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公开(公告)号:DE3063378D1
公开(公告)日:1983-07-07
申请号:DE3063378
申请日:1980-12-09
Applicant: BASF AG
Inventor: BRUDER HORST DR , DEGEN HANS-JUERGEN DR , FEICHTMAYR FRANZ DR , GRYCHTOL KLAUS DR , MAYER UDO DR
Abstract: Compounds of the general formula I where the radicals A, A1 and B are identical or different and A is unsubstituted or substituted benzene or heteroaromatic, A1, if n=1, is unsubstituted or substituted heteroaromatic or is aryl which is unsubstituted or substituted by alkyl, aryl, cycloalkyl, chlorine, bromine, hydroxyl, alkoxy, aryloxy, nitro, hydroxycarbonyl, alkoxycarbonyl, or aminocarbonyl, and, if n>1, A1 may also be aryl substituted by unsubstituted or substituted amino, B is a bridge member of the formula B1 is a bridge member which may or may not be quaternized, R1 and R2 are hydrogen, unsubstituted or substituted alkyl, cycloalkyl, aryl, alkoxy or amino, n is an integer equal to or greater than 1 and X theta is an anion. The compounds according to the invention are preferably used for coloring paper pulp.
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52.
公开(公告)号:DE2138931A1
公开(公告)日:1973-02-15
申请号:DE2138931
申请日:1971-08-04
Applicant: BASF AG
Inventor: KAST HELLMUT DR , BAUMANN HANS DR , MAYER UDO DR , OBERLINNER ANDREAS DR
Abstract: Basic dyes of formula (I): (where R is H, 1-4C alkyl, 2-3C hydroxyalkyl, cyanethyl, 2-5C carbalkoxyalkyl, methoxyethyl, ethoxyethyl, 4-11C alkanoyloxyalkyl, benzyl, phenylethyl, phenyl opt. substd. by methyl, methoxy or ethoxy, or the gp. R1 is 1-4C alkyl, 2-3C hydroxyalkyl, cyanethyl, methoxyethyl, ethoxyethyl or phenyl, R2 is as R; R3 is as R1; X, Y are each H, Cl, methyl, methoxy or ethoxy; A is phenyl opt. mono- or disubstd. by Cl, OH, methyl, methoxy, ethoxy or sulphonic acid gp. or a gp. of formulae: in which R4 is H, Cl, methyl, methoxy or ethoxy; R5 is H or Cl; X- is an anion) are obtained by dehydrogenating cpds. of formula (II): with benzoquinones substd. by F, Cl, Br or Cn or nitro-substd. phenanthrene -quinones in the presence of O2 and catalysts contg. complex heavy metals (where A' is as A or a gp. of formula.
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公开(公告)号:DE59407376D1
公开(公告)日:1999-01-14
申请号:DE59407376
申请日:1994-09-03
Applicant: BASF AG
Inventor: HENGELSBERG HEIDI DR , RUSKE MANFRED , MAYER UDO DR
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公开(公告)号:DE59308137D1
公开(公告)日:1998-03-19
申请号:DE59308137
申请日:1993-11-25
Applicant: BASF AG
Inventor: MAYER UDO DR , DEGEN HANS-JUERGEN DR
Abstract: Azo dyes of the formula in which a) m is 1, n is 0, Y is hydroxyl and L is C1-C6-alkylene, or in which b) m is 0 or 1, n is 1, X is hydrogen, Y is amino and L is piperazine-1,4-diyl if m is 0 or is C2-C6-alkylene or phenylene if m is 1, their use for the dyeing or printing of paper pulps, and dye mixtures containing the new dyes.
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公开(公告)号:DE59306076D1
公开(公告)日:1997-05-15
申请号:DE59306076
申请日:1993-01-14
Applicant: BASF AG
Inventor: HAHN ERWIN DR , HENGELSBERG HEIDI DR , MAYER UDO DR
Abstract: Basic azo dyes useful for dyeing or printing polymeric material have the formula (* CHEMICAL STRUCTURE *) where R1 is hydrogen, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-alkanoylamino, R2 is hydrogen, C1-C4-alkyl, C1-C4-alkoxy or a radical of the formula CO-X, and X is hydroxyl, C1-C4-alkoxy, amino, mono- or di(C1-C6-alkyl)amino or a radical of the formula (* CHEMICAL STRUCTURE *) (* CHEMICAL STRUCTURE *) (* CHEMICAL STRUCTURE *) where n is 0 or 1, R3, R4 and R5 are hydrogen or substituted or unsubstituted C1-C4-alkyl, R6 is hydrogen or C1-C4-alkyl, L is C2-C6-alkylene, and An(negative earth) is one equivalent of an anion, with the proviso that at least one basic or quaternary radical is present in the molecule.
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公开(公告)号:AT124979T
公开(公告)日:1995-07-15
申请号:AT91117713
申请日:1991-10-17
Applicant: BASF AG
Inventor: RUSKE MANFRED , MAYER UDO DR
IPC: C09B44/16 , C07D401/04 , C07D401/14 , C07D521/00 , C09B44/10 , D06P1/08 , D21H21/28
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公开(公告)号:DE4232524A1
公开(公告)日:1994-03-31
申请号:DE4232524
申请日:1992-09-29
Applicant: BASF AG
Inventor: SCHROEDER GUNTER-RUDOLF DR , MAYER UDO DR
IPC: C07D471/04 , C07D487/04 , G03G9/08 , G03G9/097
Abstract: Benzimidazoles of the formula in which n and q are 1 or 2, R is hydrogen, chlorine or methyl, R is hydrogen, optionally substituted C1-C4-alkyl, halogen, nitro or C1-C4-alkanoyl, L is C2-C6-alkylene and An is the equivalent of an anion, electrostatic toners containing the benzimidazoles as charge stabilisers, and the use of the benzimidazoles at charge stabilisers.
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公开(公告)号:DE58906464D1
公开(公告)日:1994-02-03
申请号:DE58906464
申请日:1989-01-03
Applicant: BASF AG
Inventor: KRANZ JOACHIM DR , LANDMANN BERND DR , MAYER UDO DR
IPC: C07C229/34 , C07C229/52 , C07D209/46 , C07D295/155
Abstract: Novel isoindolenines of the general formula (I) … … in which… R stands for hydrogen, for C1-C12-alkyl which is optionally substituted by chlorine, hydroxyl, phenyl or cyano, for C5-C8 cycloalkyl or for phenyl which is optionally substituted by chlorine or methyl,… R stands for hydrogen, C1-C6-alkyl which is optionally substituted by chlorine, hydroxyl, phenyl or cyano, or … … or for a morpholino, pyrrolidino or piperidino radical and… R stands for hydrogen or methyl and the benzene ring A is optionally substituted by 1 to 4 chlorine, 1 or 2 C1-C4-alkyl or a nitro group,… are obtained by condensation of 3-aminophenols of the formula (II) … … with 3-amino-1-oxoisoindolenines of the general formula (III) … … in the presence of acids. … The isoindolenine compounds (I) can be hydrolysed to benzoylbenzoic acids (IV) … … in very good yield. … In this way, benzoylbenzoic acids are readily accessible which are only accessible with difficulty or are virtually inaccessible according to the processes of the prior art.
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公开(公告)号:DE59003404D1
公开(公告)日:1993-12-16
申请号:DE59003404
申请日:1990-05-19
Applicant: BASF AG
Inventor: HAHN ERWIN DR , BREITSCHAFT WALTER DR , MAYER UDO DR , SCHROEDER GUNTER-RUDOLF DR
IPC: C07D295/18 , C07D295/185 , C09B11/00 , C09B11/10 , C09B11/12 , C09B11/16 , C09B11/18 , D06P1/42 , D21H21/28
Abstract: Triphenylmethane dyes of the formula +TR where each R1 is independently of the others hydrogen or substituted or unsubstituted C1-C6-alkyl, or two R1 radicals together with the nitrogen atom joining them form a heterocyclic radical, R2 and R5 is independently of the others hydrogen or C1-C4-alkyl, R3 and R4 is independently of the others hydrogen, C1-C4-alkyl, C1-C4-alkoxy or halogen, An(-) is one equivalent of an anion, and n is 1 or 2, preparable from piperazine derivatives as intermediates, are useful for coloring paper.
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公开(公告)号:DE4215391A1
公开(公告)日:1993-11-18
申请号:DE4215391
申请日:1992-05-11
Applicant: BASF AG
Inventor: HAHN ERWIN DR , KRAEH CLAUDIA DR , MAYER UDO DR
Abstract: New rhodamine dyestuffs are 2,2,4,8,10,10-hexamethyl-6-(2-carboxy phenyl)-1,2,3,4,8,9,10,11-octahydro- dipyrido(3,2-a:3,2-g) xanthylium salts of formula (I). R1, R2 are H or (substd.) 1-4C alkyl; and An(-) is the equiv. of an anion. (I) may be prepd. by the prior art in e.g. J. Org. Chem., vol. 30, pp. 1832-1837, 1965; SU A-548603; and US Application 566924 (29.12.83); examples are given (below). Specifically, R1 is 1-4C alkyl or esp. H; and R2 is H or esp. 1-4C alkyl. (I) may be prepd. by reacting an opt. N-substd. 3-ethoxy aniline with acetone, giving a 7-ethoxy-2,2,4- trimethyl- dihydroquinoline, hydrogenation and treatment with HBr in glacial acetic acid and reaction of the resultant 2,2,4-trimethyl-7-hydroxy- tetrahydroquinoline with e.g. phthalic anhydride. USE/ADVANTAGE - (I) are used for dyeing polyacrylonitrile fibres, for pigmenting polymers or in ink prodn. (claimed). They may also be used as laser dyestuffs or in electrophotographic toner mfr. and have improved properties, esp. high light fastness.
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