3,3@-THIOBIS %2-METHOXY-1-AZABENZANTHRONE

    公开(公告)号:AU7249274A

    公开(公告)日:1976-02-19

    申请号:AU7249274

    申请日:1974-08-19

    Applicant: MONTEDISON SPA

    Abstract: A new process for preparing 3,3 - thio - bis[2-Methoxy-1-azabenzanthrone], a useful intermediate in the synthesis of dyestuffs, is disclosed. The process involves reacting 2-methoxy-1-azabenzanthrone with sulfur chlorides in suspension or solution in an inert solvent under heating, and recovering the reaction product from the reaction mass, e.g., by filtering.

    48.
    发明专利
    未知

    公开(公告)号:AT279572B

    公开(公告)日:1970-03-10

    申请号:AT649764

    申请日:1964-07-28

    Applicant: MONTEDISON SPA

    Abstract: Lactams are prepared by the reaction of a cycloalkanecarboxylic acid or an alkyl derivative thereof with nitrosyl hydrogen pyrosulphate. The reaction may be carried out in an inert solvent, e.g. in aliphatic, cycloaliphatic, chlorinated aliphatic hydrocarbon or nitroparaffin. The acid may be one having 4-12 carbon atoms in the ring. Examples are given for the preparation of caprolactam, capryllactam, valerolactam and lauryllactam. The process is operated at a temperature between 30 DEG and 150 DEG C. The lactam is separated by extracting the unreacted acid from the mixture by solvent extraction; neutralizing the remaining aqueous solution with an alkaline material, and extracting the lactam with a solvent, e.g. benzene, chloroform or methylene dichloride.

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