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公开(公告)号:FI925777A
公开(公告)日:1992-12-18
申请号:FI925777
申请日:1992-12-18
Applicant: LUBRIZOL CORP
Inventor: SALOMON MARY F , DAVIS KIRK E , KARN JACK L , CAHOON JOHN M
IPC: C10M20060101 , C10M163/00 , C10N10/02 , C10N10/04 , C10N20/04 , C10N30/04 , C10N30/10 , C10N40/25 , F02F7/00
Abstract: This invention relates to a lubricating oil composition, comprising: a major amount of an oil of lubricating viscosity; and (A) an amount of at least one alkali metal overbased salt of an acidic organic compound sufficient to provide at least about 0.005 equivalents of alkali metal per 100 grams of the lubricating composition; (B) at least about 1.13% by weight of at least one dispersant; (C) at least one metal dihydrocarbyl dithiophosphate; and (D) at least one antioxidant, provided that the lubricating oil composition is free of calcium overbased sulfonate; provided that the composition contains less than about 0.08% by weight calcium; and provided that (C) and (D) are not the same.
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公开(公告)号:NO924807L
公开(公告)日:1992-12-11
申请号:NO924807
申请日:1992-12-11
Applicant: LUBRIZOL CORP
Inventor: CAHOON JOHN M , SALOMON MARY F , KARN JACK L , DAVIS KIRK E
IPC: C10M20060101 , C10M163/00 , C10N10/02 , C10N10/04 , C10N20/04 , C10N30/04 , C10N30/10 , C10N40/25 , F02F7/00
Abstract: This invention relates to a lubricating oil composition, comprising: a major amount of an oil of lubricating viscosity; and (A) an amount of at least one alkali metal overbased salt of an acidic organic compound sufficient to provide at least about 0.005 equivalents of alkali metal per 100 grams of the lubricating composition; (B) at least about 1.13% by weight of at least one dispersant; (C) at least one metal dihydrocarbyl dithiophosphate; and (D) at least one antioxidant, provided that the lubricating oil composition is free of calcium overbased sulfonate; provided that the composition contains less than about 0.08% by weight calcium; and provided that (C) and (D) are not the same.
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公开(公告)号:NO924683D0
公开(公告)日:1992-12-04
申请号:NO924683
申请日:1992-12-04
Applicant: LUBRIZOL CORP
Inventor: CAHOON JOHN M , SALOMON MARY F , KARN JACK L , TIPTON CRAIG D
IPC: C10M163/00 , C10M20060101 , C10M159/00 , C10M159/20 , C10M159/22 , C10M159/24 , C10M167/00 , C10N10/02 , C10N20/00 , C10N20/04 , C10N30/04 , C10N40/25 , C10N70/00 , C10M
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公开(公告)号:CA2085372A1
公开(公告)日:1992-10-20
申请号:CA2085372
申请日:1992-02-27
Applicant: LUBRIZOL CORP
Inventor: CAHOON JOHN M , KARN JACK L , SALOMON MARY F , TIPTON CRAIG D
IPC: C10M163/00 , C10M20060101 , C10M159/00 , C10M159/20 , C10M159/22 , C10M159/24 , C10M167/00 , C10N10/02 , C10N20/00 , C10N20/04 , C10N30/04 , C10N40/25 , C10N70/00
Abstract: 2085372 9218587 PCTABS00017 The invention relates to a composition, comprising: at least one basic alkali metal salt of at least one hydrocarbyl-substituted acidic organic compound, wherein the hydrocarbyl group is derived from a polyalkene having an M¬ B7n of at least 600, provided that when the organic compound is a sulfonic acid, the polyalkene has an M¬ B7n of at least 900; and provided that when the acidic organic compound is a mixture of acidic organic compounds containing a carboxylic acid and a sulfonic acid which has a hydrocarbyl group derived from a polyalkene having an M¬ B7n of less than 900, then the carboxylic acid comprises at least 10 % of the equivalents of the mixture.
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公开(公告)号:CA951709A
公开(公告)日:1974-07-23
申请号:CA70231
申请日:1969-12-18
Applicant: LUBRIZOL CORP
Inventor: GERGEL WILLIAM C , KARN JACK L , KING LAURENCE E
IPC: C10L1/30 , C07C51/41 , C10M159/20 , C10M159/22 , C10M159/24 , C10N10/02 , C10N10/04 , C10N30/00 , C10N30/04 , C10N40/04 , C10N40/08 , C10N40/20 , C10N40/25 , C10N40/26 , C10M1/40
Abstract: 1297150 Lubricants and fuels containing basic magnesium salts LUBRIZOL CORP 15 Dec 1969 [19 Dec 1968 17 Sept 1969] 61007/69 Heading C5F and C5G Oil-soluble basic magnesium salts are prepared by: (1) contacting an inorganic acidic material with a mixture comprising (a) a total of X equivalents of at least one organic acid, other than an aliphatic carboxylic acid, or an equivalent derivative thereof; (b) a total of Y equivalents of at least one aliphatic carboxylic acid or sulphonic acid or an equivalent derivative thereof except that when (b) is a sulphonic acid or equivalent derivative thereof then (a) must be other than a sulphonic acid or an equivalent derivative thereof, wherein the ratio of X : Y is from 1:1 to 20:1; (c) Z equivalents of basically reacting magnesium oxide or freshly formed magnesium hydroxide, wherein the value of Z/X+Y is from 1À1 to 30; and (d) water, until the reaction between the acidic material and the mixture substantially ceases; or by (2) contacting an inorganic acidic material with a mixture comprising (a) a total of X equivalents of at least one organic acid, other than an aliphatic carboxylic acid, or an equivalent derivative thereof; (b) a total of Y equivalents of at least one aliphatic carboxylic acid or an equivalent derivative thereof, wherein the ratio of X : Y is from 1:1 to 20:1; (c) Z equivalents of basically reacting magnesium oxide or freshly formed magnesium hydroxide wherein the value of Z/X+Y is from 1À1 to 30; (d) at least one C 1 -C 7 aliphatic alcohol; and (e) water, until the reaction between the acidic material and the mixture substantially ceases, subsequently removing all free alcohol, and continuing the contacting of the acidic material with the remainder of the mixture. The salts prepared are added to mineral or synthetic lubricants or to liquid fuels together with other conventional additives such as calcium petrosulphonate, zinc di - n - octylphpsphorodithioate, an ester of polyisobutenyl substituted succinic anhydride and pentaerythritol, an adduct of zinc di-cyclohexylphosphorodithioate and ethylene oxide, sulphurized sperm oil. Extensive lists of suitable lubricants, liquid fuels and reactants used to prepare the basic salts are given. Lists of inert diluents and of auxiliary phenolic promoters which can be included in the reaction mixture are given.
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公开(公告)号:DE69717361T2
公开(公告)日:2003-09-04
申请号:DE69717361
申请日:1997-08-14
Applicant: LUBRIZOL CORP
Inventor: CLEVELAND WILLIAM K S , KARN JACK L , VARGO DANIEL M
IPC: C10M129/54 , C10M129/76 , C10M133/16 , C10M167/00 , C10N30/04 , C10N40/26 , F02B75/02 , C10M159/22
Abstract: Two-stroke cycle engines can be effectively lubricated by supplying to the engine a mixture of an oil of lubricating viscosity and a hydrocarbyl-substituted hydroxyaromatic carboxylic acid or an ester, unsubstituted amide, hydrocarbyl-substituted amide, ammonium salt, hydrocarbylamine salt, or monovalent metal salt thereof in an amount suitable to reduce piston deposits in said engine. The mixture supplied to the engine contains less than 0.06 percent by weight of divalent metals.
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公开(公告)号:AT142249T
公开(公告)日:1996-09-15
申请号:AT92907871
申请日:1992-02-27
Applicant: LUBRIZOL CORP
Inventor: CAHOON JOHN M , KARN JACK L , SALOMON MARY F , TIPTON CRAIG D
IPC: C10M163/00 , C10M20060101 , C10M159/00 , C10M159/20 , C10M159/22 , C10M159/24 , C10M167/00 , C10N10/02 , C10N20/00 , C10N20/04 , C10N30/04 , C10N40/25 , C10N70/00
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公开(公告)号:AU3421095A
公开(公告)日:1996-05-02
申请号:AU3421095
申请日:1995-10-13
Applicant: LUBRIZOL CORP
Inventor: KARN JACK L , KOKSIS JODY A , KING LAURENCE E , ADAMS PAUL E , NOTARO VINCENT A
IPC: C10L1/10 , C10L1/12 , C10L1/18 , C10L1/188 , C10L1/189 , C10L1/19 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/24 , C10L1/30 , C10M159/20 , C10M159/22 , C10N10/02 , C10N10/04 , C10N30/00 , C10N30/04 , C10N30/10
Abstract: Lubricants containing metal salts of hydrocarbyl-substituted carboxyalkylene-linked phenols, dihydrocarbyl esters of alkylene dicarboxylic acids, the alkylene group being substituted with a hydroxy group and an additional carboxylic acid group, or alkylene-linked polyaromatic molecules, the aromatic moieties whereof comprise at least one hydrocarbyl-substituted phenol and at least one carboxy phenol, where the hydrocarbyl groups are of sufficient length to provide oil solubility to the salt, exhibit good asphaltene suspension for marine diesel applications. Preferably the salts are overbased.
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公开(公告)号:CA2112183A1
公开(公告)日:1994-06-25
申请号:CA2112183
申请日:1993-12-22
Applicant: LUBRIZOL CORP
Inventor: CAHOON JOHN M , KARN JACK L , HUANG NAI Z
IPC: C10M159/20 , C10M163/00 , C10N10/02 , C10N10/04 , C10N30/04 , C10N30/06 , C10N40/22 , C10N50/10 , C10M135/08 , C10M133/04 , C10M135/02 , C10M137/02 , C10M143/06 , C10M155/00
Abstract: Title: LUBRICATING COMPOSITIONS, GREASES AND FUNCTIONAL FLUIDS CONTAINING SULFITE OR SULFATE OVERBASED SALTS The invention includes a lubricating composition comprising a major amount of an oil of lubricating viscosity, and a minor amount of (A) a sulfite or sulfate overbased or borated overbased metal salt of an acidic organic compound, whereinthe lubricating composition contains less than 1.5 % by weight of an ashless dispersant which is the reaction product of a polyisobutene substituted succinic anhydride and a polyamine, and provided that when (A) is a sulfate overbased or borated overbased metal salt, then the lubricating composition includes (B) at least one phosphorous of boron antiwear/extreme pressure agent, or (C) a sulfur compound. The invention also includes grease and functional fluids containing the sulfite and sulfate overbased metal salts. These composition have improved antiwear, antiweld, and extreme pressure properties.
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公开(公告)号:CA2105314A1
公开(公告)日:1994-03-05
申请号:CA2105314
申请日:1993-09-01
Applicant: LUBRIZOL CORP
Inventor: CAHOON JOHN M , KARN JACK L , HUANG NAI Z , ROSKI JAMES P
IPC: C09K15/10 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/08 , C10M141/04 , C10M141/08 , C10M159/20 , C10M167/00 , C10M169/00 , C10M173/00 , C10N10/02 , C10N10/04 , C10N30/06 , C10N30/08 , C10N30/10 , C10N40/04 , C10N40/22 , C10N50/10 , C10N60/10 , C10N70/00 , F02B75/02 , C10M135/02 , C10M139/00 , C10M135/08 , C10M129/10
Abstract: This invention relates to a composition comprising at least one sulfurized overbased product made by contacting (A) at least one overbased product or (A') at least one boron-containing overbased product with (B) sulfur and/ or at least one source of sulfur; said overbased product (A) or boron-containing overbas ed product (A') being made using at least one acidic material, with the proviso that when said acidic material is other than SO2 or a source of SO2 said overbased product (A) or boron-containing overbased product (A') is contacted with an effective amount of SO2 or a source of SO2 to displace at least part of said acidic material. In one embodiment the sulfurized overbased product is an overbased thiosulfate or a boron- containing overbased thiosulfate. In one embodiment, the sulfurized overbase d product is made using the overbased product (A) and the composition further comprises at least one non-sulfurized boron-containing overbased product. Th e sulfurized overbased products are thermally stable and are useful as extreme pressure (EP) and/or anti-wear agents or antioxidants for use in lubricants, function al fluids and normally liquid fuels. The functional fluids can be oil-based, water-oil emulsions or water-based. The sulfurized overbased products are particularly suitable for useas EP and/or anti-wear agents for use in gear lubricants and cutting fluids. In one embodiment lubricating compositions are provided that pass both the L-37 Hig h Torque Test and the L-42 High Speed Shock Test without the necessity of employing phosphorus and sulfurized olefin anti-wear systems in their formulation.
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