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    S,S-dialkyl-o-and s-alkenyl phosphites and phosphates
    48.
    发明授权
    S,S-dialkyl-o-and s-alkenyl phosphites and phosphates 失效
    S，S-二烷基-O-和s-烯基亚磷酸酯和磷酸酯

    公开(公告)号：US3885000A

    公开(公告)日：1975-05-20

    申请号：US37421873

    申请日：1973-06-27

    Applicant: CIBA GEIGY AG

    Inventor： BERIGER ERNST ,  MARTIN HENRY

    IPC: C07F9/165 ,  C07F9/201 ,  C07F9/16 ,  A01N9/36

    CPC classification number: C07F9/201 ,  C07F9/1651 ,  C07F9/1653

    Abstract: Phosphoric acid esters of the formula

    WHEREIN X denotes oxygen or sulphur, the integer n is the number 0 or 1, R'' and R'''' independently of each other represent an alkyl radical with 3 to 5 carbon atoms and wherein A. IF X is oxygen, R represents an alkoxyalkylene, alkylmercaptoalkylene or alkenyloxyalkylene radical with at most 7 carbon atoms, an alkenyl radical with 3 to 6 carbon atoms or an unsubstituted benzyl group or a benzyl group which is substituted by halogen, methyl and/or methoxy, or wherein B. IF X is sulphur, R represents an alkenyl radical with 3 to 6 carbon atoms or an unsubstituted benzyl group or a benzyl group substituted by halogen, methyl and/or methoxy; these compounds are useful for defoliating and promoting the ripening of crop plants especially cotton.

    Abstract translation: 式WHEREIN X表示氧或硫的磷酸酯，整数n为数0或1，R'和R“彼此独立地表示具有3至5个碳原子的烷基，其中A.Ix X为 氧，R表示烷氧基亚烷基，具有至多7个碳原子的烷基巯基亚烷基或烯氧基亚烷基，具有3至6个碳原子的烯基或未被取代的苄基或被卤素，甲基和/或甲氧基取代的苄基，或其中 B.FX是硫，R表示具有3至6个碳原子的烯基或未被取代的苄基或被卤素，甲基和/或甲氧基取代的苄基; 这些化合物可用于脱叶和促进作物特别是棉花的成熟。

    S,s-dialkyl-o-aliphaticoxyalkyl phosphites
    49.
    发明授权
    S,s-dialkyl-o-aliphaticoxyalkyl phosphites 失效
    S，S-DIALKYL-O-ALIPHATICOXYALKYL PHOSPHITES

    公开(公告)号：US3760042A

    公开(公告)日：1973-09-18

    申请号：US3760042D

    申请日：1971-01-08

    Applicant: CIBA GEIGY AG

    Inventor： BERIGER E ,  MARTIN H

    IPC: C07F9/16 ,  C07F9/165 ,  C07F9/173 ,  C07F9/201 ,  A01N9/36

    CPC classification number: C07F9/1651 ,  C07F9/16 ,  C07F9/1653 ,  C07F9/173 ,  C07F9/201 ,  C07F9/2015

    Abstract: Phosphoric acid esters of the formula

    D R A W I N G
    WHEREIN X denotes oxygen or sulphur, the integer n is the number 0 or 1, R'' and R'''' independently of each other represent an alkyl radical with 3 to 5 carbon atoms and wherein a. if X is oxygen, R represents an alkoxyalkyl, alkylmercaptoalkyl or alkenyloxyalkyl radical with at most 7 carbon atoms, an alkenyl radical with 3 to 6 carbon atoms or an unsubstituted benzyl group or a benzyl group which is substituted by halogen, methyl and/or methoxy, or wherein b. if X is sulphur, R represents an alkenyl radical with 3 to 6 carbon atoms or an unsubstituted benzyl group or a benzyl group substituted by halogen, methyl and/or methoxy; these compounds are useful for defoliating and promoting the ripening of crop plants especially cotton.

    Abstract translation: 式WHEREIN X表示氧或硫的磷酸酯，整数n是数字0或1，R'和R“彼此独立地表示具有3至5个碳原子的烷基，其中a。 如果X是氧，R代表具有至多7个碳原子的烷氧基烷基，烷基巯基烷基或烯氧基烷基，具有3-6个碳原子的烯基或被卤素，甲基和/或甲氧基取代的未取代的苄基或苄基 ，或其中b。 如果X是硫，R代表具有3至6个碳原子的烯基或未被取代的苄基或被卤素，甲基和/或甲氧基取代的苄基; 这些化合物可用于脱叶和促进作物特别是棉花的成熟。

    Polyphosphites
    50.
    发明授权
    Polyphosphites 失效
    多晶磷

    公开(公告)号：US3692879A

    公开(公告)日：1972-09-19

    申请号：US3692879D

    申请日：1970-01-15

    Applicant: WATSON CHEM CORP ,  KENNETH H RATTENBURY

    Inventor： RATTENBURY KENNETH H ,  LARRISON MILLARD S

    IPC: C07F9/201 ,  C08K5/5398 ,  C07F9/06 ,  C08F45/58 ,  C10M1/48

    CPC classification number: C08K5/5398 ,  C07F9/201 ,  Y10S524/925

    Abstract: Compounds are prepared having the formula WHERE R1 and R3 are alkyl, haloalkyl, aryl, haloaryl, alkenyl, aralkyl, haloalkenyl, cycloalkyl, R2 is a divalent aromatic, aliphatic or cycloaliphatic group and R4 and R5 are aryl or haloaryl. The compounds are useful as antioxidants.

    Abstract translation: 制备具有下式的化合物，其中R 1和R 3是烷基，卤代烷基，芳基，卤代芳基，烯基，芳烷基，卤代烯基，环烷基，R 2是二价芳族，脂族或脂环族基团，R 4和R 5是芳基或卤代芳基。

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