公开(公告)号：DE2453677A1

公开(公告)日：1975-06-12

申请号：DE2453677

申请日：1974-11-13

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL JEROME ,  MILBERGER ERNEST CARL ,  DOLHYJ SERGE ROMAN

IPC: C07D307/60 ,  B01J23/22 ,  B01J27/00 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07D307/32

Abstract: Catalysts containing the oxides of vanadium, phosphorus and uranium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in high yield.

公开(公告)号：AU5479273A

公开(公告)日：1974-10-24

申请号：AU5479273

申请日：1973-04-19

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST CARL ,  DOLHYJ SERGE ROMAN

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  C07C51/23 ,  C07C51/25 ,  C07C51/31 ,  C07C51/54 ,  B01J11/06

Abstract: 1427389 Maleic anhydride STANDARD OIL CO 18 April 1973 [5 May 1972] 18738/73 Heading C2C [Also in Division B1] Maleic anhydride is produced by oxidizing 1,3-butadiene, n-butenes, crotonaldehyde, furan or a mixture thereof with molecular oxygen at 250-600‹ C. using a catalyst comprising antimony, molybdenum, oxygen, vanadium and/or iron and, optionally, tungsten, magnesium, aluminium and/or nickel in the atomic proportions Sb a Mo b V c Fed Z e O x wherein: Z=W, Mg, Al and/or Ni; a=1-9; b=1-10; c, d, e=0-1 but c + d is greater than zero; and x is a number to satisfy valency requirements. The reaction pressure is usually superatmospheric but may be atmospheric or subatmospheric with a contact time of 1 to 50 sees. The feed may contain diluents, e.g. steam, nitrogen and carbon oxides. An air to reactant ratio of 12 to 20=1 may be employed. The examples describe the use of butadiene as feed to give a maleic anhydride product containing some acrylic acid.

公开(公告)号：DE2241918A1

公开(公告)日：1973-03-08

申请号：DE2241918

申请日：1972-08-25

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST CARL ,  DOLHYJ SERGE ROMAN ,  HARDMAN HARLEY FOCH

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  B01J23/887 ,  B01J37/16 ,  C07B61/00 ,  C07C51/25 ,  C07C51/31 ,  C07C57/14

Abstract: The process in this invention relates to the conversion of organic compounds selected from the group consisting of the n-butylenes, butadiene, crotonaldehyde and furan in a selective manner to maleic anhydride in the presence of a catalyst comprising the mixed oxides of antimony and molybdenum.

公开(公告)号：DE3564424D1

公开(公告)日：1988-09-22

申请号：DE3564424

申请日：1985-10-23

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE ,  DOLHYJ SERGE ROMAN

IPC: B01J27/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/377 ,  C07C57/065 ,  C07C67/00 ,  C07C57/04

Abstract: A process for the catalytic conversion of lactic acid and/or ammonium lactate to acrylic acid comprises contacting a mixture of water and lactic acid and/or ammonium lactate in the vapor phase with aluminum phosphate which has been treated with an aqueous inorganic base.

公开(公告)号：DE3161612D1

公开(公告)日：1984-01-19

申请号：DE3161612

申请日：1981-02-18

Applicant: STANDARD OIL CO OHIO

Inventor： SUNDEEN MARCIA HENNIGER ,  VELENYI LOUIS JOSEPH ,  DOLHYJ SERGE ROMAN

IPC: B01J31/00 ,  C07C67/00 ,  C07C407/00 ,  C07C409/02 ,  C07C409/08 ,  C07C409/10 ,  C07C409/14 ,  C07C179/04 ,  B01J31/02 ,  C07C178/00 ,  C07C179/053

公开(公告)号：ATA388179A

公开(公告)日：1981-02-15

申请号：AT388179

申请日：1979-05-28

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY ,  MILBERGER ERNEST CARL ,  WOODBURY DAVID ROY ,  DOLHYJ SERGE ROMAN

IPC: B01J23/28

公开(公告)号：NO142626C

公开(公告)日：1980-09-17

申请号：NO744106

申请日：1974-11-14

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL JEROME ,  MILBERGER ERNEST CARL ,  DOLHYJ SERGE ROMAN

IPC: C07D307/60 ,  B01J23/22 ,  B01J27/00 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  B01J23/00

Abstract: Catalysts containing the oxides of vanadium, phosphorus and uranium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in high yield.

公开(公告)号：NO142626B

公开(公告)日：1980-06-09

申请号：NO744106

申请日：1974-11-14

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL JEROME ,  MILBERGER ERNEST CARL ,  DOLHYJ SERGE ROMAN

IPC: C07D307/60 ,  B01J23/22 ,  B01J27/00 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  B01J23/00

Abstract: Catalysts containing the oxides of vanadium, phosphorus and uranium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in high yield.

公开(公告)号：NO142335B

公开(公告)日：1980-04-28

申请号：NO743668

申请日：1974-10-11

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHYJ SERGE ROMAN ,  MILBERGER ERNEST CARL

IPC: B01J23/16 ,  B01J23/30 ,  B01J23/31 ,  B01J23/34 ,  B01J23/88 ,  B01J23/888 ,  B01J23/89 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055 ,  C07C67/00 ,  B01J23/84

公开(公告)号：ATA252676A

公开(公告)日：1977-09-15

申请号：AT252676

申请日：1976-04-07

Applicant: STANDARD OIL CO OHIO

Inventor： BRIDGEMAN DAVID ROGER ,  DOLHYJ SERGE ROMAN ,  MILBERGER ERNEST CARL

IPC: C07C27/14 ,  B01J20060101 ,  B01J8/06 ,  B01J23/00 ,  B01J23/887 ,  B23K20060101 ,  C07B61/00 ,  C07C27/00 ,  C07C45/00 ,  C07C45/35 ,  C07C47/22 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00