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    58.
    发明专利
    未知

    公开(公告)号：BR9602539A

    公开(公告)日：1998-10-27

    申请号：BR9602539

    申请日：1996-05-30

    Applicant: HOECHST AG

    Inventor： SCHLOGL GUNTER ,  WINTER ANDREAS ,  DRIES THOMAS ,  PEIFFER HERBERT ,  BUSCH DETLEF

    IPC: B29C47/06 ,  B29C55/12 ,  B29K23/00 ,  B29L7/00 ,  B32B27/18 ,  B32B27/32 ,  C08F8/00 ,  C08F10/06 ,  C08J5/18 ,  C08L23/10

    Abstract: Biaxially oriented polypropylene (BOPP) film with at least one base layer (A) contg. polypropylene (PP) is claimed, in which (a) the isotactic block length between two structural defects is more than 40 (statistical average), (b) the n-heptane-insol. component of the PP has an isotacticity (by C-NMR spectrometry) of at least 95%, (c) the mol. wt. ratio Mw/Mn is less than 4, (d) the PP contains less than 1% n-heptane-soluble component, and (e) the base layer has elastic moduli of more than 2400 and more than 4800 N/mm in the machine (longitudinal) and transverse directions respectively. Also claimed is a process for the prodn. of this BOPP film, by heating, compressing and melting the polymers for the different layers in extruders, combining the different melts, extruding through a sheet die, cooling and compacting the film on a take-off roll, and orienting the film by stretching in the machine direction by a factor of (3:1)-(9:1) and in the transverse direction by a factor of (4:1)- (12:1).

    59.
    发明专利
    未知

    公开(公告)号：BR9602577A

    公开(公告)日：1998-10-06

    申请号：BR9602577

    申请日：1996-05-31

    Applicant: HOECHST AG

    Inventor： PEIFFER HERBERT ,  WINTER ANDREAS ,  SCHLOEGL GUNTER ,  DRIES THOMAS ,  BUSCH DETLEF

    IPC: B29C47/06 ,  B29C55/12 ,  B29K23/00 ,  B29L7/00 ,  B29L9/00 ,  B32B27/18 ,  B32B27/32 ,  C08F8/00 ,  C08F10/06 ,  C08J5/18 ,  C08L23/10

    Abstract: Biaxially oriented polypropylene film with at least one base layer contg. polypropylene has (a) isotactic block length between two structural defects of more than 40 (statistical average), (b) n-heptane-insol. component of the polypropylene with an isotacticity (by C-NMR spectrometry) of at least 95%, (c) mol. wt. ratio Mw/Mn of less than 4 and (d) polypropylene contg. less than 1% n-heptane-soluble component. Also claimed is a process for the prodn. of this film. Pref. the base layer (A) has elastic moduli of more than 2400 and more than 3800 N/mm in the machine direction and transverse direction respectively. (A) contains polypropylene in which the heptane-insol. component has an isotacticity of at least 96%, pref. at least 97%, and a Mw/Mn ratio of less than 3.0, pref. less than 2.7. The film may have outer layer(s) (B) of olefinic polymer on one or pref. both sides and interlayer(s) (C) of olefinic polymer between base and outer layers. Layer (A) contains an antistatic agent, (B) contain(s) lubricants and/or antiblocking agents, and (A), (B) and/or (C) contain neutralising agents and/or stabilisers; interlayer(s) (C) may contain neutralising agents, stabilisers, antistatics and/or antiblocking agents. Layers (B) may or may not be sealable. The total film thickness is 4-100 microns, with the base layer (A) making up 40-60% of this. Alternatively, the film may consist of a single layer.

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