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公开(公告)号：JP2000154315A
公开(公告)日：2000-06-06
申请号：JP26462199
申请日：1999-09-17
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition having excellent blow moldability, capable of reducing weight, having excellent heat resistance and mechanical properties by melting and kneading a polyamide resin with a laminar silicate. SOLUTION: This composition comprises (A) a polyamide resin and (B) a laminar silicate and satisfies equation I and equation II [Tm is the melting point ( deg.C) of the polyamide; T is a temperature equal to or higher than (Tm+10 deg.C) and equal to or lower than (Tm+70 deg.C); μa 10 is a melt viscosity (poise) at T deg.C at 10 (sec-1) shear rate; μa 1,000 is a melt viscosity (poise) at T deg.C at 1,000 (sec-1) shear rate. The component B is preferably a laminar silicate in which an exchangeable cation existing between layers is replaced with an organic onium ion. Montmorillonite, beidellite, nontronite, saponite, etc., may be cited as the component B. The composition is obtained by kneading the component A with the component B n a molten state.
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公开(公告)号：JP2000135713A
公开(公告)日：2000-05-16
申请号：JP31124498
申请日：1998-10-30
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
IPC: B29B7/84 , B29B7/86 , B29K101/10 , C08K3/34 , C08L55/02 , C08L67/00 , C08L77/00 , C08L81/02 , C08L101/00
Abstract: PROBLEM TO BE SOLVED: To obtain a thermoplastic resin compsn. wherein a lamellar silicate is uniformly dispersed in a thermoplastic resin and whose amt. of gas generation is less at higher temp. or during retention under molten state. SOLUTION: When a thermoplastic resin A and a swelling lamellar silicate B are melted and kneaded by using a melt kneader wherein at least one vent hole 4 is installed, the resin compsn. under molten state is brought into contact with water content C and is melted and kneaded and in addition, water content is removed by bringing at least one vent hole 4 installed in the melt kneader into under vacuum.
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公开(公告)号：JP2000129120A
公开(公告)日：2000-05-09
申请号：JP30017298
申请日：1998-10-21
Applicant: TORAY INDUSTRIES
Inventor： KATO KIMIYA , NISHIMURA TORU , YAMANAKA TORU
Abstract: PROBLEM TO BE SOLVED: To obtain the subject polyamide resin composition that can suppress the decomposition of organic substances distributing between the silicate salt layers and can retain the rigidity of a high level by exchanging the exchangeable metal ions distributing between the layers of laminar silicate salt with a specific organic substance. SOLUTION: (A) A polyamide resin (preferably nylon 6 or nylon 66) and (B) a laminar silicate salt in which the exchangeable metal ions distributing between the layers are exchanged with a polyamide of which the amino terminal groups are ionized (preferably an amino terminal-ionized and alcohol-soluble polyamide) are melt-kneaded to give the objective composition. The inorganic ash content in this composition is 0.1-40 wt.%. In a preferred embodiment, the polyamide bearing ionized amino terminals is selected from a nylon 6/nylon 66 copolymer and the like. The component B is prepared by dissolving a polyamide resin in an alcohol, adding acidic water to the polyamide solution to ionize the amino terminal groups and the ionized polyamide is mixed with the laminar silicate salt.
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公开(公告)号：JP2000119516A
公开(公告)日：2000-04-25
申请号：JP29431298
申请日：1998-10-15
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
Abstract: PROBLEM TO BE SOLVED: To obtain a polyamide resin composition having improved mechanical properties by melting and kneading a polyamide resin with a laminar silicate and an organic onium salt and forming an ionic bond between the laminar silicate and the polyamide. SOLUTION: This composition is obtained by melting and kneading 100 pts.wt. of at least one kind of a polyamide resin selected from nylon 6 and nylon 66 with 0.01-10 pts.wt. of an organic onium salt and a laminar silicate containing an exchangeable metal ion existing between layers, replaced with an organic onium ion composed of a 11-30C organic ammonium salt so as to make the amount of the silicate 0.1-50 pts.wt. calculated as an inorganic ash in the composition. The polyamide resin composition comprises >=40 pts.wt. total amino terminal group in the polyamide resin, subjected to ionic bond with the silicate and >=40 wt.% total carboxyl terminal group subjected to ionic bond with the organic onium ion.
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公开(公告)号：JP2000086890A
公开(公告)日：2000-03-28
申请号：JP12078599
申请日：1999-04-27
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
IPC: C08K3/02 , C08K3/22 , C08K3/32 , C08K3/34 , C08K3/38 , C08K5/02 , C08K5/3492 , C08K5/521 , C08K9/06 , C08L23/02 , C08L23/26 , C08L77/00
Abstract: PROBLEM TO BE SOLVED: To provide a polyamide resin composition which combines low water absorption properties, mechanical strength, heat resistance and toughness, has excellent fluidity upon molding and is suitable for injection molding of automobile parts and electrical components. SOLUTION: This resin composition is formed by blending a polyamide resin (A), a silicate-base inorganic filler (B) and an olefin polymer (C) grafted with an unsaturated dicarboxylic acid and/or an unsaturated dicarboxylic derivative, and in said resin composition, 50% or more of the dispersed particles of the silicate-base inorganic filler (B) are dispersed independently in the polyamide resin (A).
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Patent Agency Ranking
公开(公告)号：JPH10101918A
公开(公告)日：1998-04-21
申请号：JP21032097
申请日：1997-08-05
Applicant: TORAY INDUSTRIES
Inventor： SUGIE RYUICHI , NISHIMURA TORU , HIRATSUKA MOTONORI
Abstract: PROBLEM TO BE SOLVED: To provide a polyester resin composition having heat resistance higher than those of a binary compatible polycarbonate (PC)/1,4-cyclohexanedimethanol(CHDM) derivative copolyester system and a binary incompatible PC/CHDM derivative copolyester system and having good mechanical properties. SOLUTION: This composition comprises a polyester (A) comprising dicarboxylic acid units based on terephthalic acid(TPA) units and glycol units based on ethylene glycol(EG) units (I) and CHDM units (II) and having a (I) to (II) molar ratio of 1 or above, a polyester (B) comprising dicarboxylic acid units based on TPA units (II) and glycol units based on EG units and CHDM units (II) and having a (I) to (II) molar ratio of below 1, and an aromatic PC (C).
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公开(公告)号：JPH08120180A
公开(公告)日：1996-05-14
申请号：JP4458195
申请日：1995-03-03
Applicant: TORAY INDUSTRIES
Inventor： OKITA SHIGERU , MATSUOKA HIDEO , NISHIMURA TORU
IPC: C08K3/00 , C08K5/13 , C08K5/3477 , C08K5/52 , C08K5/521 , C08L67/00 , C08L67/02 , C08L71/00 , C08L71/08 , C08L71/10 , C08L71/12 , C08L81/02 , C08L85/02 , C08L101/00
Abstract: PURPOSE: To obtain the subject composition excellent in flame retardancy, moldability, hydrolytic resistance and mechanical properties and free from bleeding by compounding a thermoplastic resin with a polyphosphate polymer having a specific structure. CONSTITUTION: This composition is composed of (A) 100 pts.wt. of a thermoplastic resin (preferably, a thermoplastic polyester resin such as polybutylene terephthalate or a mixture of the resin with a phenoxy resin) and (B) 1-100 pts.wt. of a polyphosphate consisting of constructing units of formula I (Ar is a divalent aromatic residual group; R1 is a 1-12C alkyl, an aryl, etc.; n expresses a number-average molecular weight and is >=40) (preferably, a hydroquinone-type polyphosphate of formula II). The component B is generally obtained by polycondensing phosphoric acid dichloride with a bisphenol. Preferably, the composition is further compounded with a salt of (iso)cyanuric acid with melamine, benzoguanamine or acetoguanamine.
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公开(公告)号：JPH05230308A
公开(公告)日：1993-09-07
申请号：JP3603992
申请日：1992-02-24
Applicant: TORAY INDUSTRIES
Inventor： IWAMOTO MASAAKI , NISHIMURA TORU , ONISHI KOJI
Abstract: PURPOSE:To produce the subject copolymer type flame retardant excellent in compatibility with a thermoplastic resin and capable of providing a flame- retardant resin composition excellent in mechanical strength and visual appearance by copolymerizing two or more kinds of specified halogen-containing monomers. CONSTITUTION:(A) The objective copolymer type flame retardant contains units derived from two or more kinds of halogen-containing monomers of formulae I to III (X-Z is Br or Cl; 1 to n are each an integer of 1 to 5) in an amount of >=30wt.% in total (Other copolymer components are styrene, acrylonitrile, malic anhydride, etc.) and the number-average molecular weight thereof is >=1000, preferably >=5000. (B) The objective flame-retardant resin composition contains 10 to 99 pts.wt., preferably 15 to 98 pts.wt. thermoplastic resin (e.g. a polyamide-based resin, a polycarbonate-based resin or an acrylic resin), 1 to 90 pts.wt., preferably 2 to 85 pts.wt. the above-mentioned copolymer type flame retardant and 0 to 10 pts.wt. flame retardant assistant (preferably antimony oxide) as necessary and the halogen content of the composition is >=5wt.%, preferably >=8wt.%.
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公开(公告)号：JPH05140386A
公开(公告)日：1993-06-08
申请号：JP30787091
申请日：1991-11-22
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KARASAWA HIROO , IWAMOTO MASAAKI
Abstract: PURPOSE:To obtain the subject composition, composed of a specific partially saponified substance and a specified terminal-modified polyamide resin in a specific proportion, excellent in melt stability, drawability, gas barrier properties, hot water, oil and impact resistances and useful as films, etc. CONSTITUTION:The objective composition is composed of (A) 1-99wt.% partially saponified ethylene-vinyl acetate copolymer and (B) 99-1wt.% terminal-modified polyamide resin having terminal amino groups modified with a carboxylic acid or a carboxylic acid ester, equiv./g content of the residual terminal amino groups and 2.0-7.0 relative viscosity [etar] of the polymer.
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公开(公告)号：JPH04198360A
公开(公告)日：1992-07-17
申请号：JP32779690
申请日：1990-11-28
Applicant: TORAY INDUSTRIES
Inventor： OSANAWA NOBUO , NISHIMURA TORU , IWAMOTO MASAAKI
Abstract: PURPOSE:To obtain a composition, excellent in heat resistance, dimensional stability, etc., having low-temperature breaking resistance after coating and suitable as outside plate parts, etc., of automotive exterior trims by blending a specific modified polyphenylene ether with two same kinds of polyamides having specific different solution relative viscosities, etc. CONSTITUTION:A thermoplastic resin composition is obtained by blending (A) a modified polyphenylene ether prepared by reacting a polyphenylene ether derived from phenols expressed by formula I (R to R are H, 1-10C alkyl, etc.) with a substituted olefinic compound having a functional group selected from carboxylate group, etc., with (B) a polyamide resin which are the same kind of polyamides, having >=0.2 difference in solution relative viscosity and containing 50-99wt.% low-viscosity polyamide and 1-50wt.% high-viscosity polyamide and (C) a rubber component selected from A-B-A' type or A-B type block copolymer elastomers (A and A' are vinylic aromatic hydrocarbon; B is conjugated diene), hydrogenated A-B-A' type or A-B type block copolymer elastomers, etc., at (5-90)/(90-5)wt.% ratio. The amount of the component (C) is 1-25 pts.wt. based on 100 pts.wt. total amount of the components (A) and (B).
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