公开(公告)号：KR101408134B1

公开(公告)日：2014-06-19

申请号：KR1020120043410

申请日：2012-04-25

Applicant: 한국과학기술연구원

Inventor： 김선진 ,  우경자 ,  조소혜 ,  박종구 ,  나유미

IPC: C09K11/79

CPC classification number: C09K11/7734 ,  C09K11/7706 ,  C09K11/7774

Abstract: 본 발명은 실리케이트 발광재료의 제조방법 및 실리케이트 발광재료에 과한 것으로, (1) 희토류 금속의 이온, NaOH, 실리카를 포함하는 수용액인 반응용액을 수열 처리하여 희토류 금속으로 치환된 실리카 층상물질을 얻는 수열처리단계, 그리고 (2) 상기 희토류 금속으로 치환된 실리카 층상물질을 소성하여 결정성 실리케이트 물질을 형성하는 소성단계를 포함하는 실리케이트 발광재료의 제조방법을 제공한다. 상기 실리케이트 발광재료의 제조방법은 공유결합성이 강하여 발광강도가 좋고, 고온에서도 안정하기 때문에 LED 용 발광재료로 활용될 수 있는 실리케이트 발광재료를 간단하고 경제성 있게 제조할 수 있으며, 다양한 종류의 희토류 금속을 실리콘 자리에 치환시키는 것이 가능하기 때문에 적색, 녹색, 청색 등의 발광을 선택적으로 이용할 수 있는 실리케이트 발광재료를 간단하고 경제적으로 제조할 수 있다.

公开(公告)号：KR101389832B1

公开(公告)日：2014-04-30

申请号：KR1020120126525

申请日：2012-11-09

Applicant: 한국과학기술연구원

Inventor： 박종구 ,  조소혜 ,  송봉근 ,  이승용 ,  박보인 ,  박형호

IPC: H01L31/0749 ,  H01L31/042 ,  H01L31/18

CPC classification number: H01L31/0322 ,  H01L31/0326 ,  H01L31/03923 ,  H01L31/072 ,  H01L31/0749 ,  Y02E10/541 ,  Y02P70/521

Abstract: The present invention relates to CIGS or CZTS based film solar cells and a method for preparing thereof. According to one embodiment of the present invention, the CIGS or CZTS based film solar cells and a method for preparing thereof include a substrate, a molybdenum backside electrode layer, a Cu thin film, and a light absorption powder layer. The composition of light absorption powder layer has CuxInyGa1-y(SzSe1-z)2 (0

Abstract translation: 本发明涉及基于CIGS或CZTS的薄膜太阳能电池及其制备方法。 根据本发明的一个实施例，基于CIGS或CZTS的薄膜太阳能电池及其制备方法包括基板，钼背面电极层，Cu薄膜和光吸收粉末层。 光吸收粉末层的组成具有CuxInyGa1-y（SzSe1-z）2（0

公开(公告)号：KR1020130036269A

公开(公告)日：2013-04-11

申请号：KR1020130019391

申请日：2013-02-22

Applicant: 한국과학기술연구원

Inventor： 박종구 ,  조소혜 ,  최벽파 ,  박수영

IPC: C01B33/18 ,  C01B37/02 ,  C09D1/00 ,  G02B1/02

CPC classification number: C01B33/18 ,  C01P2002/70 ,  C01P2004/32 ,  C01P2006/60 ,  C09D1/00

Abstract: PURPOSE: A sphere oxide particle, a manufacturing method thereof, and a photonic crystal and a coating agent of the particle are provided to regularly arrange a silica particle in a wide area and manufacture a three dimensional megacrystal by preventing a monodisperse oxide particle changing the particle property according to an external circumstance. By remarkably increasing the stability of the silica particle according to the heating process, the sphere oxide particle, the manufacturing method thereof, and the photonic crystal and a coating agent of the particle are provided to lengthen a processing time and select a processing temperature from a room temperature to the hundreds >=. CONSTITUTION: A manufacturing method of a sphere oxide particle satisfying more than one among below properties include heating the sphere oxide particle in a temperature higher than a room: (1) A weight reduction after the heating processing higher than 550>= is 12 weight% or less; (2) A non-surface area increasing rate after the heating processing higher than 550>= is 9% or less; (3) A size contraction (average diameter changing standard) after the heating processing higher than 550>= is 2 % or less; (4) A transmittance at 960 cm^-1 is 9% or less than the transmittance at 1100 cm^-1 when measuring an infrared spectrum in a powdered status; (5) An inclination augmenter within a Q=0.7~2 nm^-1 domain is 8% or less than before the heating processing when analyzing a low-angle scattering X-ray in the powdered status after the heating process higher than 550>=. [Reference numerals] (AA) Weight[%]; (BB) Temperature[°C];

Abstract translation: 目的：提供球形氧化物颗粒，其制造方法，以及颗粒的光子晶体和涂层剂，以规模地将二氧化硅颗粒布置在广泛的区域，并通过防止单分散氧化物颗粒改变颗粒来制造三维晶体 财产根据外部情况。 通过根据加热工艺显着提高二氧化硅颗粒的稳定性，提供球状氧化物颗粒，其制造方法以及颗粒的光子晶体和涂层剂，以延长处理时间，并从 室温到数百= 构成：在以下特性中满足多于一个的球状氧化物粒子的制造方法包括在高于室内的温度下加热球状氧化物粒子：（1）加热处理后的重量减少高于550≥= 12重量％ 或更少; （2）加热处理后的550℃以上的非表面积增加率为9％以下; （3）加热处理后的尺寸收缩（平均直径变化标准）高于550≥= 2％以下; （4）当测量粉末状态下的红外光谱时，960cm -1处的透射率为在1100cm -1处的透射率的9％或更小; （5）在加热处理后的加热处理中分析散热状态下的低角度散射X射线高于550℃以上时，Q = 0.7〜2nm ^ -1区域内的倾斜增强器为8％以下， =。 （标号）（AA）重量[％]; （BB）温度[℃];

公开(公告)号：KR1020130006577A

公开(公告)日：2013-01-17

申请号：KR1020120143120

申请日：2012-12-10

Applicant: 한국과학기술연구원

Inventor： 조소혜 ,  박종구 ,  지현석 ,  최형일 ,  송봉근

IPC: C01G23/047 ,  H01L31/042 ,  H01B1/08 ,  B82B3/00

CPC classification number: Y02E10/542 ,  C01G23/053 ,  C01G23/08 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/90 ,  H01G9/2031

Abstract: PURPOSE: A titanium dioxide nanopowder for high efficiency longevity dye-sensitized solar cell and a manufacturing method thereof are provided to increase photoelectric conversion efficiency through vapor synthesis and post-annealing. CONSTITUTION: A titanium dioxide nanopowder for high efficiency longevity dye-sensitized solar cell and a manufacturing method thereof comprises the following steps: forming titanium nanopowder by using titanium alkoxide precursor; and post-annealing the titania nanopowder to form anatase type titanium nanopowder having bipyramid structure. The titanium dioxide precursor is one or more selected from titanium tetraisopropoxide, titanium methoxide, titanium ethoxide, titanium butoxide, titanium tertiary butoxide and titanium ethylhexoxide. The post-annealing is processed at 400-600 deg. Celsius for 0.5-10 hours.

Abstract translation: 目的：提供一种用于高效寿命染料敏化太阳能电池的二氧化钛纳米粉末及其制造方法，以通过蒸气合成和后退火提高光电转换效率。 构成：用于高效寿命染料敏化太阳能电池的二氧化钛纳米粉末及其制造方法包括以下步骤：通过使用钛醇盐前体形成钛纳米粉末; 并对二氧化钛纳米粉末进行后退火，形成具有双吡啶结构的锐钛矿型钛纳米粉末。 二氧化钛前体是选自四异丙氧基钛，甲醇钛，乙醇钛，丁醇钛，叔丁醇钛和乙基己酸乙酯中的一种或多种。 后退火在400-600度处理。 摄氏0.5-10小时。

公开(公告)号：KR1020110121020A

公开(公告)日：2011-11-07

申请号：KR1020100040420

申请日：2010-04-30

Applicant: 한국과학기술연구원

Inventor： 박종구 ,  조소혜 ,  최벽파 ,  박수영

IPC: C01B33/18 ,  C01B37/02 ,  C09D1/00 ,  G02B1/02

CPC classification number: C01B33/18 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/03 ,  C01P2004/04 ,  C08K3/22 ,  C08K3/36 ,  C08K7/26 ,  C09D1/02 ,  C09D7/70 ,  C01P2002/70 ,  C01P2004/32 ,  C09D1/00

Abstract: PURPOSE: A method for reducing the generation of defects in a spherical oxide particle arranging process is provided to obtain three dimensionally large size of crystals and to regularly arrange silica particles on a wide area. CONSTITUTION: The weight reduction of spherical oxide particles is less than or equal to 12 weight% after a heating process is implemented at 550 degrees Celsius or more. The specific surface area increasing rate of the spherical oxide particles is less than or equal to 9 weight% after the heating process is implemented at 550 degrees Celsius or more. The size shrinkage of the spherical oxide particles is less than or equal to 2% after the heating process is implemented at 550 degrees Celsius or more. The transmittance of the spherical oxide particles at 960 cm^-1 is 9% lower than that of the spherical oxide particles at 1100cm^-1 in an infrared ray spectrum measuring process.

Abstract translation: 目的：提供一种用于减小球形氧化物颗粒排列过程中的缺陷产生的方法，以获得三维大尺寸的晶体并且在大面积上规则地排列二氧化硅颗粒。 构成：在550摄氏度或更高温度下进行加热处理后，球形氧化物颗粒的重量减少小于或等于12重量％。 在550摄氏度以上的加热处理之后，球形氧化物粒子的比表面积增加率小于或等于9重量％。 在550摄氏度或更高温度下进行加热处理后，球形氧化物颗粒的尺寸收缩率小于或等于2％。 在红外线光谱测量过程中，960cm -1处的球形氧化物颗粒的透射率比1100cm ^ -1处的球形氧化物颗粒的透射率低9％。