公开(公告)号：US20150203708A1

公开(公告)日：2015-07-23

申请号：US14416303

申请日：2013-03-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Alan K. Nachtigal ,  Joseph C. Spagnola ,  Mark A. Roehrig ,  Jennifer K. Schnobrich ,  Guy D. Joly ,  Christopher S. Lyons

IPC: C09D135/02 ,  C23C16/44 ,  C08K3/34 ,  C23C14/08 ,  B05D3/10 ,  B05D1/00 ,  C23C14/34 ,  C23C16/40

CPC classification number: C09D143/04 ,  B05D1/60 ,  B05D3/067 ,  B05D3/068 ,  B05D3/101 ,  B32B27/308 ,  B32B2250/04 ,  B32B2307/7242 ,  B32B2307/7244 ,  C07F7/1804 ,  C08F130/08 ,  C08J7/045 ,  C08J2333/12 ,  C08K3/34 ,  C09D133/14 ,  C09D135/02 ,  C09J133/14 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  H01L51/004 ,  H01L51/107 ,  H01L51/448 ,  H01L51/5253 ,  Y10T428/1064 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31609 ,  Y10T428/31663

Abstract: Urethane (multi)-(meth)acrylate (multi)-silane compositions, and articles including a (co)polymer reaction product of at least one urethane (multi)-(meth)acrylate (multi)-silane precursor compound. The disclosure also articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urethane (multi) (meth)acrylate (multi)-silane precursor compound. The substrate may be a (co)polymeric film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making urethane (multi)-(meth)acrylate (multi)-silane precursor compounds and their use in composite multilayer barrier films are also described. Methods of using such barrier films in articles selected from a solid state lighting device, a display device, and combinations thereof, are also described

Abstract translation: 聚氨酯（多） - （甲基）丙烯酸酯（多） - 硅烷组合物，以及包含至少一种聚氨酯（多） - （甲基）丙烯酸酯（多） - 硅烷前体化合物的（共）聚合物反应产物的制品。 本公开还涉及包括基材，基材主表面上的基底（共））聚合物层，基底（共）聚合物层上的氧化物层的制品; 和氧化物层上的保护（共）聚合物层，所述保护（共）聚合物层包括至少一种聚氨酯（多）（甲基）丙烯酸酯（多） - 硅烷前体化合物的反应产物。 基底可以是（共）聚合物膜或诸如有机发光器件，电泳发光器件，液晶显示器，薄膜晶体管或其组合的电子器件。 还描述了制备聚氨酯（多） - （甲基）丙烯酸酯（多） - 硅烷前体化合物的方法及其在复合多层阻挡膜中的应用。 还描述了在选自固态照明装置，显示装置及其组合的制品中使用这种阻挡膜的方法

公开(公告)号：US20150194541A1

公开(公告)日：2015-07-09

申请号：US14420060

申请日：2013-08-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joseph C. Spagnola ,  Mark A. Roehrig ,  Thomas P. Klun ,  Alan K. Nachtigal ,  Jennifer K. Schnobrich ,  Guy D. Joly

IPC: H01L31/0216 ,  B32B27/30 ,  C09D183/04 ,  B05D1/00

CPC classification number: H01L31/02167 ,  B05D1/60 ,  B05D7/04 ,  B05D7/56 ,  B32B7/12 ,  B32B27/08 ,  B32B27/281 ,  B32B27/283 ,  B32B27/286 ,  B32B27/288 ,  B32B27/30 ,  B32B27/308 ,  B32B27/36 ,  B32B33/00 ,  B32B2307/554 ,  B32B2307/558 ,  B32B2307/584 ,  B32B2307/712 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2307/7248 ,  B32B2457/00 ,  B32B2457/12 ,  B32B2457/20 ,  C08J7/045 ,  C08J2367/02 ,  C08J2433/14 ,  C08J2483/04 ,  C09D183/04 ,  G02F1/133305 ,  G02F2001/133337 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31547 ,  Y10T428/31663

Abstract: A barrier film that includes a substrate, a first polymer layer on a major surface of the substrate, an oxide layer on the first polymer layer, and a second polymer layer on the oxide layer. At least one of the first or second polymer layers includes a siloxane reaction product of a secondary or tertiary amino-functional silane having at least two silane groups. A method of making the barrier film and articles and a barrier assembly including the barrier film are also disclosed.

Abstract translation: 一种阻挡膜，其包括基板，在所述基板的主表面上的第一聚合物层，所述第一聚合物层上的氧化物层，以及所述氧化物层上的第二聚合物层。 第一或第二聚合物层中的至少一个包括具有至少两个硅烷基团的仲或叔氨基官能的硅烷的硅氧烷反应产物。 还公开了制造阻挡膜和制品的方法和包括阻挡膜的阻挡组件。

公开(公告)号：US20140162517A1

公开(公告)日：2014-06-12

申请号：US14182741

申请日：2014-02-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guy D. Joly ,  Leon Levitt ,  Vivek Bharti

IPC: C09J7/02

CPC classification number: C09J7/021 ,  C08K5/0016 ,  C08L23/36 ,  C08L33/064 ,  C08L2666/02 ,  C09J7/381 ,  C09J123/22 ,  Y10T156/10 ,  Y10T428/249983 ,  Y10T428/2839 ,  Y10T428/2848 ,  Y10T428/2891 ,  Y10T442/2754

Abstract: Adhesive compositions are described comprising a) a non-functional isobutylene (co)polymer, b) an amine-functional poly(isobutylene) polymer, optionally an acid-functional (meth)acrylate copolymer, and optionally a tackifier.

Abstract translation: 描述的粘合剂组合物包括a）非功能异丁烯（共）聚合物，b）胺官能聚（异丁烯）聚合物，任选的酸官能（甲基）丙烯酸酯共聚物，以及任选的增粘剂。

公开(公告)号：US08569537B2

公开(公告)日：2013-10-29

申请号：US13661086

申请日：2012-10-26

Applicant: 3M Innovative Properties Company

Inventor： Guy D. Joly ,  Nathan E. Schultz ,  Encai Hao

IPC: C07C275/64 ,  C07C69/52 ,  C09D1/00 ,  C07C229/38

CPC classification number: C09D5/006 ,  C01G25/02 ,  C01P2006/60 ,  C07C275/64 ,  C07C2601/14 ,  C08K3/22 ,  C08K9/04 ,  C08K2003/2244 ,  C09D7/62

Abstract: The present disclosure relates to surface-modified zirconia nanoparticles, methods for making and using the same, and high index of refraction films made therefrom. The provided zirconia nanoparticles are surface modified with ligands that include N-hydroxyurea functionalities. The provided ligands also can contain compatibilizing groups that allow the provided surface-modified zirconia nanoparticles to be incorporated into an organic matrix. High index of refraction films can be made using these organic matrices.

公开(公告)号：US11111320B2

公开(公告)日：2021-09-07

申请号：US16591055

申请日：2019-10-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： William H. Moser ,  Ann R. Fornof ,  Guy D. Joly ,  Serkan Yurt ,  Larry R. Krepski ,  Ahmed S. Abuelyaman ,  Afshin Falsafi ,  Bradley D. Craig ,  Joel D. Oxman ,  Babu N. Gaddam

IPC: C08F22/10 ,  C07F7/18 ,  C09J4/06 ,  C08F292/00 ,  A61K6/62 ,  A61K6/71 ,  A61K6/887 ,  C09D7/61 ,  C07C69/602 ,  C07F9/09 ,  C09D4/00 ,  C08K3/36

Abstract: Novel stress-reducing crosslinking oligomers that have application in dental restoratives, thin films, hardcoats, composites, adhesives, and other uses subject to stress reduction are described. The addition-fragmentation process of crosslinking results in a chain-transfer event that provides novel polymers that may be further functionalized. In addition, the addition-fragmentation oligomer comprises pendent functional groups that bond to a substrate by forming an ionic or covalent bond, or etch the substrate by chemically removing some material from the substrate.

公开(公告)号：US10947618B2

公开(公告)日：2021-03-16

申请号：US16266254

申请日：2019-02-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joseph C. Spagnola ,  Mark A. Roehrig ,  Thomas P. Klun ,  Alan K. Nachtigal ,  Christopher S. Lyons ,  Guy D. Joly

IPC: C23C14/22 ,  C08J7/04 ,  C23C14/02 ,  C23C14/08 ,  C23C14/12 ,  C23C14/34 ,  C23C14/58 ,  C23C28/00 ,  C23C14/14 ,  C08J7/048 ,  H01J1/70

Abstract: A barrier film including a substrate; a base polymer layer adjacent to the substrate; an oxide layer adjacent to the base polymer layer; a adhesion-modifying layer adjacent to the oxide layer; and a top coat polymer layer adjacent to the adhesion-modifying layer. An optional inorganic layer can be applied over the top coat polymer layer. The inclusion of a adhesion-modifying layer provides for enhanced resistance to moisture and improved peel strength adhesion of the top coat polymer layer to the underlying barrier stack layers.

公开(公告)号：US10894905B2

公开(公告)日：2021-01-19

申请号：US16323573

申请日：2017-08-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ilya Gorodisher ,  Gregory P. Sorenson ,  Guy D. Joly

IPC: C09K3/00 ,  C09K3/14 ,  B24D3/28 ,  C08G8/10 ,  C08G8/04 ,  C08G8/22 ,  C08G8/20 ,  C08G8/24

Abstract: A catalyst for use with a phenolic resins which imparts accelerated curing at reduced temperatures. The catalyst is selected from elemental halogen or opium polyhalide compounds of the general formula: O+X(2n+1)−, where 1≤n≤4, Q is onium group, preferably selected from ammonium, sulfonium and phosphonium; and X is a halide. Each X may be the same or different and may include mixed halides such a X═Br2Cl or Cl2Br.

公开(公告)号：US10774236B2

公开(公告)日：2020-09-15

申请号：US15955151

申请日：2018-04-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Alan K. Nachtigal ,  Joseph C. Spagnola ,  Mark A. Roehrig ,  Jennifer K. Schnobrich ,  Guy D. Joly ,  Christopher S. Lyons

IPC: C09D143/04 ,  H01L51/00 ,  H01L51/52 ,  H01L51/44 ,  H01L51/10 ,  B05D3/06 ,  B32B27/30 ,  C07F7/18 ,  C09J133/14 ,  C08J7/04 ,  C09D133/14 ,  B05D1/00 ,  B05D3/10 ,  C08K3/34 ,  C09D135/02 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  C08F130/08

Abstract: Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-(meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the urea (multi)-(meth)acrylate (multi)-silanes and their use in composite films and electronic devices are described.

公开(公告)号：US20200087447A1

公开(公告)日：2020-03-19

申请号：US16471885

申请日：2018-02-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ying Lin ,  Hassan Sahouani ,  Guy D. Joly

IPC: C08G59/66 ,  C08G59/24 ,  C08G59/68 ,  C08K3/08 ,  C08K3/26 ,  C08K3/36 ,  H01B3/00 ,  H01B3/30

Abstract: The present disclosure provides a curable, one-part epoxy/thiol resin composition. The composition comprises an epoxy/thiol resin mixture including: an epoxy resin component including an epoxy resin having at least two epoxide groups per molecule, a thiol component including a polythiol compound having at least two primary thiol groups, and a nitrogen-containing catalyst for the epoxy resin. The epoxy/thiol resin mixture further includes metal nanoparticles (e.g., silver nanoparticles, copper nanoparticles, or both), dispersed in the epoxy/thiol resin mixture. The present disclosure provides a method of curing a curable, one-part epoxy/thiol resin composition, including providing a curable, one-part epoxy/thiol resin composition and heating the composition to a temperature of at least 50° C.

公开(公告)号：US20200031961A1

公开(公告)日：2020-01-30

申请号：US16591055

申请日：2019-10-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： William H. Moser ,  Ann R. Fornof ,  Guy D. Joly ,  Serkan Yurt ,  Larry R. Krepski ,  Ahmed S. Abuelyaman ,  Afshin Falsafi ,  Bradley D. Craig ,  Joel D. Oxman ,  Babu N. Gaddam

IPC: C08F22/10 ,  C09J4/06 ,  C08F292/00 ,  C07F7/18 ,  C09D7/61 ,  A61K6/00 ,  A61K6/083 ,  C07C69/602 ,  C07F9/09 ,  C09D4/00

Abstract: Novel stress-reducing crosslinking oligomers that have application in dental restoratives, thin films, hardcoats, composites, adhesives, and other uses subject to stress reduction are described. The addition-fragmentation process of crosslinking results in a chain-transfer event that provides novel polymers that may be further functionalized. In addition, the addition-fragmentation oligomer comprises pendent functional groups that bond to a substrate by forming an ionic or covalent bond, or etch the substrate by chemically removing some material from the substrate.