公开(公告)号：JP2002179756A

公开(公告)日：2002-06-26

申请号：JP2000378779

申请日：2000-12-13

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C08G18/18 ,  C08G18/00 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a low density polyurethane foam of 20 kg/m3 or lower density, having good adhesion with an adherend without shrinking of the foam or formation of voids inside for a formulation using abundant water as a foaming agent, capable of producing the polyurethane foam in good conditions of working environment reducing bad smell due to a catalyst for producing polyurethane. SOLUTION: This method for producing a polyurethane foam having 20 kg/m3 or lower density comprises reacting a polyol component with an isocyanate component in the presence of a catalyst for producing polyurethane, a foaming agent and a foam stabilizer, wherein the catalyst comprises a tertiary amine expressed by the formula (I) (where n is an integer of 2 to 4) and an imidazole compound expressed by the formula (II) (where R1 represents a C1-6 linear or branched alkyl group or a C1-6 linear or branched hydroxyalkyl group; and R2 represents a hydrogen atom, a C1-6 linear or branched alkyl group or a C1-6 linear or branched hydroxyalkyl group).

公开(公告)号：JP2001247643A

公开(公告)日：2001-09-11

申请号：JP2000062614

申请日：2000-03-07

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C08G18/20 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an odorless polyurethane foam which keeps the inherent properties of an N-substituted imidazole and is reduced in an offensive odor based on the N-substituted imidabzoles, allowing a good producing environment. SOLUTION: The method for producing an odorless polyurethane foam comprises a reaction of the polyol component with the isocyanate component in the presence of a low-odored catalyst and a foaming agent, wherein said catalyst comprises an imidazole compound represented by the formula (I) (Wherein R1 is a 1-4C alkyl group, R2 is hydrogen or methyl, and n is 1 or 2).

公开(公告)号：JP2001172351A

公开(公告)日：2001-06-26

申请号：JP35982099

申请日：1999-12-17

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C09K3/10 ,  C08G18/18 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To produce a catalyst for producing a polyurethane of a low odor, and to provide a process for producing a polyurethane excellent in vinyl stain resistance, fogging resistance and heat resistance by using the catalyst for producing the polyurethane. SOLUTION: There are provided a catalyst for producing a polyurethane comprising a dialkylaminoalkyl alcohol represented by formula (I): R1R2N-(CH2)n- OH (I) (wherein R1 and R2 are each independently a 1-4C alkyl group; and (n) is an integer of 9-12), and a process for producing a polyurethane comprising reacting a polyol component with an isocyanate component in the presence of the catalyst for producing a polyurethane.

公开(公告)号：JP2001048947A

公开(公告)日：2001-02-20

申请号：JP22568599

申请日：1999-08-09

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C08G18/18 ,  C08G18/00 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing the subject thermal insulation material, favorable in foam fluidity during molding process, excellent in demoldability after the molding process, and capable of giving the polyurethane foam with high compressive strength and thermal conductivity retention. SOLUTION: This method for producing the objective polyurethane foam as thermal insulation material comprises reaction between a polyol component and an isocyanate component in the presence of (A) a catalyst comprising a quaternary ammonium salt and at least one compound selected from N,N,N',N'- tetramethyl-1,6-hexanediamine, N,N-dimethylcyclohexylamine and N-(2- dimethylaminoethyl)-N'-methylpiperazine, (B) a foaming agent composed of water and cyclopentane and (C) a foam stabilizer.

公开(公告)号：JPH06338044A

公开(公告)日：1994-12-06

申请号：JP12584693

申请日：1993-05-27

Applicant: KAO CORP

Inventor： KOBAYASHI ISAO ,  ISHIKAWA ATSUSHI

IPC: G11B5/64 ,  G11B5/73 ,  G11B5/738 ,  G11B5/704

Abstract: PURPOSE:To provide a recording medium having high durability by interposing a required gas barrier film between a carbon substrate and a recording layer. CONSTITUTION:A recording medium is composed of a carbon substrate made of vitreous carbon and a recording layer, and a gas barrier film of SiO2, SiO, Si3N4, ZrO2, ITO, Ta2O5, a composite material of them, etc., is interposed between the carbon substrate and the recording layer. Even when the carbon substrate is set in an atmosphere at a high temp. in order to form a magnetic film on the substrate, gaseous impurities generated from the carbon substrate owing to unsatisfactory carbonization do not diffuse into the magnetic film by the presence of the gas barrier film and the objective recording medium having high durability is obtd.

公开(公告)号：JPH04181528A

公开(公告)日：1992-06-29

申请号：JP31041890

申请日：1990-11-16

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  KAMIYAMA KENICHI

IPC: G11B7/24

Abstract: PURPOSE:To achieve higher quality by building an electroconductive layer based on a pi conjugate structure on the surface of an organic protective film. CONSTITUTION:An ultraviolet hardening type hard coating agent is applied on a polycarbonate substrate 2 at a thickness of 1-20 mum by a spin coat method and hardened by irradiation with ultraviolet rays to form an organic protective film 3. The substrate 2 is allowed to stand in a pyrole monomer vapor for two hours. Thereafter, it is immersed into a 10% ferrous methanol chloride solution and washed by water sufficiently after one hour to make a electroconductive layer 4 based on a pi conjugate structure. This makes the product hard to damage and achieves higher quality with limited adhesion of dirt and dust and limited generation of errors.

公开(公告)号：JPS6483148A

公开(公告)日：1989-03-28

申请号：JP24115787

申请日：1987-09-26

Applicant: KAO CORP

Inventor： YAMAUCHI MICHIHIDE ,  ISHIKAWA ATSUSHI

IPC: G01N27/30 ,  G01N27/416 ,  G01N27/48

Abstract: PURPOSE:To improve the stability of a base current in a carbon electrode and thereby to improve the precision in analysis and reproducibility, by a method wherein the density and the size of an opening existing in a working electrode are set at specified values. CONSTITUTION:A sample liquid to be quantified is supplied from a high-speed liquid chromatography 1 into an introduction port 2, made to contact with a working electrode 4 covered with a Teflon seal 3, made further to contact with a reference electrode 5 and then discharged from a discharge port 7 to which an auxiliary electrode 6 is fitted. Between the working electrode 4 and the reference electrode 5 a voltage is impressed from a power source 8. A current value of the working electrode 4 is relation to the eluation volume of the sample liquid passing from the introduction port 2 to the discharge port 7 is measured for analysis by a current measuring device 9. Besides, the working electroe 4 has openings whose density is 2X10 /mm bellow and whose maximum diameter is 0.5mum or below, and it is formed of an isotropic carbon material. By using a surface-polished vitreous carbon material as this carbon material, S/N can be improved and thus a stable analysis can be attained.

公开(公告)号：JP2014125516A

公开(公告)日：2014-07-07

申请号：JP2012282204

申请日：2012-12-26

Applicant: Kao Corp ,  花王株式会社

Inventor： ISHIKAWA ATSUSHI

IPC: C08G18/00 ,  C08G18/42

Abstract: PROBLEM TO BE SOLVED: To provide a polyol mixture capable, even in a case where a hydrocarbon foaming agent is used on an occasion for manufacturing a rigid polyurethane foam obtained by using an aromatic polyester polyol as a polyol component, of preserving a homogeneous state of the polyol mixture.SOLUTION: The provided polyol mixture is a polyol mixture for manufacturing a rigid polyurethane foam including (A) polyols including an aromatic polyester polyol having a hydroxyl value of 100 mgKOH/g or above and 500 mgKOH/g or below, (B) a hydrocarbon foaming agent, (C) a catalyst, (D) a foam stabilizer, and (E) a polyoxyethylene adduct of castor oil and/or polyoxyethylene adduct of cured castor oil.

Abstract translation: 要解决的问题：为了提供一种多元醇混合物，即使在使用芳香族聚酯多元醇作为多元醇成分得到的硬质聚氨酯泡沫塑料的制造中使用烃类发泡剂的情况下，也可以保持均匀状态 多元醇混合物。溶液：所提供的多元醇混合物是用于制造硬质聚氨酯泡沫体的多元醇混合物，其包括（A）包含羟值为100mgKOH / g或更高和500mgKOH / g或更低的芳族聚酯多元醇的多元醇 B）烃发泡剂，（C）催化剂，（D）泡沫稳定剂和（E）蓖麻油的聚氧乙烯加合物和/或固化蓖麻油的聚氧乙烯加合物。

公开(公告)号：JP2008266579A

公开(公告)日：2008-11-06

申请号：JP2008036487

申请日：2008-02-18

Applicant: Kao Corp ,  花王株式会社

Inventor： ISHIKAWA ATSUSHI

IPC: C08G18/66 ,  C08G101/00

CPC classification number: Y02P20/544

Abstract: PROBLEM TO BE SOLVED: To provide a manufacturing method for rapidly producing a molded polyurethane article under a high reactivity by a reaction injection molding method and in the method described above even in the case that the molded polyurethane article is made to be a low density by foaming, and the molded polyurethane article in which the surface property is good and lowering of hardness is suppressed, further under suppressing the lowering of hardness, weatherability is superior, can be rapidly produced. SOLUTION: Provided is a method for producing a molded polyurethane article by the reaction injection molding, wherein a polyol-containing component containing a polyether type polyol with a hydroxyl value of 15-60 mgKOH/g and a number of a functional group of 2 to 4, and a chain extender having a molecular weight of 60-200 and a number of functional groups of 2 to 4, and a polyisocyanate component containing an aromatic polyisocyanate and its modified material are reacted, under the condition where a catalyst is present and water is not substantially contained, for 10 sec or less, to form a solid phase. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 解决的问题：提供一种通过反应注射成型法快速制备高反应性的模制聚氨酯制品的制造方法，并且在上述方法中，即使在将模制的聚氨酯制品制成为 低密度发泡，并且抑制表面性能好，硬度降低的成型聚氨酯制品进一步抑制硬度降低，耐气候性优异。 解决方案：提供一种通过反应注射成型制造模制的聚氨酯制品的方法，其中含有羟值为15-60mgKOH / g的聚醚型多元醇和多官能团的含多元醇的组分 为2〜4，分子量为60〜200，官能团数为2〜4的增链剂和含有芳香族多异氰酸酯及其改性物质的多异氰酸酯成分在催化剂为 存在和水基本上不含有10秒或更少的时间以形成固相。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008138053A

公开(公告)日：2008-06-19

申请号：JP2006324740

申请日：2006-11-30

Applicant: Kao Corp ,  花王株式会社

Inventor： ISHIKAWA ATSUSHI

IPC: C08G18/78

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a foamed polyurethane by which the foamed polyurethane having good surface nature, and highly maintained hardness, breaking strength and breaking elongation even after being formed into a low density product by foaming can be produced in high reactivity without using a lead salt of an organic acid of an environmental loading material by a reaction injection molding method.
SOLUTION: The method for producing the foamed polyurethane by the reaction injection molding method using a polyol-containing component, a polyisocyanate component, a catalyst and a foaming agent is characterized by the following items. The polyol-containing component has 15-60 mg KOH/g hydroxy value, and contains a polyether-based polyol having two to four functional groups, and a chain extender having 60-200 molecular weight and two to four functional groups. The polyisocyanate component contains an aliphatic and/or alicyclic polyisocyanate and an isocyanate-modified product of the polyisocyanate, and the NCO content thereof is 22-32 wt.%. The catalyst contains a bismuth salt of an organic acid, and the foaming agent is a supercritical gas.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供一种发泡聚氨酯的制造方法，其中具有良好表面性质的发泡聚氨酯，即使在通过发泡形成低密度产品之后，硬度，断裂强度和断裂伸长率也能保持高 通过反应注射成型法不使用环境负荷材料的有机酸的铅盐，以高反应性生产。 解决方案：通过使用含多元醇的成分，多异氰酸酯成分，催化剂和发泡剂的反应注射成型法制造发泡聚氨酯的方法的特征在于以下项目。 含有多元醇的组分具有15-60mg KOH / g羟基值，并且含有具有2-4个官能团的聚醚基多元醇和具有60-200分子量和2-4个官能团的扩链剂。 多异氰酸酯组分含有脂族和/或脂环族多异氰酸酯和多异氰酸酯的异氰酸酯改性产物，其NCO含量为22-32重量％。 催化剂含有有机酸的铋盐，发泡剂是超临界气体。 版权所有（C）2008，JPO＆INPIT