component containing a transition metal of the 8-10 group in the periodic table, (ii) a strong Bronsted acid compound and/or a Lewis acid compound, and (iii) a polymerization catalyst containing an organoaluminium component, at least one kind of aromatic vinyl compound is added as a chain-transfer agent to produce the cyclic olefin addition polymer.

Abstract translation: 要解决的问题：提供在分子链末端具有分子量改性且具有芳香族取代基的降冰片烯系环状烯烃加成聚合物。 解决方案：在（i）含有周期表中8-10族的过渡金属的化合物组分存在下，在烃溶剂中加成环烯烃时，（ii）强烈的布朗斯台德酸化合物和/或 路易斯酸化合物和（iii）含有有机铝组分的聚合催化剂，加入至少一种芳香族乙烯基化合物作为链转移剂以制备环状烯烃加成聚合物。

公开(公告)号：JP2002317014A

公开(公告)日：2002-10-31

申请号：JP2001039941

申请日：2001-02-16

Applicant: JSR CORP

Inventor： KAIZU MITSUTAKA ,  OSHIMA NOBORU

IPC: C08J5/18 ,  C08F32/00 ,  C08K3/22 ,  C08K3/36 ,  C08L45/00 ,  C09D145/00 ,  C09J145/00

Abstract: PROBLEM TO BE SOLVED: To obtain an imide group-containing cyclic olefin-based (co)polymer together having excellent optical transparency, heat resistance, and adhesiveness, and useful as an optical material, adhesive, and coating agent, and to obtain a composite material given by using the same. SOLUTION: The imide group-containing cyclic olefin-based (co)polymer contains a repeating unit (a) expressed by formula (1) and has a weight-average molecular weight of 5,000-1,000,000. The composite material contains the (co)polymer together with silica and/or alumina.

公开(公告)号：JP2002212209A

公开(公告)日：2002-07-31

申请号：JP2001015318

申请日：2001-01-24

Applicant: JSR CORP

Inventor： OKITA KENZO ,  IMAMURA TAKASHI ,  OSHIMA NOBORU

IPC: C08F2/38 ,  C08F4/602 ,  C08F4/80 ,  C08F32/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a norbornene type cyclic olefin addition polymer with the polymerization activity having a controlled molecular weight and a narrow molecular weight distribution. SOLUTION: One or more norbornene type cyclic olefins are subjected to addition polymerization in the presence of a polymerization catalyst comprising a component of a group VIII-X transition metal compound of the Periodic Table, wherein at least one type of a cyclic nonconjugated polyene is added to polymerize as a molecular weight regulator.

公开(公告)号：JP2002179875A

公开(公告)日：2002-06-26

申请号：JP2000374310

申请日：2000-12-08

Applicant: JSR CORP

Inventor： MARUYAMA YOICHIRO ,  MAKITA MINORU ,  OSHIMA NOBORU

IPC: C08L45/00 ,  C08F232/00 ,  C08K5/13 ,  C08K5/37 ,  C08K5/521 ,  C08K5/524

Abstract: PROBLEM TO BE SOLVED: To obtain a heat-resistant resin composition having excellent thermal aging resistance and especially suitable as a liquid crystal substrate material, a semiconductor coating material and an adhesive for lens by compounding a cyclic olefin (co)polymer with a combination of specific antioxidants. SOLUTION: The heat-resistant resin composition contains (A) a specific cyclic olefin (co)polymer and (B) at least one kind of antioxidant selected from (b-1) a phenolic antioxidant, (b-2) a phosphorus-based antioxidant and (b-3) a thioether-based antioxidant.

公开(公告)号：JP2002020435A

公开(公告)日：2002-01-23

申请号：JP2000210362

申请日：2000-07-11

Applicant: JSR CORP

Inventor： OSHIMA NOBORU ,  MARUYAMA YOICHIRO ,  SAWADA KATSUTOSHI ,  SAKABE NOBUYUKI

IPC: G02B6/00 ,  C08F232/00 ,  C08J5/18 ,  G02B1/04

Abstract: PROBLEM TO BE SOLVED: To obtain a cycloolefin copolymer and an optical material both excellent in optical characteristics, heat resistance, adhesiveness, tightly contacting properties, and resistance to moisture absorption. SOLUTION: The cycloolefin copolymer contains repeating units represented by formula (1) and repeating units represented by formula (2) and has a number average mol.wt. (in terms of polystyrene) of 10,000-1,000,000.