New cycloalkene-di:one cpds. including bis:cpds. - useful as photoinitiator for polymerisation with visible light

    公开(公告)号:DE3927480A1

    公开(公告)日:1991-02-21

    申请号:DE3927480

    申请日:1989-08-19

    Applicant: BASF AG

    Abstract: New carbocyclicc keto cpds. are 4-substd.-3-cyclopenten-, -3-cyclohexen- and -3-cyclohepten-1,2-dione cpds. and analogous bis cpds. of formula (I). X = =N-, =CH- or =CH-CH=N-; R1 = H or 1-6 C alkyl; A = an alkylene completing a 5-, 6- or 7-membered ring, opt. with 1 or 2 Me substits.; n = 1 or 2; if n = 1, B = phenyl (opt. substd. by amino, di-1-4 C-alkylamino, 1-4 Calkyl, 1-4 C alkoxy or NO2, N-phenylamino, -NH-CO-NH2, 1-4C alkylamino (in which the alkyl gp. is opt. substd. by phenyl and/or OH or COOH) and, if X = =N-, B may also = OH; if n = 2, B = phenylene with up to three 1-4 C alkoxy substits. Pref. n = 1, X = =N-, B = OH, -NH-phenyl (opt. with 1 or 2 NO2 substits.), -NH-CO-NH2 or phenyl (opt. with 1 or 2 NH2, N,N-di-1-4 C alkylamino, 1-4 C alkyl or 1-4 C alkoxy substits.); or n = 1, X = =CH- and B = Ph; or n = 2, X = =N- and B = 1,3- or 1,4-phenylene, opt. substd. by 1-4C alkoxy; A = -CMe2- or -CMe2-CH2-. (I) are prepd. by condensing the corresp. 3,4-dioxo-cycloalkenal or beta-(3,4-dioxocycloalkenyl)-acrolein with NH2OH, hydrazine or amines, pref. in solvents and opt. in the presence of catalysts. U - () Cn uSd as Snsilisrs fgr inititin photopolymerisation with visible light.

    60.
    发明专利
    未知

    公开(公告)号:DE58908863D1

    公开(公告)日:1995-02-23

    申请号:DE58908863

    申请日:1989-03-22

    Applicant: BASF AG

    Abstract: Silicon naphthalocyanines of the formula … … in which… Nc denotes the radical of a naphthalocyanine system which is optionally substitued by C1-C10-alkyl or C1-C10-alkoxy, and… R and R independently of one another denote a radical of the formula … … in which R stands for branched C6-C20-alkyl of the formula … … in which n has the meaning 1 to 5 and R and R independently of one another have the meaning C1-C16-alkyl, and R and R independently of one another stand for C1-C10-alkyl or the radical OR , in which R has the abovementioned meaning, or the radical R also denotes C1-C10-alkyl, and thin radiation-sensitive coating films containing these silicon naphthalocyanines.

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