公开(公告)号：DE2259681A1

公开(公告)日：1974-06-12

申请号：DE2259681

申请日：1972-12-06

Applicant: BASF AG

Inventor： SCHAFFNER ERNST DIPL CHEM DR ,  EILINGSFELD HEINZ DIPL CHEM DR ,  PATSCH MANFRED DIPL CHEM DR ,  EISFELD WOLFGANG DIPL CHEM DR

IPC: C07C51/31 ,  C07C65/20

Abstract: Halogen-substd. o-benzoylbenzoic acid of formula (I) are prepd. by oxidising haloindanes of formula (II) (where X and Y are halogen of H, but not both H, R1-3 are each alkyl and R1 and R3 are also be H), with O2 in liq. phase in presence of heavy metal salts and of a cpd. yielding a Br ion, as described in Parent patent, in which o-benzoylbenzoic acids are prepd. by oxidn. of indanes.

公开(公告)号：DE2257674A1

公开(公告)日：1974-05-30

申请号：DE2257674

申请日：1972-11-24

Applicant: BASF AG

Inventor： EILINGSFELD HEINZ DIPL CHEM DR ,  BANTEL KARLHEINZ DIPL CHEM DR

IPC: C07C79/36

Abstract: Prepn. of aromatic ketones is by acylation of suitable aromatic cpds. with acid chlorides or anhydrides opt. under pressure, using as catalyst a mono- or bi-cyclic aromatic sulphonic acid carrying is not 2 NO2 pgs. and cpds. of formula (I): R1-C(O)-R2 (where R1 is aryl or aliphatic and R2 is aromatic or heterocyclic carrying 2-4 gps. 1, 2 or 3 of which are NO2. Nitrobenzophenones are inters for plasticisers and dyes.