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公开(公告)号:DE60026679T2
公开(公告)日:2006-10-19
申请号:DE60026679
申请日:2000-12-21
Applicant: AGENCY IND SCIENCE TECHN
Inventor: FUKUDA TAKASHI , MATSUDA HIROO , SUMARU KIMIO , KIMURA TATSUMI , KATO MASAO
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公开(公告)号:FR2763066B1
公开(公告)日:2001-01-05
申请号:FR9803379
申请日:1998-03-19
Applicant: AGENCY IND SCIENCE TECHN
Inventor: MATSUDA HIROO , FUKUDA TAKASHI , YAMADA SHINJI , KIMURA TATSUMI , KATO MASAO , BUAN XUAN MING , OKADA SHUJI , NAKANISHI HACHIRO
IPC: C07C69/92 , C07C205/43 , C07C255/55 , C08F2/00 , G02F1/361 , G02F1/35
Abstract: Disclosed is a novel aromatic ester compound represented by the general formula in which Pn is a 1,4-phenylene group, R1 is an alkyl group having 1 to 4 carbon atoms, R2 is a group selected from the group consisting of perfluoroalkyl groups having 1 to 4 carbon atoms, cyano group, nitro group, 2,2-dicyanoethenyl group and methylsulfonyl group and the subscript n is a number of 2, 3 or 4. These aromatic ester compounds are useful as a second-order non-linear optical material in the ultraviolet wavelength range so that a resin film containing the compound has a good second-order non-linear optical coefficient d33 of 2-4x10-9 esu.
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公开(公告)号:DE60026679D1
公开(公告)日:2006-05-11
申请号:DE60026679
申请日:2000-12-21
Applicant: AGENCY IND SCIENCE TECHN
Inventor: FUKUDA TAKASHI , MATSUDA HIROO , SUMARU KIMIO , KIMURA TATSUMI , KATO MASAO
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公开(公告)号:FR2763022B1
公开(公告)日:2000-07-28
申请号:FR9805718
申请日:1998-05-06
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAMAOKI NOBUYUKI , PARFENOV ALEXANDER , MASAKI ATSUSHI , MATSUDA HIROO
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公开(公告)号:FR2763066A1
公开(公告)日:1998-11-13
申请号:FR9803379
申请日:1998-03-19
Applicant: AGENCY IND SCIENCE TECHN
Inventor: MATSUDA HIROO , FUKUDA TAKASHI , YAMADA SHINJI , KIMURA TATSUMI , KATO MASAO , BUAN XUAN MING , OKADA SHUJI , NAKANISHI HACHIRO
IPC: C07C69/92 , C07C205/43 , C07C255/55 , C08F2/00 , G02F1/361 , G02F1/35
Abstract: Disclosed is a novel aromatic ester compound represented by the general formula in which Pn is a 1,4-phenylene group, R1 is an alkyl group having 1 to 4 carbon atoms, R2 is a group selected from the group consisting of perfluoroalkyl groups having 1 to 4 carbon atoms, cyano group, nitro group, 2,2-dicyanoethenyl group and methylsulfonyl group and the subscript n is a number of 2, 3 or 4. These aromatic ester compounds are useful as a second-order non-linear optical material in the ultraviolet wavelength range so that a resin film containing the compound has a good second-order non-linear optical coefficient d33 of 2-4x10-9 esu.
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公开(公告)号:FR2763022A1
公开(公告)日:1998-11-13
申请号:FR9805718
申请日:1998-05-06
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAMAOKI NOBUYUKI , PARFENOV ALEXANDER , MASAKI ATSUSHI , MATSUDA HIROO
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公开(公告)号:JP2001051276A
公开(公告)日:2001-02-23
申请号:JP2000208722
申请日:2000-07-10
Applicant: AGENCY IND SCIENCE TECHN , FUKUDA TAKASHI , MATSUDA HIROO
Inventor: FUKUDA TAKASHI , MATSUDA HIROO , NISHIKADO TADAMORI , KATO MASAO
IPC: G02F1/1337 , C08F2/48 , C08F20/34 , G02F1/1333
Abstract: PROBLEM TO BE SOLVED: To form a polymerized film, which controls interaction between a substrate and a liquid crystal, on a cell substrate by incorporating a divinyl compound into the liquid crystal and photopolymerizing the divinyl compound on a cell substrate by being irradiated with light from a transparent substrate side. SOLUTION: A polymerized film is formed on a liquid crystal cell substrate in which a liquid crystal is encapsulated between two substrates at least one of which is a transparent substrate. For this purpose, a divinyl compound is incorporated into the liquid crystal and photopolymerized on the substrate by being irradiated with light from the side of the transparent substrate. The used divinyl compound has two vinyl groups in its molecule and is a low molecular weight compound having a molecular weight of 1,000 or lower, preferably 400 or lower. The lower limit of the molecular weight is normally about 250. The divinyl compound expressed by the formula is preferably used. In the formula, A denotes a linear molecule backbone part and R3-R8 each denotes hydrogen or a substituent. The linear molecule backbone part A includes a linear bivalent aliphatic group and the like.
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公开(公告)号:JP2000313172A
公开(公告)日:2000-11-14
申请号:JP4905199
申请日:1999-02-25
Applicant: AGENCY IND SCIENCE TECHN , RICOH KK
Inventor: SUGIMOTO HIROYUKI , FUTAMURA YOSHIROU , TSUTSUI KYOJI , TAMAOKI NOBUYUKI , MATSUDA HIROO
IPC: B41J2/32 , B41M5/28 , B41M5/337 , B41M5/36 , B41M5/46 , G02F1/133 , G02F1/1333 , G02F1/137 , B41M5/26
Abstract: PROBLEM TO BE SOLVED: To improve a contrast of a non-image portion by providing a reversible cholesteric reflection layer on a support base, providing a reversible heat color developing layer between the reflection layer and the base, and providing the reflection layer so as to be fixed at a specific temperature. SOLUTION: A reversible heat color developing layer 2 made of a composition containing an electron donative chromogenic compound and an electron acceptive compound is formed on a support 1, and a reversible cholesteric reflection layer (Ch reflection layer) 3 containing a cholesteric liquid crystal phase or a thermotropic liquid crytalline compound for forming an isotropic phase is formed on the layer 2. As needed, an intermediate layer 4 is formed between the layer 2 and the layer 3, a surface protective layer 5 is formed on the surface of the layer 3, and a substrate layer 6 or the like is provided between the support 1 and the layer 2. The layer 3 is provided so that a selectively reflecting state of the cholesteric liquid crystal phase displayed when the layer 3 is heated to a glass transition temperature or above can be fixed to the transition temperature or below.
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公开(公告)号:JP2000247039A
公开(公告)日:2000-09-12
申请号:JP4905399
申请日:1999-02-25
Applicant: AGENCY IND SCIENCE TECHN , TAMAOKI NOBUYUKI , MATSUDA HIROO , RICOH KK , OKAMURA OIL MILL
Inventor: SUGIMOTO HIROYUKI , FUTAMURA YOSHIROU , TAMAOKI NOBUYUKI , MATSUDA HIROO , KIDA YOSHIE
Abstract: PROBLEM TO BE SOLVED: To provide a method and an apparatus for recording a multicolor image of two or more colors including a color having a short wavelength even without realizing a large cooling speed by using a cholesteric liquid crystal compound. SOLUTION: A heat-sensitive recording layer containing a thermotropic liquid crystal compound for forming a cholesteric liquid crystal compound is provided between two transparent substrates. In this case, after the recording layer is heated to a temperature exhibiting an isotropic phase or the cholesteric liquid crystal, the layer is cooled at a specific cooling speed. Thus, a cholesteric glass phase is formed. An area of the heat-sensitive recording layer of a recording material exhibiting a selected reflecting color caused by a spiral molecular arrangement is heated and cooled and an image of a first selected reflecting color is recorded, and a pressing force is applied to the area of the image of the first selected reflecting color, thereby color changing to a second selected reflecting color.
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公开(公告)号:JPH11322685A
公开(公告)日:1999-11-24
申请号:JP14214298
申请日:1998-05-08
Applicant: AGENCY IND SCIENCE TECHN , MATSUDA HIROO , FUKUDA TAKASHI
Inventor: MATSUDA HIROO , FUKUDA TAKASHI , KIMURA TATSUMI , KATO MASAO , OKADA SHUJI , NAKANISHI HACHIRO
IPC: G02F1/35 , C07C227/18 , C07C229/60 , C07C253/30 , C07C255/55 , C07C323/62 , G02F1/355 , G02F1/361
Abstract: PROBLEM TO BE SOLVED: To obtain a novel compound that has a good level of optical transparency and the secondary nonlinear optical property and is useful as an organic secondary nonlinear optical material. SOLUTION: This novel compound is represented by formula I (X is a dialkylamino, an alkylthio; Y is nitro or cyano; n is 1-3), typically the compound of formula II. The compound of formula I is prepared by reaction of an aromatic carboxylic halide of formula III (Hal is a halogen), for example, 4- dimethylaminobenzoyl chloride, with a p-substituted phenol, for example, 4- cyanophenol or the like in the presence of a hydrogen halide acceptor in an inert solvent such as acetone and the like.
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