公开(公告)号：HK93392A

公开(公告)日：1992-12-04

申请号：HK93392

申请日：1992-11-26

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  GLAESER LINDA CLAIRE ,  TOFT MARK ANTHONY

IPC: B01J23/22 ,  B01J27/08 ,  B01J35/08 ,  B01J37/04 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：BR9105578A

公开(公告)日：1992-09-01

申请号：BR9105578

申请日：1991-12-23

Applicant: STANDARD OIL CO OHIO

Inventor： LYNCH CHARLES STAFFORD ,  GLAESER LINDA CLAIRE ,  BRAZDIL JAMES FRANK ,  TOFT MARK ANTHONY

IPC: B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/34 ,  B01J23/843 ,  B01J23/847 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C253/24 ,  C07C255/08

Abstract: Disclosed is a process for making an activated antimony and vanadium-containing catalyst in oxide form having an atomic ratio of Sb:V in the range from 0.8-4, which comprises calcining such an oxidic vanadium and antimony-containing composition at a temperature of over 750 DEG C, and thereafter contacting said calcined catalyst with a hydroxy compound in liquid form selected from (1) cyclohexanol, (2) cyclopentanol, (3) a monohydroxy, acyclic hydrocarbon having 1-8 C atoms, and (4) a dihydroxy, acyclic hydrocarbon having 2-4 carbon atoms, and separating as a liquid said compound from said catalyst insofar as it is present beyond the amount wetting said catalyst, and thereafter drying said catalyst.

公开(公告)号：DE68902042D1

公开(公告)日：1992-08-13

申请号：DE68902042

申请日：1989-10-26

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  GLAESER LINDA CLAIRE ,  TOFT MARK ANTHONY

IPC: B01J23/22 ,  B01J27/08 ,  B01J35/08 ,  B01J37/04 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：BR8905787A

公开(公告)日：1990-06-12

申请号：BR8905787

申请日：1989-11-14

Applicant: STANDARD OIL CO OHIO

Inventor： TOFT MARK ANTHONY ,  BRAZDIL JAMES FRANK ,  GLAESER LINDA CLARE

IPC: B01J23/22 ,  B01J27/08 ,  B01J35/08 ,  B01J37/04 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08 ,  B01J37/02 ,  B01J23/16

公开(公告)号：AT380806B

公开(公告)日：1986-07-10

申请号：AT615480

申请日：1980-12-17

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV DHANARAJ ,  BRAZDIL JAMES FRANK ,  GRASSELLI ROBERT KARL

IPC: B01J23/54 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J23/84 ,  B01J23/88 ,  B01J27/057 ,  B01J38/48 ,  C07C45/00 ,  C07C45/34 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/85 ,  B01J27/02 ,  B01J37/02

Abstract: Antimony-based oxide complex catalysts are improved by adding to these catalysts an antimony-containing compound such as Sb 2 O 3 , in an amount of 0.1 to 25% based on an atomic basis of the antimony relative to the antimony already present in the catalyst. In this way a catalyst is produced which gives improved yields for example in the procuction of acrylonitrile by the ammoxidation of propylene.

公开(公告)号：ATA304479A

公开(公告)日：1982-04-15

申请号：AT304479

申请日：1979-04-23

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ

IPC: B01J27/18 ,  B01J23/24 ,  B01J23/31 ,  B01J23/34 ,  B01J23/54 ,  B01J23/835 ,  B01J23/85 ,  B01J23/89 ,  B01J27/057 ,  B01J27/186 ,  B01J27/188 ,  B01J35/00 ,  C07C45/35 ,  C07C51/25 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/88

公开(公告)号：NO782715A

公开(公告)日：1979-02-13

申请号：NO782715

申请日：1978-08-09

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  SURESH DEV DHANARAJ ,  GRASSELLI ROBERT KARL

IPC: B01J23/24 ,  B01J23/31 ,  B01J23/88 ,  B01J27/057 ,  B01J27/192 ,  B01J35/00 ,  B01J37/02 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  B01J

CPC classification number: B01J23/8872 ,  B01J23/002 ,  B01J23/887 ,  B01J23/8876 ,  B01J27/0576 ,  B01J27/192 ,  B01J35/0006 ,  B01J37/0236 ,  B01J2523/00 ,  C07C45/35 ,  C07C51/252 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  C07C255/08

公开(公告)号：DE69324956T2

公开(公告)日：1999-09-16

申请号：DE69324956

申请日：1993-03-10

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  LITTLE IAN RAYMOND ,  HAZEN JOSEPH BRIAN

IPC: B01J23/14 ,  B01J23/22 ,  B01J37/02 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07F7/22 ,  B01J37/03

公开(公告)号：DE69324956D1

公开(公告)日：1999-06-24

申请号：DE69324956

申请日：1993-03-10

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  LITTLE IAN RAYMOND ,  HAZEN JOSEPH BRIAN

IPC: B01J23/14 ,  B01J23/22 ,  B01J37/02 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07F7/22 ,  B01J37/03

公开(公告)号：ES2059511T3

公开(公告)日：1994-11-16

申请号：ES88303391

申请日：1988-04-14

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK ,  TOFT MARK ANTHONY ,  GLAESER LINDA CLAIRE

IPC: B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/28 ,  B01J27/199 ,  B01J23/30 ,  B01J23/31 ,  B01J23/84 ,  B01J23/847 ,  B01J23/88 ,  B01J27/057 ,  B01J27/14 ,  B01J27/192 ,  B01J27/198 ,  B01J37/04 ,  C07C67/00 ,  C07C253/00 ,  C07C253/24 ,  C07C255/08

Abstract: Ammoxidation of propane or isobutane with NH3 and 02 using (1) a mole ratio of paraffin:NH3 in the range from 2 to 16 and a mole ratio of paraffin:O2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.