公开(公告)号：KR101219556B1

公开(公告)日：2013-01-08

申请号：KR1020090104023

申请日：2009-10-30

Applicant: 제일모직주식회사

Inventor： 김우중 ,  김만석 ,  주범준 ,  이선애 ,  이변근

IPC: C07F9/38 ,  C08K5/5317 ,  C08K5/521 ,  C08K5/53

CPC classification number: C07F9/657181 ,  C07F9/12 ,  C08K5/5313 ,  C08K5/5357

Abstract: 상기식에서, R은 C-C의알킬기이거나페닐기또는시아노기이고, R 및 R는, 각각독립적으로, 수소, C-C의알킬, 바람직하게는 t-부틸이다. 상기본 발명에따른난연성열가소성수지조성물은화재에대하여안정성이있고, 할로겐계난연제를사용하지않아연소시 환경오염을발생시키지않아환경친화적이며, 강도가우수한비할로겐계난연성열가소성수지조성물을제공한다.

公开(公告)号：KR101217827B1

公开(公告)日：2013-01-02

申请号：KR1020080135168

申请日：2008-12-29

Applicant: 제일모직주식회사

Inventor： 주범준 ,  김만석 ,  김우중 ,  이선애 ,  김명준

IPC: C08L69/00 ,  C08L51/04 ,  C08K5/527 ,  C08J5/00

Abstract: 본발명에따른폴리카보네이트계조성물은화재에대하여안정성이있고, 할로겐계난연제를사용하지않아연소시 환경오염을발생시키지않는환경친화적인난연성폴리카보네이트계수지조성물을제공한다.

公开(公告)号：KR101209103B1

公开(公告)日：2012-12-06

申请号：KR1020080136857

申请日：2008-12-30

Applicant: 제일모직주식회사

Inventor： 김만석 ,  김우중 ,  주범준 ,  이선애 ,  이변근

IPC: C08L69/00 ,  C08L53/02 ,  C08K5/527 ,  C08J5/00

Abstract: 본발명에따른폴리카보네이트계조성물은화재에대하여안정성이있고, 할로겐계난연제를사용하지않아연소시환경오염을발생시키지않는환경친화적인난연성폴리카보네이트계수지조성물을제공한다.

公开(公告)号：KR1020120078582A

公开(公告)日：2012-07-10

申请号：KR1020110114177

申请日：2011-11-03

Applicant: 제일모직주식회사

Inventor： 이민수 ,  고창홍 ,  이선애 ,  홍상현

IPC: C08G79/04 ,  C08L85/02 ,  C08L69/00 ,  C09K21/14

CPC classification number: C09K21/14

Abstract: PURPOSE: A polyphosphonate is provided to remarkably reduce acid value without using an end-capping agent, and to able to provide a flame retardant thermoplastic resin composition having excellent flame retardance, and thermal resistance, and not degrading other physical properties. CONSTITUTION: A polyphosphonate is in chemical formula 1, and has acid value of 5.5 KOH mg/g or less. In chemical formula 1, A is a single bond, C1-5 alkylene, C1-5 alkylidene, C5-6 cycloalkylidene, -S- or -SO2-, R is a substituted or unsubstituted C6-20 aryl group, or a C6-20 substituted or unsubstituted aryloxy group, R1 and R2 is respectively and independently a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C3-6 cycloalkyl group, a substituted or unsubstituted C6-12 aryl group, or halogen atom, and a and b is respectively an integer from 0-4, and n is an integer from 1-500.

Abstract translation: 目的：提供聚膦酸盐以不使用封端剂显着降低酸值，并且能够提供具有优异的阻燃性和耐热性并且不降解其它物理性能的阻燃热塑性树脂组合物。 构成：聚膦酸盐在化学式1中，酸值为5.5KOHmg / g以下。 在化学式1中，A是单键，C1-5亚烷基，C1-5亚烷基，C5-6亚环烷基，-S-或-SO2-，R是取代或未取代的C6-20芳基或C6- 20取代或未取代的芳氧基，R 1和R 2分别独立地为取代或未取代的C 1-6烷基，取代或未取代的C 3-6环烷基，取代或未取代的C 6-12芳基或卤素原子， b分别为0-4的整数，n为1-500的整数。

公开(公告)号：KR101156089B1

公开(公告)日：2012-06-20

申请号：KR1020080135464

申请日：2008-12-29

Applicant: 제일모직주식회사

Inventor： 이경훈 ,  김만석 ,  주범준 ,  이민수 ,  이선애

IPC: C09K21/12

Abstract: 본 발명에 따른 하기 화학식 1로 표시되는 새로운 구조의 디페녹시포스포릴계 난연제를 제공한다. 상기 난연제를 열가소성 수지 조성물에 적용할 경우, 친환경적이며, 우수한 난연성 뿐만 아니라, 개선된 유동성을 부여할 수 있어 가공 시에 잇점이 있다:
[화학식 1]

(상기 식에서, R
1
및 R
2 는 각각 독립적으로 H, C
1 -C
6 알킬기이고, n은 0～5의 정수이며, R3는 수소, C
1 -C
6 알킬기 또는 페닐기이고, R4는 수소, 메틸기 또는 페닐기임)
디페녹시포스포릴 난연제, 스티렌계 수지, 폴리페닐렌 에테르 수지, 인계 화합물

公开(公告)号：KR1020110078521A

公开(公告)日：2011-07-07

申请号：KR1020090135349

申请日：2009-12-31

Applicant: 제일모직주식회사

Inventor： 이선애 ,  배임혁 ,  주범준

IPC: C08L69/00 ,  C08L53/02 ,  C08K5/523 ,  C08K5/527

Abstract: PURPOSE: A polycarbonate resin composition is provided to ensure environment-friendliness while maintaining excellent flame retardancy and heat resistance and to enable the application to the molded products of electric/electronic materials. CONSTITUTION: A polycarbonate resin composition includes 100 parts by weight of a base resin and 0.1~40 parts by weight of a phosphorus compound. The phosphorus compound includes a phosphate-based compound represented by chemical formula 2 and a phosphate-based compound represented by chemical formula 3. The base resin comprises 30~99 weight% of a polycarbonate resin and 1~70 weight% of a rubber-modified aromatic vinyl resin.

Abstract translation: 目的：提供聚碳酸酯树脂组合物以确保环境友好性，同时保持优异的阻燃性和耐热性，并且能够应用于电子/电子材料的模制产品。 构成：聚碳酸酯树脂组合物包含100重量份的基础树脂和0.1〜40重量份的磷化合物。 磷化合物包括由化学式2表示的磷酸酯类化合物和由化学式3表示的磷酸酯类化合物。基础树脂包含30〜99重量％的聚碳酸酯树脂和1〜70重量％的橡胶改性 芳族乙烯基树脂。

公开(公告)号：KR101004668B1

公开(公告)日：2011-01-04

申请号：KR1020080091047

申请日：2008-09-17

Applicant: 제일모직주식회사

Inventor： 이선애 ,  홍상현 ,  신경훈

IPC: C08K5/10 ,  C08K5/5373 ,  C08L101/00

Abstract: 본 발명에 따른 난연성 열가소성 수지 조성물은 (A) 열가소성 수지 100 중량부; (B) 승화성 충진제(Sublimational Filler) 1∼40 중량부; 및 (C) 인계 난연제 1∼30 중량부를 포함하여 이루어진다. 상기 열가소성 수지 조성물은 종래 충진제 투입에 따른 고비중화와 난연성 저하문제를 해소할 수 있다.
승화성 충진제, 승화열, 스티렌 수지, 폴리페닐렌에테르, 인계 화합물

公开(公告)号：KR1020100080338A

公开(公告)日：2010-07-08

申请号：KR1020090104023

申请日：2009-10-30

Applicant: 제일모직주식회사

Inventor： 김우중 ,  김만석 ,  주범준 ,  이선애 ,  이변근

IPC: C07F9/38 ,  C08K5/5317 ,  C08K5/521 ,  C08K5/53

CPC classification number: C07F9/657181 ,  C07F9/12 ,  C08K5/5313 ,  C08K5/5357

Abstract: PURPOSE: A novel phosphonate compounds and flame retardant thermoplastic resin composition containing the same are provided to ensure stability and strength and to prevent environmental pollution. CONSTITUTION: A phosphonate compound is denoted by chemical formula 1. In chemical formula 1, R1 is alkyl group of C1-C4, phenyl group, or cyano group; and R2 and R3 are independently hydrogen and alkyl of C1-C4. A flame retardant thermoplastic resin composition contains 100 weight parts of thermoplastic resin and 0.5-30 weight parts of phosphonate compounds of chemical formula 1. The composition further contains 1-20 weight parts of phosphate flame retardant compound.

Abstract translation: 目的：提供一种新的膦酸酯化合物和含有它们的阻燃热塑性树脂组合物，以确保稳定性和强度，并防止环境污染。 构成：化学式1表示膦酸酯化合物。在化学式1中，R1为C1-C4，苯基或氰基的烷基; R2和R3独立地是氢和C1-C4的烷基。 阻燃热塑性树脂组合物含有100重量份的热塑性树脂和0.5-30重量份的化学式1的膦酸酯化合物。该组合物还含有1-20重量份的磷酸酯阻燃化合物。

公开(公告)号：KR1020100077509A

公开(公告)日：2010-07-08

申请号：KR1020080135464

申请日：2008-12-29

Applicant: 제일모직주식회사

Inventor： 이경훈 ,  김만석 ,  주범준 ,  이민수 ,  이선애

IPC: C09K21/12

Abstract: PURPOSE: A diphenoxyphosphoryl flame retardant is provided to obtain excellent flame retardant property, to be environment-friendly used without using a halogen retardant when a resin is processed or combusted, and to enable a user to easily handle the diphenoxyphosphoryl flame retardant due to solid phase. CONSTITUTION: A diphenoxyphosphoryl flame retardant is marked as a chemical formula 1. In the chemical formula 1, R1 and R2 are hydrogen or an alkyl group with C1-C6 and n is integer of 0-5. A method for manufacturing the diphenoxyphosphoryl flame retardant includes a step of reacting a compound of a chemical formula 2 with a diketone compound of a chemical formula 3. In the chemical formula 2, R1 and R2 are hydrogen or the alkyl group with C1-C6.

Abstract translation: 目的：提供二苯氧基磷酰基阻燃剂，以获得优异的阻燃性能，在树脂加工或燃烧时不使用卤素阻燃剂而环保使用，并且使用户能够容易地处理由固相产生的二苯氧基磷酰基阻燃剂 。 构成：二苯氧基磷酰基阻燃剂被标记为化学式1.在化学式1中，R 1和R 2是氢或具有C 1 -C 6的烷基，n是0-5的整数。 二苯氧基磷酰基阻燃剂的制造方法包括使化学式2的化合物与化学式3的二酮化合物反应的步骤。在化学式2中，R 1和R 2是氢或与C 1 -C 6的烷基。

公开(公告)号：KR1020100077266A

公开(公告)日：2010-07-08

申请号：KR1020080135168

申请日：2008-12-29

Applicant: 제일모직주식회사

Inventor： 주범준 ,  김만석 ,  김우중 ,  이선애 ,  김명준

IPC: C08L69/00 ,  C08L51/04 ,  C08K5/527 ,  C08J5/00

Abstract: PURPOSE: A non-halogen flameproof polycarbonate resin composition is provided to have stability to fire, to be environment-friendly used without using a halogen fire retardant, and to obtain excellent fire retardant property using a small amount of the fire retardant. CONSTITUTION: A non-halogen flameproof polycarbonate resin composition comprises 100.0 parts by weight of a base resin and a phosphonate compound which is marked as a chemical formula 1. The base resin is comprised of 50-100.0 parts by weight of a polycarbonate resin and 0-50 parts by weight of a rubber-modified styrene-based resin. In the chemical formula 1, R1 is a phenyl group or a cyano group and R2 and R3 are hydrogen or an alkyl group of C1-C4.

Abstract translation: 目的：提供非卤素防火聚碳酸酯树脂组合物以具有稳定的火焰，在不使用卤素阻燃剂的情况下使用环保，并且使用少量的阻燃剂获得优异的阻燃性能。 构成：非卤素防火聚碳酸酯树脂组合物包含100.0重量份的基础树脂和标记为化学式1的膦酸酯化合物。基础树脂由50-100.0重量份的聚碳酸酯树脂和0 -50重量份的橡胶改性苯乙烯类树脂。 在化学式1中，R 1是苯基或氰基，R 2和R 3是氢或C 1 -C 4的烷基。