公开(公告)号：DE69215009D1

公开(公告)日：1996-12-12

申请号：DE69215009

申请日：1992-06-03

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  PEPERA MARC ANTHONY

IPC: B01J23/22 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/215 ,  C07C53/08 ,  B01J27/195

Abstract: Disclosed is a process for making acetic acid which comprises oxidizing ethane with molecular oxygen in a reaction zone at a pressure of at least 100 psig while the reactants are in contact with a solid catalyst having the elements and relative atomic proportions indicated by the empirical formula: VPaMbOx where M is one or more optional element selected from Co, Cu, Re, Fe, Ni, Nb, Cr, W, U, Ta, Ti, Zr, Zn, Hf, Mn, Pt, Pd, Sn, Sb, Bi, Ce, As, Ag, and Au, wherein a is 0.5 to 3, b is 0 to 1, and x is a number determined by the valence requirements of the other elements in the catalyst, and wherein said catalyst contains crystalline vanadyl pyrophosphate.

公开(公告)号：ZA9501443B

公开(公告)日：1996-08-21

申请号：ZA9501443

申请日：1995-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  LEMANSKI MICHAEL FRANCIS ,  PEPERA MARC ANTHONY ,  CIRJAK LARRY MICHAEL ,  PAPARIZOS CHRISTOS ,  WAGNER DAVID RUDOLPH

IPC: B01J8/24 ,  B01J8/32 ,  B01J8/38 ,  B01J19/00 ,  C07C67/055 ,  C07C

CPC classification number: B01J19/002 ,  B01J8/24 ,  B01J8/32 ,  B01J8/388 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

公开(公告)号：BR9500737A

公开(公告)日：1996-01-02

申请号：BR9500737

申请日：1995-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  CIRJAK MICHAEL LARRY ,  LEMANSKI MICHAEL FRANCIS ,  PAPANZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  WAGNER DAVID RUDOLPH ,  BENKALOWYCZ NANCY CHRISTOFFERS

IPC: B01J23/58 ,  B01J8/24 ,  B01J8/32 ,  B01J8/38 ,  B01J19/00 ,  C07B61/00 ,  C07C67/05 ,  C07C67/055 ,  C07C67/313 ,  C07C69/15 ,  C08F18/08

Abstract: A fluid bed process for the manufacture of vinyl acetate from ethylene, acetic acid and oxygen comprising feeding ethylene and acetic acid into a fluid bed reactor through one or more inlets, introducing the oxygen into the reactor through at least one further inlet, co-joining the oxygen, ethylene and acetic acid in the reactor in contact with a fluid bed catalyst to produce vinyl acetate. The particle size diameter of the particulate catalyst material preferably has a range of 60% of the particles being below 200 microns (0.2 mm) with no more than 40% of the particles being below 40 microns (0.04 mm).

公开(公告)号：NO177850C

公开(公告)日：1995-12-06

申请号：NO924746

申请日：1992-12-08

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  WAGNER DAVID RUDOLPH

IPC: B01J27/195 ,  C07B61/00 ,  B01J23/36 ,  C07C51/215 ,  C07C53/08

Abstract: Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone, wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.

公开(公告)号：BR9500736A

公开(公告)日：1995-10-31

申请号：BR9500736

申请日：1995-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  CIRJAK LARRY MICHAEL ,  LEMANSKI MICHAEL FRANCIS ,  PAPERIZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  SURESH DEVASIRVATHAM DHANARAH

IPC: B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J23/644 ,  B01J23/648 ,  B01J23/66 ,  B01J23/68 ,  B01J32/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C67/04 ,  C07C67/055 ,  C07C69/15 ,  C08F18/08

Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm /g and the surface area is from 100 to 200 m /g.

公开(公告)号：NO950645L

公开(公告)日：1995-08-23

申请号：NO950645

申请日：1995-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  CIRJAK LARRY MICHAEL ,  LEMANSKI MICHAEL FRANCIS ,  PAPARIZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  SURESH DEVASIRVATHAM DHANARAH

IPC: B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J23/644 ,  B01J23/648 ,  B01J23/66 ,  B01J23/68 ,  B01J32/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C67/04 ,  C07C67/055 ,  C07C69/15 ,  B01J35/08 ,  B01J23/54

Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm /g and the surface area is from 100 to 200 m /g.

公开(公告)号：FI950819A0

公开(公告)日：1995-02-22

申请号：FI950819

申请日：1995-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  CIRJAK LARRY MICHAEL ,  LEMANSKI MICHAEL FRANCIS ,  PAPARIZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  SURESH DEVASIRVATHAM DHANARAH

IPC: B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J23/644 ,  B01J23/648 ,  B01J23/66 ,  B01J23/68 ,  B01J32/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C67/04 ,  C07C67/055 ,  C07C69/15 ,  B01J

Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm /g and the surface area is from 100 to 200 m /g.

公开(公告)号：NO924746L

公开(公告)日：1993-06-10

申请号：NO924746

申请日：1992-12-08

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  WAGNER DAVID RUDOLPH

IPC: B01J27/195 ,  B01J23/36 ,  C07B61/00 ,  C07C51/215 ,  C07C53/08

Abstract: Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone, wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.

公开(公告)号：FI925313A

公开(公告)日：1993-06-10

申请号：FI925313

申请日：1992-11-23

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  WAGNER DAVID RUDOLPH

IPC: B01J23/36 ,  B01J27/195 ,  C07B61/00 ,  C07C51/215 ,  C07C53/08

Abstract: Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone, wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.

公开(公告)号：DE3170443D1

公开(公告)日：1985-06-13

申请号：DE3170443

申请日：1981-12-15

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  NICHOLAS MARK LEE

IPC: C07D307/60 ,  B01J27/18 ,  B01J27/198 ,  C01B25/37 ,  C01B25/45 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  B01J23/22

Abstract: A process is provided for preparing fluid bed catalysts containing the mixed oxides of vanadium and phosphorus prepared from a mixed phosphoric acid source. The process comprises(a) introducing at least one pentavalent vanadium compound into an organic liquid capable of reducing at least a portion of the vanadium to a valence state of +4;(b) effecting reduction of at least a portion of the vanadium to a valence state of +4;(c) contacting the vanadium with a mixed phosphorus component prior or subsequent to effecting said reduction, wherein said mixed phosphorus component comprises 75-90 weight percent orthophosphoric acid and 10-25 weight percent pyrophosphoric acid;(d) comminuting the catalyst precursor resulting from step (a)- (c);(e) introducing the catalyst precursor into water prior or subsequent to said comminuting to form an aqueous slurry; and(f) spray drying said slurry to form microspheroidal catalyst particles.The catalysts are used in the oxidation of C 4 -hydrocarbons, in particular n-butane to maleic anhydride.