公开(公告)号：JP2008177046A

公开(公告)日：2008-07-31

申请号：JP2007009440

申请日：2007-01-18

Applicant: Bridgestone Corp ,  株式会社ブリヂストン

Inventor： TOYOSAWA SHINICHI ,  SUGIYAMA HIDEO

IPC: H01M4/88 ,  H01M4/92 ,  H01M4/96 ,  H01M8/10

CPC classification number: Y02P70/56

Abstract: PROBLEM TO BE SOLVED: To provide a manufacturing method of an electrode for a solid polymer fuel cell capable of reducing carrying amount of a metal catalyst and capable of suppressing voltage drop in a large current region. SOLUTION: This is the manufacturing method of an electrode for solid polymer fuel cell equipped with a conductive porous substrate, carbon fiber arranged on the conductive porous substrate, and a metal catalyst carried on the carbon fiber, and comprises (i) a process to apply a water repellency treatment on one of the surfaces of the conductive porous substrate, (ii) a process to produce a fibril-like polymer by electrolytic oxidation polymerization of a compound having an aromatic ring on the other surface of the conductive porous substrate, (iii) a process to produce carbon fiber on the conductive porous substrate by calcining the fibril-like polymer, and (iv) a process to have the metal catalyst carried on the carbon fiber. COPYRIGHT: (C)2008,JPO&INPIT

公开(公告)号：JP2008106384A

公开(公告)日：2008-05-08

申请号：JP2006288545

申请日：2006-10-24

Applicant: Bridgestone Corp ,  株式会社ブリヂストン

Inventor： FUKUSHIMA ATSUSHI ,  TOYOSAWA SHINICHI ,  SUGIYAMA HIDEO ,  SUGI SHINICHIRO

IPC: D01F9/24 ,  C01B31/02

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing carbon fiber that is small in fiber diameter, large in surface area, and used for a catalyst layer of a solid polymer-type fuel cell, enhances the performance of the solid polymer-type fuel cell through improving the efficiency of carrying the catalyst.
SOLUTION: The method includes the step A of forming a fibrillar polymer by electrolytic polymerization of an aromatic ring-containing compound and a step B of forming the objective carbon fiber by baking the fibrillar polymer. In this method, in the step A, pulsed electric current is applied wherein the maximum level of the electric current is positive, while the minimum level is negative.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 待解决的问题：为了提供一种生产纤维直径小，表面积大，用于固体聚合物型燃料电池的催化剂层的碳纤维的方法，提高了固体聚合物的性能 型燃料电池，通过提高载体催化剂的效率。 解决方案：该方法包括通过含芳环化合物的电解聚合形成原纤维聚合物的步骤A和通过烘焙原纤维聚合物形成目标碳纤维的步骤B. 在该方法中，在步骤A中，施加脉冲电流，其中电流的最大电平为正，而最小电平为负。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2008081854A

公开(公告)日：2008-04-10

申请号：JP2006260291

申请日：2006-09-26

Applicant: Bridgestone Corp ,  株式会社ブリヂストン

Inventor： SUGI SHINICHIRO ,  TOYOSAWA SHINICHI

IPC: D01F9/24 ,  C01B31/02

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a fibrous carbon, which does not require a spinning process and an infusibilization process and giving a fibrous carbon having excellent electrical conductivity, and especially a diameter of several ten to several hundred nanometers and suitable as an electrode material of a solid-polymer fuel cell and a filler for various resin products.
SOLUTION: The method for producing a fibrous carbon includes a step (A) to form a fibrous polymer structure by the electrolytic polymerization of a compound having an aromatic ring on a conductive substrate and a step (B1) to form a fibrous carbon structure by firing the fibrous polymer structure and recover the fibrous carbon by separating the produced fibrous carbon structure from the conductive substrate or a step (B2) to recover the fibrous polymer by separating the fibrous polymer structure from the conductive substrate and obtain the fibrous carbon by firing the fibrous polymer.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 待解决的问题：提供一种不需要纺丝工艺和不熔化工艺并产生具有优异导电性的纤维状碳，特别是几十​​至几百纳米直径的纤维状碳的生产方法 并且适合作为固体聚合物燃料电池的电极材料和用于各种树脂产品的填料。 解决方案：纤维状碳的制造方法包括通过在导电性基材上进行具有芳香环的化合物的电解聚合而形成纤维状聚合物结构的工序（A）和工序（B1），形成纤维状碳 通过烧结纤维聚合物结构并通过从导电性基材分离生产的纤维状碳结构和工序（B2）回收纤维状碳，回收纤维状聚合物的结构，通过将纤维状聚合物结构与导电性基材分离而回收纤维状聚合物，并通过 焙烧纤维聚合物。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007227084A

公开(公告)日：2007-09-06

申请号：JP2006045326

申请日：2006-02-22

Applicant: Bridgestone Corp ,  株式会社ブリヂストン

Inventor： TOYOSAWA SHINICHI ,  SUGIYAMA HIDEO ,  SUGI SHINICHIRO ,  SUZUKI KINYA

IPC: H01M8/04 ,  H01M4/88 ,  H01M4/92 ,  H01M8/10

CPC classification number: Y02E60/521

Abstract: PROBLEM TO BE SOLVED: To provide an operating method of a solid polymer fuel cell capable of shortening the preliminary operating period. SOLUTION: This is the operating method of the solid polymer fuel cell, having a solid polymer electrolyte membrane 3, an anode catalyst layer 5A arranged on one side of the solid polymer electrolyte membrane 3, and a cathode catalyst layer 5B arranged on another side of the solid polymer electrolyte membrane 3. As a preliminary operation, power generation is carried out, by supplying oxidant gas to the anode catalyst layer 5A and supplying hydrogen gas to the cathode catalyst layer, and then, in the normal operation, power generation is carried out, by supplying fuel gas or liquid to the anode catalyst layer 5A and supplying oxidizer gas to the cathode catalyst layer 5B. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供能够缩短预备操作时间的固体聚合物燃料电池的操作方法。 解决方案：这是固体聚合物燃料电池的操作方法，其具有固体聚合物电解质膜3，布置在固体聚合物电解质膜3一侧的阳极催化剂层5A和布置在固体聚合物电解质膜3的一侧上的阴极催化剂层5B 固体高分子电解质膜3的另一侧。作为初步操作，通过向阳极催化剂层5A供给氧化剂气体并向阴极催化剂层供给氢气，然后在正常运行中进行发电， 通过向阳极催化剂层5A供给燃料气体或者向阴极催化剂层5B供给氧化剂气体来进行发电。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2007227083A

公开(公告)日：2007-09-06

申请号：JP2006045324

申请日：2006-02-22

Applicant: Bridgestone Corp ,  株式会社ブリヂストン

Inventor： TOYOSAWA SHINICHI ,  SUGIYAMA HIDEO ,  SUGI SHINICHIRO ,  SUZUKI KINYA

IPC: H01M4/88 ,  H01M4/96 ,  H01M8/10

CPC classification number: Y02P70/56

Abstract: PROBLEM TO BE SOLVED: To provide an electrode for a solid polymer fuel cell capable of shortening a preliminary operating period, and to provide its manufacturing method. SOLUTION: This is a manufacturing method of an electrode for solid polymer fuel cell, having a catalyst carrier and a metal catalyst carried on the catalyst carrier, and includes a process in which the metal catalyst is carried on the catalyst carrier and a process, in which the catalyst carrier carrying the metal catalyst is applied an oxidation reduction treatment electrochemically in an acid water solution. The electrode for the solid polymer fuel cell manufactured by this method is also provided. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供一种能够缩短预备操作时间的固体高分子型燃料电池用电极，提供其制造方法。 解决方案：这是一种用于固体高分子型燃料电池的电极的制造方法，其具有载体和催化剂载体上的催化剂载体和金属催化剂，并且包括其中金属催化剂载于催化剂载体上的方法和 其中携带金属催化剂的催化剂载体在酸性水溶液中电化学地进行氧化还原处理。 还提供了通过该方法制造的固体高分子型燃料电池用电极。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2007173207A

公开(公告)日：2007-07-05

申请号：JP2006235923

申请日：2006-08-31

Applicant: Bridgestone Corp ,  株式会社ブリヂストン

Inventor： TOYOSAWA SHINICHI ,  SUGIYAMA HIDEO ,  SUZUKI KINYA

IPC: H01M4/88 ,  H01M4/86 ,  H01M8/10

CPC classification number: Y02P70/56

Abstract: PROBLEM TO BE SOLVED: To provide a manufacturing method of an electrode for a solid polymer fuel cell capable of sharply improving power generation efficiency of the solid polymer fuel cell. SOLUTION: The electrode for the solid polymer fuel cell is manufactured by generating fibrous polymer on a porous supporting body by oxidizing and polymerizing a compound having aromatic ring on the porous supporting body, generating carbon fiber on the porous supporting body by baking the fibrous polymer, and by making the carbon fiber carry metal by applying electric plating on the carbon fiber. On the electric plating, current is impressed in pulse-form, and duty ratio expressed by formula (1): duty ratio=t 1 /(t 1 +t 2 )×100 [in formula, t 1 denotes current impressing period (second), and t 2 denotes suspension period] is turned into 2 to 20%. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 解决问题的方案：提供一种固体高分子型燃料电池用电极的制造方法，能够大幅提高固体高分子型燃料电池的发电效率。 解决方案：固体高分子型燃料电池用电极通过在多孔性支持体上氧化并聚合具有芳香环的化合物，通过在多孔性支持体上产生纤维状聚合物而制造， 纤维聚合物，并且通过在碳纤维上施加电镀使碳纤维携带金属。 在电镀中，以脉冲形式施加电流，并且由公式（1）表示的占空比：占空比= t 1 /（t 1 + t 2 ）×100 [式中，t 1 表示电流施加期间（秒），t 2 表示悬浮期]变为2〜20 ％。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2007153717A

公开(公告)日：2007-06-21

申请号：JP2005354951

申请日：2005-12-08

Applicant: Bridgestone Corp ,  株式会社ブリヂストン

Inventor： TOYOSAWA SHINICHI

IPC: C01B31/02

Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a carbon material capable of controlling pore characteristics and a carbon material manufactured by such method.
SOLUTION: The method for manufacturing the carbon material including (i) a process of subjecting a compound having an aromatic ring in the presence of anion to oxidation polymerization or preferably electrolytic oxidation polymerization to generate a polymer, (ii) a process of removing the anion from the obtained polymer, and (iii) a process of firing the polymer from which the anion is removed, more preferably firing the polymer in a non-oxidizing atmosphere to generate the carbon material, and the carbon material manufactured by such method are provided.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供一种能够控制孔特性的碳材料的制造方法和通过这种方法制造的碳材料。 解决方案：制造碳材料的方法包括（i）在阴离子存在下使具有芳环的化合物进行氧化聚合或优选电解氧化聚合以产生聚合物的方法，（ii） 从所获得的聚合物中除去阴离子，和（iii）焙烧除去阴离子的聚合物的方法，更优选在非氧化气氛中焙烧聚合物以产生碳材料，并且通过这种方法制造的碳材料 被提供。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2003113318A

公开(公告)日：2003-04-18

申请号：JP2001309796

申请日：2001-10-05

Applicant: BRIDGESTONE CORP

Inventor： NISHIMURO YOICHI ,  MACHIDA KUNIO ,  TOYOSAWA SHINICHI

IPC: C08J5/18 ,  C08K3/00 ,  C08K7/02 ,  C08L23/10 ,  C08L53/02 ,  C08L71/12 ,  C08L91/00 ,  C08L101/00 ,  H01L23/373

Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic elastomer composition which can give heat-radiating sheets maintaining heat-radiating properties and flame retardancy and simultaneously having sufficient strengths, and to provide the heat-radiating sheet comprising the composition. SOLUTION: This thermoplastic elastomer composition comprising a thermoplastic elastomer, a heat-conductive filler and a flame retardant is characterized by containing a flame-retardant whisker as at least one part of the flame retardant. And the heat-radiating sheet comprises the composition.

公开(公告)号：JP2001208205A

公开(公告)日：2001-08-03

申请号：JP2000036164

申请日：2000-02-15

Applicant: BRIDGESTONE CORP

Inventor： NISHIMURO YOICHI ,  TOYOSAWA SHINICHI ,  MACHIDA KUNIO

IPC: B65D53/06 ,  F16J15/10

Abstract: PROBLEM TO BE SOLVED: To provide a gasket for preventing the generation of gas which contaminates a magnetic disk or the like in use of electronic equipment without installing a mechanism for degasing in an electronic equipment body. SOLUTION: In the gasket fixed to a cover or a frame and integrated with the cover or the frame, after the gasket is molded in the specified shape, gas contained in the gasket is removed.

公开(公告)号：JP2001192527A

公开(公告)日：2001-07-17

申请号：JP2000005473

申请日：2000-01-14

Applicant: BRIDGESTONE CORP

Inventor： TOYOSAWA SHINICHI ,  NISHIMURO YOICHI ,  MASHITA NARUHIKO ,  MACHIDA KUNIO

IPC: C08L53/00 ,  C08K5/01 ,  C08L23/26 ,  C08L51/06

Abstract: PROBLEM TO BE SOLVED: To provide a resin composition which can be directly bonded to a metal by injection molding without using an adhesive and has a good adhesiveness. SOLUTION: This composition comprises (a) 100 pts.wt. thermoplastic styrene elastomer comprising a block copolymer, (b) 1-15 pts.wt. maleic anhydride- grafted polyolefin, and 30-170 pts.wt. paraffin oil.