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公开(公告)号：JPS6259934A
公开(公告)日：1987-03-16
申请号：JP19970585
申请日：1985-09-10
Applicant: AGENCY IND SCIENCE TECHN
Inventor： OKADA SHUJI , MATSUDA HIROO , NAKANISHI HACHIRO , KATO MASAO , SAMURA HIDEO
IPC: G02F1/35 , C07C211/42 , G02F1/313 , G02F1/355 , G02F1/361
Abstract: PURPOSE:To obtain the titled material having a large 2nd high frequency generating capacity (SHG) and a high stability at a room temp. and a large-sized monocrystal by incorporating a specific org. compd. to the titled material. CONSTITUTION:The titled material comprises a 2-amino fluorenone shown by formula I or a 4-amino-4'-nitrobiphenyl shown by formula II. The prescribed compds. may grow to the large monocrystal by a slow evaporation method. The prescribed compds. has a SHG larger than that of an urea by few times and has a good stability at the room temp. and may be easily grown to the large monocrystal. Thus, the titled material is used for materials of an optical wavelength conversion element, an optical shutter, a high switching element, a optical logical gate and an phototransistor.
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公开(公告)号：JP2000136384A
公开(公告)日：2000-05-16
申请号：JP31358198
申请日：1998-11-04
Applicant: AGENCY IND SCIENCE TECHN , TAMAOKI NOBUYUKI , MATSUDA HIROO
Inventor： TAMAOKI NOBUYUKI , MORIYAMA MASAYA , MATSUDA HIROO
Abstract: PROBLEM TO BE SOLVED: To provide a method for forming a solid thin film having an optical rotatory power and exhibiting an interference color, a solid thin film formed thereby, and a color recording material. SOLUTION: This method for forming a solid thin film having an optical rotatory power and exhibiting an interference color comprises dissolving a cholesteric liquid crystal compound having a mol.wt. of 800-3,000 and a glass transition point of 30 deg.C or higher or a mixture of such compounds in an organic solvent and applying the resultant solution to a substrate or film having a smooth surface by spin coating, by casting, or with an applicator or a wire bar. The solid film is formed by the method, and the color recording material comprises the solid thin film.
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53.发明专利
公开(公告)号：JP2000089398A
公开(公告)日：2000-03-31
申请号：JP25253398
申请日：1998-09-07
Applicant: AGENCY IND SCIENCE TECHN , TAMAOKI NOBUYUKI , MATSUDA HIROO
Inventor： TAMAOKI NOBUYUKI , SO SHOEI , MATSUDA HIROO
Abstract: PROBLEM TO BE SOLVED: To provide a reloadable color image recording medium by light of a short recording time and a color image recording method using the same. SOLUTION: This color image recording medium is formed by holding a compsn. obtd. by adding a 0.5 to 10 wt.% photochromic compd. to cholesteric liquid crystalline compds. having a mol.wt. of =35 deg.C between two sheets of substrates or films at least one of which are transparent or a mixture composed of these liquid crystalline compds. This color image forming method consists in subjecting the reloadable color image recording medium formed by holding the compsn. described above between two sheets of the substrates or films at least one of which are transparent to photoirradiation at a temp. at which the compsn. exhibits cholesteric liquid crystallinity or below, then rapidly cooling the recording medium down to a temp. below the glass transition tamp. at a rate of >=1 deg.C/sec.
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公开(公告)号：JP2000044592A
公开(公告)日：2000-02-15
申请号：JP21759698
申请日：1998-07-31
Applicant: AGENCY IND SCIENCE TECHN , TAMAOKI NOBUYUKI , MATSUDA HIROO , RICOH KK , OKAMURA OIL MILL
Inventor： TAMAOKI NOBUYUKI , MATSUDA HIROO , KIDA YOSHIE
Abstract: PROBLEM TO BE SOLVED: To obtain a new liquid crystalline compound consisting of a specific cholesterol derivative, capable of exhibiting red color hard to be developed with conventional thermal recording materials, and useful as an erasable full- color thermal recording material or the like. SOLUTION: This new liquid crystalline compound consisting of a new cholesterol derivative is shown by formula I [A is an 1,5-hexadienylene of formula II (R is H or methyl); Y is a cholesterol residue as a result of eliminating the hydroxyl group from cholesterol; (n) is 5-7], e.g. 8,12-eicosadienoic diacid dicholesteryl ester. This liquid crystalline compound is useful as e.g. a full-color thermal recording material freed from such a problem being hard to present red color as to be involved in conventional erasable full-color thermal recording materials. This compound of formula I is obtained by reaction of a dicarboxylic acid such as 8,12-eicosadienoic diacid with the corresponding cholesterol in the presence of dicyclohexylcarbodiimide and 4-dimethylaminopyridine.
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55.发明专利
公开(公告)号：JPH11322678A
公开(公告)日：1999-11-24
申请号：JP14229198
申请日：1998-05-08
Applicant: AGENCY IND SCIENCE TECHN , FUKUDA TAKASHI , MATSUDA HIROO
Inventor： FUKUDA TAKASHI , MATSUDA HIROO , KIMURA TATSUMI , MORIYA NORIHIKO , KATO MASAO , OKADA SHUJI , NAKANISHI HACHIRO
Abstract: PROBLEM TO BE SOLVED: To obtain a new aromatic ester oligomer giving organic secondary nonlinear optical materials having good optical transparency and secondary nonlinear optical characteristics and not causing the deterioration of the characteristics with the passage of time. SOLUTION: A compound of formula I [R and R are each H or methyl; (n) and (n') are each 4-10; (m) is 2-5], for example, 4-[4'-(6-acryloyloxyhexyloxy) phenylcarbonyloxy]benzoic acid 6-acryloyloxyhexyl ester. The compound of formula I is preferably obtained by a method comprising converting an aromatic carboxylic acid of formula II [for example, 4-(6-acryloyloxyhexyloxy)benzoic acid] into the corresponding acid halide by the use of thionyl chloride, etc., and subsequently reacting the acid halide with a compound of formula III (for example, 4-hydroxybenzoic acid 6-acryloyloxyhexyl ester) in the presence of a hydrogen halide-capturing agent such as triethylamine in an organic solvent such as tetrahydrofuran.
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Patent Agency Ranking
公开(公告)号：JPH11258642A
公开(公告)日：1999-09-24
申请号：JP7660398
申请日：1998-03-10
Applicant: AGENCY IND SCIENCE TECHN , TOKUYAMA CORP , MATSUDA HIROO , FUKUDA TAKASHI
Inventor： KAWASAKI TAKEYOSHI , MATSUDA HIROO , FUKUDA TAKASHI
Abstract: PROBLEM TO BE SOLVED: To obtain an org. polymer molding in which the refractive index can be reversibly changed with a large change width, and moreover, which can be easily formed, by using a material in which the refractive index is reversibly changed by irradiation of incoherent light and stopping the irradiation and controlling the change width of the refractive index to a specified value or larger. SOLUTION: The refractive index of the formed body is reversibly changed by irradiation of incoherent light or by stopping the irradiation, and further, the change width of the refractive index is >=0.005. From the viewpoints of easy production and a large change rate of the refractive index, the org. polymer which constitutes the formed body is preferably a linear or branched-chain org. polymer having polar org. groups on the side chains. Generally, the mol.wt. of the org. polymer ranges 1.000 to 500,000 of the weight average mol.wt., and preferably 5,000 to 300,000. Further, 2,6-diphenyl-4-(2,4,6-triphenylpyridinio)- phenolate is preferably added as an additive.
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公开(公告)号：JPH11100385A
公开(公告)日：1999-04-13
申请号：JP26459797
申请日：1997-09-29
Applicant: AGENCY IND SCIENCE TECHN , SHIMADA SATORU , ONISHI SATOMI , MATSUDA HIROO , NAKANISHI FUSAE
Inventor： SHIMADA SATORU , ONISHI SATOMI , MATSUDA HIROO , NAKANISHI FUSAE , TAKEDA HIROYUKI
Abstract: PROBLEM TO BE SOLVED: To obtain gold with an adsorbed unimolecular layer of an organic thio group, useful as a nonlinear optical material by bringing the gold into contact with a specific solution in the presence of fluoride ion. SOLUTION: This gold with an adsorbed unimolecular layer of an organic thio group is the gold having the organic thio group of formula I or II [R , R , R and R are each an aryl or an (un)saturated aliphatic group] on the surface thereof adsorbed so as to form the unimolecular layer, and obtained by bringing the gold into contact with a solution containing tri(lower alkyl) silylethyl sulfide of formula III [R is an aryl or an (un)saturated apliphatic group] in the presence of fluoride ion. For example, a quarternary ammonium salt and hydrofluoric acid, especially tetrabutylammonium fluoride, are used as a fluoride ion source.
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公开(公告)号：JPH04189805A
公开(公告)日：1992-07-08
申请号：JP32034290
申请日：1990-11-22
Applicant: AGENCY IND SCIENCE TECHN
Inventor： OKADA SHUJI , MATSUDA HIROO , MASAKI ATSUSHI , NAKANISHI HACHIRO , HIRAIZUMI KIKUKO
Abstract: PURPOSE:To easily obtain the subject material useful for electronic material, etc., by a solid-phase polymerization comprising the irradiation of a crystal of a specific tetraacetylene molecule with light or radiation or by a two-stage solid-phase polymerization comprising the thermal polymerization of the above crystal at a temperature below its melting point and the post-polymerization of the obtained polymer. CONSTITUTION:The objective conjugated polymer material consisting of a di(polydiacetylene) of formula IV can be produced either by irradiating a crystal of the molecule of a tetraacetylene of formula I [R and R' are CH3(CH2)x (x is 0-19) or group of formula II (y is 0-19; z is 1-9)] (e.g. 15,17,19,21- hexatriacontatetrayne) with light (e.g. ultraviolet light or visible light) or radiation (e.g. X-ray or gamma-ray) or by heating the crystal at a temperature below the melting point of the crystal to obtain a polymer of formula III (n is polymerization degree) and irradiating the polymer with light (e.g. ultraviolet light or visible light) or radiation (e.g. X-ray or gamma-ray) or heating the polymer.
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公开(公告)号：JPH0291106A
公开(公告)日：1990-03-30
申请号：JP24315088
申请日：1988-09-28
Applicant: AGENCY IND SCIENCE TECHN
Inventor： MATSUDA HIROO , NAKANISHI HACHIRO , KATO MASAO
IPC: C08F138/00
Abstract: PURPOSE:To produce the title crystal which has a high strength isotropically and a network structure having covalent bonds multi-dimensionally by subjecting crystals obtained from diacetylenedicarboxylic acid, a polyvalent metal carbonate and/or a polyvalent metal acetate to solid-state polymerization. CONSTITUTION:0.1-100mmol/l of a solution of a diacetylenedicarboxylic acid of the given formula (wherein n is 0-20) is added to a solution of a polyvalent metal carbonate and/or a polyvalent metal acetate (e.g., copper acetate) in a molar ratio of the acid to the metal salt of 1:(1-2) to form a homogeneous solution or suspension, which is stirred to react them at room temperature to 100 deg.C or below, thereby producing diacetylenedicarboxylic acid metal salt crystals. The crystals are irradiated with ultraviolet light for several to 100 hours, or with tens of MRad to hundreds of MRad or gamma ray (e.g., cobalt 60) in a vacuum, or are heated at tens of degrees to 200 deg.C for tens of hours to hundreds of hours, or are subjected to several thousands to ten thousands of atmospheres for tens of minutes, thereby effecting the solid-state polymerization.
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公开(公告)号：JPS6348265A
公开(公告)日：1988-02-29
申请号：JP19240486
申请日：1986-08-18
Applicant: AGENCY IND SCIENCE TECHN
Inventor： OKADA SHUJI , MATSUDA HIROO , NAKANISHI HACHIRO , KATO MASAO , MURAMATSU RYOJI
IPC: C07D213/30 , C07D213/38 , G02F1/35 , G02F1/355 , G02F1/361
Abstract: PURPOSE:To obtain the titled material useful as material for a light wavelength converting element, etc., stable at room temperature, readily providing large single crystal, comprising p-toluenesulfonic acid 1-methyl-4-[2-(4-hydroxyphenyl) vinyl[pyridinium. CONSTITUTION:An organic material for non-linear optical use comprising p- toluenesulfonic acid 1-methyl-4-[2-(4-hydroxyphenyl)vinyl] pyridinium shown by formula I and one comprising p-toluenesulfonyl acid 1-methyl-4-[2-(4-(N,N- dimethylamino)phenyl)] vinyl pyridinium shown by formula II. The compounds shown by formula I and formula II are synthesized by condensing 1,4- dimethylbipyridinium obtained from gamma-picoline and methyl iodide with 4- hydroxybenzaldehyde and 4-(N,N-dimethylamino)benzaldehyde through dehydration and reacting the reaction products with p-toluenesulfonic acid. Large single crystal is obtained by slow evaporation method, etc.
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